DOI: 10.1055/s-00000084

Synthesis

Issue 21 · Volume 57 · November 2025 DOI: 10.1055/s-015-62433

Editorial

  • III

    Paul Knochel at 70

    • Table of Contents

  • VI

    Linked PDF of Table of Contents

    • Review

    Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3031
    Cossy, Janine:

    Cross-Coupling Reactions Between Alkynyl Metals and (Pseudo)Halides Induced by Earth-Abundant Transition Metals (Mn, Fe, Co, Ni, Cu)

    Image for article: Cross-Coupling Reactions Between Alkynyl Metals and (Pseudo)Halides Induced by Earth-Abundant Transition Metals (Mn, Fe, Co, Ni, Cu)
  • 3049
    Tian, Huan; Fleming, Fraser F.:

    Isocyanoalkenes: Occurrence, Syntheses, and Reactivity

    Image for article: Isocyanoalkenes: Occurrence, Syntheses, and Reactivity

    • Short Review

    Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3094
    Jana, Sayan K.; Maji, Biplab:

    Nickel-Catalyzed Cross-Electrophile Coupling Reactions of Alcohols and Their Derivatives

    Image for article: Nickel-Catalyzed Cross-Electrophile Coupling Reactions of Alcohols and Their Derivatives
  • 3105
    Piccardi, Riccardo; Micouin, Laurent:

    An Overview of the Direct Preparation of Organoaluminum Compounds

    Image for article: An Overview of the Direct Preparation of Organoaluminum Compounds
  • 3127
    Arnaudy, Roxane; Djebbar, Faycel; Tintar, Adrien; Lefèvre, Guillaume:

    Bis-Alkenyl Compounds from Group XIV Elements (Si, Ge, Sn): Synthesis, Reactivity, and Applications

    Image for article: <i>Bis</i>-Alkenyl Compounds from Group XIV Elements (Si, Ge, Sn): Synthesis, Reactivity, and Applications

    • Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3147
    Dupeux, Aurélien; Truchon, Alexis; Gentilini, Emilie; Michelet, Véronique:

    Gold- and Platinum-Catalyzed Prins-Type [2+2+2]-Cycloadditions: From Original Methods to Applications

    Image for article: Gold- and Platinum-Catalyzed Prins-Type [2+2+2]-Cycloadditions: From Original Methods to Applications
  • 3158
    Collum, David B.:

    An Accidental Synthetic Chemist

    Image for article: An Accidental Synthetic Chemist

    • Paper

    Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3179
    Gao, M.-Y.; Durandetti, M.; Gosmini, C.:

    Synthesis of Diarylmethanes by Cobalt-Catalyzed Reductive Cross-Coupling via Csp3–S Bond Activation

    Image for article: Synthesis of Diarylmethanes by Cobalt-Catalyzed Reductive Cross-Coupling via Csp<sup>3</sup>–S Bond Activation
    Supplementary Material (PDF)
  • 3189
    Ramos, Mariah Carol; Kawasaki, Tairin; Cabanero, David; Sandmeier, Tobias; Rovis, Tomislav:

    Skeletal Rearrangement of Pyridine Derivatives via a Light-Induced Ring Expansion

    Image for article: Skeletal Rearrangement of Pyridine Derivatives <i>via</i> a Light-Induced Ring Expansion
    Supplementary Material (PDF)
  • 3197
    Blanco-López, Ester; Sirvent, Ana; Lulli, Thomas; Merino, Pedro; Nájera, Carmen; Yus, Miguel; Foubelo, Francisco; Retamosa, María de Gracia; Sansano, José M.:

    Deacetylative Protocol to Obtain Diastereoselectively α-Fluoro-β-amino-oxindoles via a Mannich-Type Reaction using Aliphatic N-tert-Butanesulfinyl Imines

    Image for article: Deacetylative Protocol to Obtain Diastereoselectively α-Fluoro-β-amino-oxindoles via a Mannich-Type Reaction using Aliphatic <i>N-tert</i>-Butanesulfinyl Imines
    Supplementary Material (PDF)
  • 3205
    Okuda, Jun; Ingram, Aaron; Wang, Dong:

    Halide-Substituted Grubbs–Hoveyda Catalysts for Aqueous Ring-Closing Metathesis

    Image for article: Halide-Substituted Grubbs–Hoveyda Catalysts for Aqueous Ring-Closing Metathesis
    Supplementary Material (PDF)

    • Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3211
    Boussandel, Sirine; Erb, William; Roisnel, Thierry; Blot, Marielle; Hurvois, Jean-Pierre; Butler, Ian; Samarat, Ali; Mongin, Florence:

    Hexafluoroisopropanol-Promoted Substitution Toward the Synthesis of Enantiopure Ferrocene Phosphines

    Image for article: Hexafluoroisopropanol-Promoted Substitution Toward the Synthesis of Enantiopure Ferrocene Phosphines
    Supplementary Material (PDF)
  • 3227
    Grimm, Joyce A. A.; List, Benjamin:

    Asymmetric Prins Cyclizations of O-Prenylated Salicylaldehydes

    Image for article: Asymmetric Prins Cyclizations of <i>O</i>-Prenylated Salicylaldehydes
    Open Access
    Supplementary Material (PDF)

    • Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3233
    Conrads, Christian; Eilers, Maverick; Hülsken, Noah; Langletz, Tim; Hoffmann, Alexander; Herres-Pawlis, Sonja:

    Synthesis of Novel Guanidine-Schiff-Base Iron(III) and Zinc(II) Complexes

    Image for article: Synthesis of Novel Guanidine-Schiff-Base Iron(III) and Zinc(II) Complexes
    Supplementary Material (PDF)
  • 3241
    Lee, Paul; Eugene, Bill D.; Allais, Christophe; Singer, Robert A.; Morken, James P.:

    Tetrahydronaphthalenes by Enantioselective Migratory Suzuki–Miyaura Cross-Coupling of meso Bis(Boronic Esters)

    Image for article: Tetrahydronaphthalenes by Enantioselective Migratory Suzuki–Miyaura Cross-Coupling of <i>meso</i> Bis(Boronic Esters)
  • 3251
    Siegmund, Torsten; S. Stephenson, David; Ofial, Armin R.; Mayer, Robert J.; Mayr, Herbert:

    How Electrophilic Are Keteniminium Ions?

    Image for article: How Electrophilic Are Keteniminium Ions?
    Supplementary Material (PDF)
  • 3263
    Knupe-Wolfgang, Paula; Hilt, Gerhard:

    The Transformation of Alkyl- and Aryl-Sodium Reagents with Simple Amides for the Direct Synthesis of Ketones

    Image for article: The Transformation of Alkyl- and Aryl-Sodium Reagents with Simple Amides for the Direct Synthesis of Ketones
    Supplementary Material (PDF)
  • 3273
    Acuña-Bolomey, Emilio G. A.; Oestreich, Martin:

    Nickel-Catalyzed Enantioconvergent C(sp3)–C(sp3) Cross-Coupling between α-Iodogermanes and Alkylzinc Reagents

    Image for article: Nickel-Catalyzed Enantioconvergent C(sp<sup>3</sup>)–C(sp<sup>3</sup>) Cross-Coupling between α-Iodogermanes and Alkylzinc Reagents
    Supplementary Material (PDF)
  • 3283
    Sánchez-Roa, David; Kocher, Jasmin; Tortajada, Andreu; Hevia, Eva:

    Structurally Mapping Sodium-Mediated Synthesis of 1,4-Substituted Dihydropyridines: Nucleophilic Addition vs. Deprotonative Metalation

    Image for article: Structurally Mapping Sodium-Mediated Synthesis of 1,4-Substituted Dihydropyridines: Nucleophilic Addition vs. Deprotonative Metalation
    Supplementary Material (PDF)
  • 3295
    Liu, Chuanqi; Wang, Xiaoqian; Du, Zhao; Wang, Yilei; Peng, Zhihua:

    Nickel-Catalyzed Reductive Cross-Coupling of Chlorobismuths with Aryl Halides

    Image for article: Nickel-Catalyzed Reductive Cross-Coupling of Chlorobismuths with Aryl Halides
    Supplementary Material (PDF)
  • 3307
    Prapapongpan, Pannaporn; Nelson, Kylee B.; Zakharov, Lev N.; Blakemore, Paul R.:

    Ferrocene-Templated Synthesis of Fused Aminofulvenes: Elaboration of Chalaniline A and a Reversed Regioisomer via a Ferroceno[b]chromone

