DOI: 10.1055/s-00000084

Synthesis

Issue 15 · Volume 49 · August 2017 DOI: 10.1055/s-007-34462

Synform

  • A123
    Zanda, Matteo:

    SYNFORM ISSUE 2017/08

    • preface

  • I
    Knochel, Paul:

    Preface – Special Issue Dedicated to Professor Herbert Mayr

    • review

  • 3183
    Evano, Gwilherm; Lecomte, Morgan; Thilmany, Pierre; Theunissen, Cédric:

    Keteniminium Ions: Unique and Versatile Reactive Intermediates for Chemical Synthesis

    Image for article: Keteniminium Ions: Unique and Versatile Reactive Intermediates for Chemical Synthesis

    • short review

  • 3215
    Chen, Yi-Hung; Ellwart, Mario; Malakhov, Vladimir; Knochel, Paul:

    Solid Organozinc Pivalates: A New Class of Zinc Organometallics with Greatly Enhanced Air- and Moisture-Stability

    Image for article: Solid Organozinc Pivalates: A New Class of Zinc Organometallics with Greatly Enhanced Air- and Moisture-Stability
  • 3224
    Breugst, Martin; von der Heiden, Daniel; Schmauck, Julie:

    Novel Noncovalent Interactions in Catalysis: A Focus on Halogen, Chalcogen, and Anion-π Bonding

    Image for article: Novel Noncovalent Interactions in Catalysis: A Focus on Halogen, Chalcogen, and Anion-π Bonding
  • 3237
    Bartolo, Nicole D.; Read, Jacquelyne A.; Valentín, Elizabeth M.; Woerpel, K. A.:

    Reactions of Allylmagnesium Halides with Carbonyl Compounds: Reactivity, Structure, and Mechanism

    Image for article: Reactions of Allylmagnesium Halides with Carbonyl Compounds: Reactivity, Structure, and Mechanism
  • 3247
    Mąkosza, Mieczysław:

    How Does Nucleophilic Aromatic Substitution in Nitroarenes Really Proceed: General Mechanism

    Image for article: How Does Nucleophilic Aromatic Substitution in Nitroarenes Really Proceed: General Mechanism
  • 3255
    Tabolin, Andrey A.; Sukhorukov, Alexey Yu.; Ioffe, Sema L.; Dilman, Alexander D.:

    Recent Advances in the Synthesis and Chemistry of Nitronates

    Image for article: Recent Advances in the Synthesis and Chemistry of Nitronates
  • 3269
    Parchomyk, Tobias; Koszinowski, Konrad:

    Iron-Catalyzed Cross-Coupling: Mechanistic Insight for Rational Applications in Synthesis

    Image for article: Iron-Catalyzed Cross-Coupling: Mechanistic Insight for Rational Applications in Synthesis
  • 3281
    Dana, Suman; Ramakrishna, Isai; Baidya, Mahiuddin:

    Ambident Reactivity of Nitroso Compounds for Direct Amination and Hydroxylation of Carbonyls

    Image for article: Ambident Reactivity of Nitroso Compounds for Direct Amination and Hydroxylation of Carbonyls
  • 3291
    Reissig, Hans-Ulrich; Zimmer, Reinhold:

    Cyclizations of Alkoxyallenes: Mechanisms, Intermediates, ­Products – A Personal Account on Solved and Unsolved Problems with Unique Allene Building Blocks

    Image for article: Cyclizations of Alkoxyallenes: Mechanisms, Intermediates, ­Products – A Personal Account on Solved and Unsolved Problems with Unique Allene Building Blocks
  • 3303
    Hartley, Will C.; O’Riordan, Timothy J. C.; Smith, Andrew D.:

    Aryloxide-Promoted Catalyst Turnover in Lewis Base Organo­catalysis

    Image for article: Aryloxide-Promoted Catalyst Turnover in Lewis Base Organo­catalysis
  • 3311
    Fantin, Marco; Lorandi, Francesca; Gennaro, Armando; Isse, Abdirisak A.; Matyjaszewski, Krzysztof:

    Electron Transfer Reactions in Atom Transfer Radical Polymerization

    Image for article: Electron Transfer Reactions in Atom Transfer Radical Polymerization
  • 3323
    Armstrong, Roly J.; Aggarwal, Varinder K.:

    50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling

    Image for article: 50 Years of Zweifel Olefination: A Transition-Metal-Free Coupling
    Open Access
  • 3337
    Abe, Manabu; Chitose, Youhei; Jakkampudi, Satish; Thuy, Pham Thi Thu; Lin, Qianghua; Van, Bui Thi; Yamada, Ayato; Oyama, Ryoko; Sasaki, Miyu; Katan, Claudine:

    Design and Synthesis of Two-Photon Responsive Chromophores for Near-Infrared Light-Induced Uncaging Reactions

    Image for article: Design and Synthesis of Two-Photon Responsive Chromophores for Near-Infrared Light-Induced Uncaging Reactions
  • 3347
    Micheletti, Gabriele; Boga, Carla:

    Nucleophile/Electrophile Combinations in Aromatic Substitution: From Wheland to Wheland–Meisenheimer Intermediates Using Strongly Activated Arenes

    Image for article: Nucleophile/Electrophile Combinations in Aromatic Substitution: From Wheland to Wheland–Meisenheimer Intermediates Using Strongly Activated Arenes
  • 3357
    Zhao, Rong; Chang, Denghu; Shi, Lei:

