DOI: 10.1055/s-00000131

Synfacts

Issue 12 · Volume 2008 · December 2008 DOI: 10.1055/s-002-13901

Synform

A116
SYNFORM ISSUE 2008/11

Synthesis of Natural Products and Potential Drugs

1241
Synthesis of (±)-Actinophyllic Acid
1242
Synthesis of (-)-Alstonerine
1243
Synthesis of an Estrogen Receptor-β Agonist
1244
Synthesis of Potent Inhibitor of HCV NS3/4A Protease
1245
Synthesis of 35-Deoxy Amphotericin B Methyl Ester
1246
Formal Synthesis of Salinosporamide A
1247
Synthesis of (-)-Secu’amamine
1248
Synthesis of Geldanamycin
1249
Synthesis of (+)-Meloscine
1250
Synthesis of Cannabinoids
1251
Synthesis of (±)-Lyconadin A
1252
Formal Synthesis of (-)-Haouamine
1253
Synthesis of (-)-Quinocarcin
1254
Synthesis of (-)-Incarvillateine
1255
Synthesis of (+)-Neopeltolide

Synthesis of Heterocycles

1257
Microreactor Synthesis of 1,2,4-Oxadiazoles
1258
Synthesis of Highly Substituted Imidazoles from 1,2-Amino Alcohols and Thioamides
1259
A Diels-Alder Approach to Benzannulated [5,6]-Spiroketals
1260
Three-Component Synthesis of 1,5-Benzo-
diazepines
1261
One-Pot Synthesis of 2-(Indolizin-2-yl)benz-imidazoles from Quinoxalinones
1262
Cu(I)-Catalyzed Synthesis of Polysubstituted Furans
1263
Acid-Mediated Synthesis of 3-N,N-Dialkyl-amino-1,2,4-Triazoles
1264
Synthesis of β-Hydroxylactams via Co-Catalyzed Alkylative Aldol Cyclization
1265
Synthesis of Spiro Pyrrolidines from Tetrahydropyridinium Salts
1266
Synthesis of Functionalized Benzofurans via Pd-Catalyzed Cycloisomerization
1267
Three-Component Synthesis of Tetra-substituted Pyridines
1268
Pd-Catalyzed Enolate α-Arylation. Synthesis of Benzofurans
1269
Synthesis of Indoles from N-Aryl Amides and Ethyl Diazoacetate
1270
Rh-Catalyzed Conjugate Addition of o-Amino-arylboronates. Synthesis of Quinolines
1271
Synthesis of 4-Hydroxy-1H-pyrrole-2,3-dicarboxylic Acids

Synthesis of Materials and Unnatural Products

1273
Poly(diacetylene)s from Preorganized Monomers
1274
BINOL-Based Columnar Fluorescent Liquid Crystals
1275
Monoprotection of Diamondoid Diols
1276
Anthracene-Fused Porphyrins
1277
Cu(I)/Cu(II) Fluorescence Switch
1278
Polycyclic Isoquinoline Salts
1279
Bright Light from C60 Chromophores
1280
Fusing Phosphole and Thiophene
1281
Addition of Heteroatoms to Perylenes
1282
Helical Polymer of Porphyrin and a Chiral Pd(II) Complex
1283
Facile Synthesis of Fullerenes
1284
A Full-Color-Tunable Fluorophore
1285
An H-Bond Tetrameric Rosette

