Synfacts
Issue 02 · February 2011
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A11
SYNFORM
ISSUE 2011/02
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Synthesis of Natural Products and Potential Drugs
z119
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0119
Synthesis of Telcagepant
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0120
Synthesis of MK-8141
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0121
Total Synthesis of (+)-Roxaticin
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0122
Synthesis of Pestalone and Pestalalactone
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0123
Synthesis of (+)-Chaetocin A
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0124
Synthesis of (+)- and (-)-Fluvastatin
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0125
Synthesis of (+)-Lycoflexine
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0126
Synthesis of Lactimidomycin
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0127
Total Synthesis of Isokidamycin
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0128
Synthesis of a CCK
1
Receptor Antagonist
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0129
Synthesis of (-)-209I and (-)-223J
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0130
Synthesis of Zanamivir Congeners
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Synthesis of Heterocycles
z131
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0131
Au/Ag-Catalyzed Synthesis of 3-Fluorofurans
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0132
Acid-Catalyzed Rearrangement of Ureido-dihydrofurans to
N
-Pyrrole Ureas
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0133
Enantioselective Synthesis of Dihydrofurans Using Dynamic Kinetic Resolution
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0134
Copper-Catalyzed Ullmann-Type Coupling Route to Quinazolines
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0135
Synthesis of Oxazoles via TBHP/I
2
-Mediated Reaction of Alkenes with Benzylic Amines
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0136
Silver-Catalyzed Synthesis of 2-Amino-imidazole Alkaloids
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0137
NHC-Catalyzed Michael Addition for the Synthesis of Dihydropyranones
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0138
A Nickel-Catalyzed [2+2+1]-Cycloaddition Approach to Lactams
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0139
Synthesis of 2-Aminobenzoxazoles from 2-Aminophenols
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0140
Synthesis of Fused Thiophene-Isoxazoles from 2-Alkynyl-3-Nitro-Thiophenes
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0141
Synthesis of 1,4-Benzothiazepin-5-ones from
N
-Tosyl Aziridines and 2-Iodothiophenols
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0142
Synthesis of Isoindolones from Imines and
ortho
-Iodobenzoyl Acid Chlorides
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0143
Directed
ortho
-Metalation-Halocyclization Route to Benzothiophenes
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0144
Palladium-Catalyzed Heterannulation Synthesis of 3-Borylated Indoles
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0145
Tertiary Amine Catalyzed Annulation Route to Tetrasubstituted Pyrans
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Synthesis of Materials and Unnatural Products
z147
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0147
Controlling Supramolecular Chirality
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0148
Perfluorobenzene Captures Fullerene
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0149
Supramolecular Glow-Sticks
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0150
Pillar[5]arenes
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0151
Unquenched Fluorescent Metal Nanocages
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0152
Polyelectrolytes: Fluorescence Turn-On Sensors in Aqueous Media
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0153
(2,1-
a
)-Indenofluorene with Clapping Fluorenes
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0154
Cheap Precursor for Arynes
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0155
Microwaveable Calixarenes
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0156
Polycyclic Imide Derivatives: Getting in Tune with Your Inner LUMO
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0157
Bicyclononynes: New Ring-Strained Alkynes for Bioorthogonal Labeling
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0158
Facile Synthesis of Benzobisthioxanthene
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0159
Novel Synthesis of Tetrabenzocoronenes
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0160
Black to Transmissive Electrochromic Polymers
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0161
Synthesis of Functionalized Pentacenes from Isobenzofurans
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z163
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0163
Stereoselective Iodocarbocyclization
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0164
Intermolecular Hydroacylation of Homoallylic Sulfides
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0165
Enantioselective Synthesis of 2-Carboxy Cyclic Ethers
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0166
The Effect of β-Substituents in Aldol Reactions of Boron Enolates
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0167
Design of a New Six-Membered NHC Ligand for Copper-Catalyzed β-Borylation
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0168
Enantioenriched Allyl Esters via Lipase-Vanadium Combo Catalysis
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0169
Enantioselective
syn
Hydration of Enones in Water Using a DNA-Based Catalyst
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0170
Alkene Alkoxycarbonylation Using Novel Chiral Dipalladium Catalysts
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0171
Chiral Fluoride Generator and Its Application in Kinetic Resolution
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0172
Enantioselective Synthesis of Planar Chiral Arene Chromium Complexes
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0173
Asymmetric Synthesis of Tertiary Stereogenic Centers
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0174
Titanium-Catalyzed Reaction of Alkenylboron Reagents with Aldehydes
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0175
Selective aza-Barbier Allylations of N-
tert
-Butanesulfinylimines
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0176
Rare Earth Metal Catalyzed Asymmetric Intermolecular Hydroamination
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0177
Lewis Base Catalyzed Asymmetric Aldol Addition of Oxyketene Imines to Aldehydes
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0178
Copper-Catalyzed Synthesis of 3-Aminoindoles and Pyrroloindolines
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0179
Synthesis of Chiral Cyclohexenones Using a Multicomponent Reaction