    Image for article: Ferrocene-Templated Synthesis of Fused Aminofulvenes: Elaboration of Chalaniline A and a Reversed Regioisomer via a Ferroceno[<i>b</i>]chromone
    Supplementary Material (PDF)
  • 3315
    Du, Hong-Jian; Yin, Hao-Nan; Zhou, Yun; Chu, Xue-Qiang; Xu, Hao; Shen, Zhi-Liang:

    Pd-Catalyzed Decarboxylative Couplings of Aryl Triazine Esters With Zinc Polyfluorobenzoates

    Image for article: Pd-Catalyzed Decarboxylative Couplings of Aryl Triazine Esters With Zinc Polyfluorobenzoates
    Supplementary Material (PDF)

    • Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3325
    Del Vecchio, Antonio; Kamal, Fadwa; Rouen, Mathieu; Mauduit, Marc:

    Photochemical Activation of Ruthenium Complexes Containing Unsymmetrical Unsaturated N-Heterocyclic Carbenes for Olefin Metathesis

    Image for article: Photochemical Activation of Ruthenium Complexes Containing Unsymmetrical Unsaturated N-Heterocyclic Carbenes for Olefin Metathesis
    Supplementary Material (PDF)
  • 3334
    Goldfuss, Bernd; Wang, Xiaochen; Sartakov, Denis:

    Hydrogen-Bonding Cyclodiphosphazane Organocatalysts in Enantioselective Michael Additions

    Image for article: Hydrogen-Bonding Cyclodiphosphazane Organocatalysts in Enantioselective Michael Additions
    Supplementary Material (PDF)

    • Published as part of the Special Topic Dedicated to Prof. Paul Knochel

  • 3341
    Luo, Donghao; Yuan, Hao; Nie, Changrui; Ge, Shulei; Li, Jie:

    Nickel-Catalyzed Alkylcarbonylation of α-Trifluoromethyl-Substituted Styrenes via Selective Monodefluorinative Strategy

    Image for article: Nickel-Catalyzed Alkylcarbonylation of α-Trifluoromethyl-Substituted Styrenes via Selective Monodefluorinative Strategy
    Supplementary Material (PDF)
  • 3350
    García, Lorena; Carrillo, Luisa; Reyes, Efraím; Uria, Uxue; Prieto, Liher; Vicario, Jose L.:

    Organocatalytic Enantioselective Nitro-Vinylcyclopropane-Cyclopentene Rearrangement: Expanding the Reactivity of Donor–Acceptor Cyclopropanes

    Image for article: Organocatalytic Enantioselective Nitro-Vinylcyclopropane-Cyclopentene Rearrangement: Expanding the Reactivity of Donor–Acceptor Cyclopropanes
    Supplementary Material (PDF)
  • 3361
    Petrini, Marino; Palmieri, Alessandro; Gheco, Elettra:

    Continuous Flow Telescoped Synthesis of Benzofurans Starting from Nitroalkanes and O-Acetyl Salicylaldehydes

    Image for article: Continuous Flow Telescoped Synthesis of Benzofurans Starting from Nitroalkanes and <i>O</i>-Acetyl Salicylaldehydes
    Supplementary Material (PDF)
  • 3370
    Joly, Nicolas; Kjellberg, Marianne; Bouchet, Alexis; Nicolas, Emmanuel; Cantat, Thibault; Anthore-Dalion, Lucile:

    Water-Mediated Rhenium-Catalyzed Photodeoxygenation of Polyfunctional Organic N-Oxides

    Image for article: Water-Mediated Rhenium-Catalyzed Photodeoxygenation of Polyfunctional Organic <i>N</i>-Oxides
    Supplementary Material (PDF)
  • 3377
    Dierenbach, Niklas; Waloch, Christoph; Bauer, Felix; Seiche, Wolfgang; Breit, Bernhard:

    Synthesis of Symmetric and P-Stereogenic Self-Assembling Pyridone-Based Phosphorus Ligands

    Image for article: Synthesis of Symmetric and P-Stereogenic Self-Assembling Pyridone-Based Phosphorus Ligands
    Supplementary Material (PDF)
  • 3394
    Zhang, Qingxin; Berro, Mahdi; Darcel, Christophe:

    Iron Catalyst and Blue Light Partnership for Selective Desulfurization of Secondary and Primary Thioamides

    Image for article: Iron Catalyst and Blue Light Partnership for Selective Desulfurization of Secondary and Primary Thioamides
    Supplementary Material (PDF)