    Recent Advances in Cyclic Diacyl Peroxides: Reactivity and Selectivity Enhancement Brought by the Cyclic Structure

    Image for article: Recent Advances in Cyclic Diacyl Peroxides: Reactivity and Selectivity Enhancement Brought by the Cyclic Structure
  • 3366
    Asahara, Haruyasu:

    Recent Advances in the Carbon–Carbon Bond-Forming Reactions of N-Acylketimines

    Image for article: Recent Advances in the Carbon–Carbon Bond-Forming Reactions of <i>N</i>-Acylketimines
  • 3377
    Maji, Biplab; Barman, Milan K.:

    Recent Developments of Manganese Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions

    Image for article: Recent Developments of Manganese Complexes for Catalytic Hydrogenation and Dehydrogenation Reactions
  • 3394
    Krishnamoorthy, Sankarganesh; Prakash, G. K. Surya:

    Silicon-Based Reagents for Difluoromethylation and Difluoromethylenation Reactions

    Image for article: Silicon-Based Reagents for Difluoromethylation and Difluoromethylenation Reactions
  • 3407
    Gao, Pin; Gu, Yu-Rui; Duan, Xin-Hua:

    Direct C–H Functionalization of Heteroarenes via Redox-Neutral Radical Process: A Facile Route to C–C Bonds Formation

    Image for article: Direct C–H Functionalization of Heteroarenes via Redox-Neutral Radical Process: A Facile Route to C–C Bonds Formation
  • 3422
    Denegri, Bernard; Matić, Mirela; Kronja, Olga:

    Impact of Electronic Effects on the Nucleofugality of Leaving Groups

    Image for article: Impact of Electronic Effects on the Nucleofugality of Leaving Groups
  • 3433
    Gualandi, Andrea; Mengozzi, Luca; Cozzi, Pier Giorgio:

    Stereoselective SN1-Type Reaction of Enols and Enolates

    Image for article: Stereoselective S<sub>N</sub>1-Type Reaction of Enols and Enolates
  • 3444
    Quint, Valentin; Noël-Duchesneau, Ludovik; Lagadic, Elodie; Morlet-Savary, Fabrice; Lalevée, Jacques; Gaumont, Annie- Claude; Lakhdar, Sami:

    Metal-Free Generation of Phosphorus-Centered Radicals for the Synthesis of Phosphorus-Based Heterocycles: A Personal Account

    Image for article: Metal-Free Generation of Phosphorus-Centered Radicals for the Synthesis of Phosphorus-Based Heterocycles: A Personal Account

    • paper

  • 3453
    Lakhdar, Sami; Berionni, Guillaume; Terrier, François:

    Superelectrophilicity in Michael-Type Reactions: Water Addition to 4-Nitrobenzodifuroxan

    Image for article: Superelectrophilicity in Michael-Type Reactions: Water Addition to 4-Nitrobenzodifuroxan
  • 3460
    Helberg, Julian; Marin-Luna, Marta; Zipse, Hendrik:

    Chemoselectivity in Esterification Reactions – Size Matters after All

    Image for article: Chemoselectivity in Esterification Reactions – Size Matters after All
    Supporting Information (PDF)
  • 3471
    Moormann, Widukind; Langbehn, Daniel; Herges, Rainer:

    Solvent-Free Synthesis of Diazocine

    Image for article: Solvent-Free Synthesis of Diazocine
  • 3476
    Sauermann, Nicolas; Loup, Joachim; Kootz, Darius; Yatham, V. Reddy; Berkessel, Albrecht; Ackermann, Lutz:

    Triazolylidene Ligands Allow Cobalt-Catalyzed C–H/C–O Alkenyl­ations at Ambient Temperature

    Image for article: Triazolylidene Ligands Allow Cobalt-Catalyzed C–H/C–O Alkenyl­ations at Ambient Temperature
    Supporting Information (PDF)
  • 3485
    Siebert, Max; Storch, Golo; Rominger, Frank; Trapp, Oliver:

    Temperature-Controlled Bidirectional Enantioselectivity in Asymmetric Hydrogenation Reactions Utilizing Stereodynamic Iridium Complexes

    Image for article: Temperature-Controlled Bidirectional Enantioselectivity in Asymmetric Hydrogenation Reactions Utilizing Stereodynamic Iridium Complexes
    Supporting Information (PDF)
  • 3495
    Follet, Elsa; Zipse, Hendrik; Lakhdar, Sami; Ofial, Armin R.; Berionni, Guillaume:

    Nucleophilicities and Lewis Basicities of Sterically Hindered Pyridines

    Image for article: Nucleophilicities and Lewis Basicities of Sterically Hindered Pyridines
    Supporting Information (PDF)
  • 3505
    Fernando, Jared E. M.; Levens, Alison; Moock, Daniel; Lupton, David W.:

    N-Heterocyclic Carbene Catalyzed Transformylation

    Image for article: N-Heterocyclic Carbene Catalyzed Transformylation
    Supporting Information (PDF)

    • errata

  • e4
    Reissig, Hans-Ulrich; Zimmer, Reinhold:

    Cyclizations of Alkoxyallenes: Mechanisms, Intermediates, Products – A Personal Account on Solved and Unsolved Problems with Unique Allene Building Blocks