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0180
Nickel-Catalyzed [2+2+2] Cycloaddition of Isocyanates and Allenes
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0181
Domino Synthesis of Complex Tetrahydropyrans
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0182
Synthesis of Chiral Tertiary Organoboronic Esters by Conjugate Addition
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0183
Enantioselective Synthesis of
C
2
and
C
1
Dienes
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0184
Neodymium-Catalyzed Asymmetric Synthesis of 1,3-Bis(hydroxymethyl)-2-oxindoles
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0185
Enantioselective Copper-Catalyzed Intramolecular Carboamination of Alkenes
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0186
Copper-Catalyzed Asymmetric Allylic Substitution with Arylaluminum Reagents
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0187
Hydrogen Bond Assisted Asymmetric Metal Catalysis
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0188
Asymmetric Hydrogenation of Fluorinated Imines
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0189
Iridium-Catalyzed Enantioselective Ring Opening of Azanorbornene Derivatives
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0190
Enantioconvergent Synthesis of Allyl Boronates
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0191
Dynamic Kinetic Resolution under Ruthenium-Catalyzed Transfer Hydrogenation
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0192
Enantioselective Desymmetrization of Cyclopropenes
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Metal-Mediated Synthesis
z193
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0193
β-Selective Arylation of Thiophenes
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0194
3,3-Bissilyl Carbonyl and Enol Derivatives via Brook Rearrangement
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0195
Stereospecific Cross-Coupling of Secondary Alkyl Trifluoroborates
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0196
Palladium(II)-Catalyzed Decarboxylative Addition of Benzoic Acids to Nitriles
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0197
Coupling of
N
-Tosylhydrazone, Terminal Alkyne, and Aryl Halide
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0198
Control of Product Selectivity in Ruthenium-Catalyzed C-H Arylation
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0199
A Multiligand-Based Palladium Catalyst for C-N Cross-Coupling Reactions
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0200
Coupling of Indium Homoenolates with Acid Chlorides
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0201
Palladium-Catalyzed Decarboxylative Cross-Coupling of 2-Phenylbenzoic Acids
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0202
Palladium-Catalyzed Cyanation of Aryl Mesylates
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0203
Iron-Catalyzed Oxidative C-H Transformation of Allylarenes or Alkenes to Alkenyl Nitriles
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0204
Palladium-Catalyzed Cross-Coupling with Hydrazine
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0205
Iridium-Catalyzed
ortho
-Silylation of Arenes by Hydroxyl-Directed C-H Activation
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0206
Rhodium-Catalyzed 1,4-Addition of Arylboronic Acids to Allyl Sulfones
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0207
Copper-Catalyzed Direct Carboxylation of C-H Bonds Using Carbon Dioxide
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Organo- and Biocatalysis
z209
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0209
NHC-Catalyzed C-H Alkylation of Aldehydes
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0210
Asymmetric α-Alkylation of Cyanocarbolines by Phase-Transfer Catalysis
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0211
α-Allylation of Aldehydes via a Conjugate Addition-Elimination Pathway
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0212
Betaine-Catalyzed Synthesis of Cyclic Carbonates
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0213
NHC-Catalyzed Intramolecular Redox Lactamization
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0214
An Efficient Entry to Chiral Pyrroloindolines
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0215
Chiral Guanidinium-Catalyzed Enantioselective Claisen Rearrangement
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0216
A New Chiral Primary Amine Catalyst: Application in Conjugate Additions
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0217
2-Hydroxyalkyl, 2-Aminoalkyl Furanes, and 2,3-Dihydrofuranes
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0218
Michael Addition of β-Ketosulfones to Nitroalkenes
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0219
SPINOL-Derived Phosphoric Acids for Addition of Indoles to Imines
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0220
A Highly Efficient Approach to Chiral Homoaldols
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0221
An Asymmetric Domino Aza-Morita-Baylis-Hillman/Aza-Michael Reaction
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Polymer-Supported Synthesis
z223
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0223
Asymmetric Addition of Diethyl Zinc to Benzaldehydes with Ti(O
i
-Pr)
4
and NS(a)
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0224
Flow Hydroalkylation of Styrenes under Microwave Irradiation
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0225
Wittig Reactions Using a Bifunctional Polymeric Reagent
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0226
A Supported Organic Catalyst for Asymmetric Michael Addition
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0227
Fluorination with Polystyrene-Supported Iodobenzenes in Ionic Liquid
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0228
Dehydration of Amides with Hydrotalcite-Supported Vanadium Catalyst
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0229
Aerobic Epoxidation of Stilbene with Copper on FePt Nanowires
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0230
Aqueous Suzuki-Miyaura Coupling with Palladium Nanoparticles/BMI-TFSI
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0231
TEMPO-Coated Fe
3
O
4
Nanoparticles for Selective Oxidation of Alcohols
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0232
N-Formylation of Amines with Methanol or Formalin Using Gold Nanoclusters
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0233
Solid-Phase Total Synthesis of Symplocamide A
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0234
Acetalization with Methanol Using Metal-Organic Frameworks
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0235
Solid-Phase Synthesis of an Amino Imidazotriazine Library
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Addenda and Errata
0236
Alkenylative Cross-Coupling between Alkyl Sulfides and Grignard Reagents
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