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Synthesis
DOI: 10.1055/a-2681-5943
Paper

Nickel-Catalyzed Reductive Cross-Coupling of Chlorobismuths with Aryl Halides

Chuanqi Liu
1   Department of Chemistry, China University of Petroleum East China, Qingdao, China (Ringgold ID: RIN71136)
,
Xiaoqian Wang
1   Department of Chemistry, China University of Petroleum East China, Qingdao, China (Ringgold ID: RIN71136)
,
Zhao Du
1   Department of Chemistry, China University of Petroleum East China, Qingdao, China (Ringgold ID: RIN71136)
,
Yilei Wang
1   Department of Chemistry, China University of Petroleum East China, Qingdao, China (Ringgold ID: RIN71136)
,
Zhihua Peng 
1   Department of Chemistry, China University of Petroleum East China, Qingdao, China (Ringgold ID: RIN71136)
› Author Affiliations
Supported by: Fundamental Research Funds for the Central Universities 22CX03031A
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A straightforward and efficient method for the synthesis of valuable arylbismuthanes via nickel-catalyzed cross-electrophilic coupling of chlorobismuths with aryl halides has been reported. This cross-electrophile C(sp2)-Bi coupling reaction is conducted under mild reaction conditions and exhibits a broad substrate scope. Notably, the described protocol tolerates various sensitive functionalities including alcohol, nitrile, ester, ketone, and aldehyde. Moreover, the application of the generated arylbismuthanes to the Pd-catalyzed cross-coupling reaction is demonstrated.



Publication History

Received: 11 July 2025

Accepted after revision: 11 August 2025

Accepted Manuscript online:
12 August 2025

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