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

1287
Nickel-Catalyzed C-CN Bond Activation and Asymmetric Arylcyanation
1288
Amino Acid Derived Sulfinamide Ligands for Transfer Hydrogenation
1289
Nickel-Catalyzed Asymmetric Nazarov Cyclization
1290
Stereodivergent Synthesis of (Z)- and (E)-Thioenamides
1291
Asymmetric Hydroformylation: Synthesis of α-Branched Aryl Aldehydes
1292
New Phosphinite Thioglycosides for Asymmetric Hydrogenation
1293
Application of an Enantioselective Cyclopentenone Synthesis
1294
Rhodium-Catalyzed Reductive Coupling of 2-Vinyl Pyridines and Imines
1295
Enantioselective Hydroarylation of Alkenes via C-H Activation
1296
Palladium-Catalyzed Asymmetric α-Arylation of Aldehydes
1297
Highly Efficient Intermolecular Hydroamination of Bicyclic Alkenes
1298
Ytterbium-Catalyzed Enantioselective Diels-Alder Reaction
1299
New C1-Symmetric Diene Ligands in Rhodium-Catalyzed 1,2-Addition
1300
Copper-Catalyzed Cyclopropanation of Allylic Carbonates with Diboron
1301
Iridium-Catalyzed Allylic Substitution Reactions in Tryptamine Synthesis
1302
Michael Addition of Nitroalkanes to Nitroolefins
1303
Air-Stable Iridium Catalyst in Asymmetric Allylic Substitution
1304
Nickel-Catalyzed Asymmetric Negishi Cross-Couplings
1305
Hydrogenation of Ketones to Provide Aryl Allylic Alcohols
1306
Diastereoselective Radical Cyclization Towards Piperidinones
1307
Borobox Ligands for Asymmetric Henry Reactions
1308
Rhodium-Catalyzed Asymmetric Hydrogenation of Cyclic Imines
1309
Oxidative Aromatic Umpolung Strategy Applied to Tetrahydrofuran Synthesis
1310
Novel P-O-P Ligands for Highly Efficient Hydrogenation of Alkenes

Metal-Mediated Synthesis

1311
Cyclization of α-Amino Alkyllithium Reagents via Carbolithiation
1312
Pd-Catalyzed Carbonylation of Aryl Bromides at Atmospheric Pressure
1313
Efficient Amination of Heteroaryl and Aryl Halides Using [(CyPF-t-Bu)PdCl2]
1314
Versatile Crossed-Claisen Rearrangement by Soft Enolization of Thioesters
1315
Efficient Cross-Coupling Using Pd-Phosphinous Acid Catalysts
1316
Sonogashira Couplings of Aryl Bromides at Room Temperature in Water
1317
An Efficient Ullmann-Type Cu-Catalyzed C-O Bond Formation
1318
Coupling of Cyclopropyl- and Cyclobutyl-trifluoroborates with Aryl Chlorides
1319
Tandem Cyclopropanation with CH2Br2 under Grignard Conditions
1320
Carboxylic Acid Derivatives through Carbonylation of Aryl Chlorides
1321
Practical Heck-Mizoroki Coupling Mediated by a Novel Palladacycle
1322
Ru-Catalyzed Selective Redox Isomerization of Propargylic Alcohols
1323
Sn-Free Radical Addition of Acyloxymethyl to Imines
1324
Rh-Catalyzed Synthesis of Sterically Hindered Diarylketones
1325
Saturated C-Glycosides via Ni-Catalyzed Diastereoselective Cross-Coupling

Organo- and Biocatalysis

1327
Cooperative Catalysis of Chiral Tetraaminophosphonium Carboxylates
1328
Noyori Ligand as Organocatalyst
1329
A New Catalyst for the Desymmetrization of Cyclic Anhydrides
1330
An Atom-Economic Domino Reaction Process
1331
Four Enzymatic Reactions in One Pot
1332
Pyridinium Salts as New Organocatalysts for Acetalizations
1333
A New Bifunctional Catalyst: The Direct Amination of α-Cyanoketones
1334
Asymmetric Transfer Hydrogenation of β-Nitroacrylates
1335
Enantioselective Michael Addition of Nitroalkanes to Nitroolefines
1336
Imidazolium-Tagged Hydroxyproline
1337
Desymmetrizing Aldol Cyclodehydration

Polymer-Supported Synthesis

1339
A Bimetallic, Heterogeneous, Multifunctional Catalyst
1340
Dihydroxylation of Olefins with Polymer-Supported Osmium Catalyst
1341
Pd Nanoparticles in Assembled Silica Microcapsules
1342
Oxidative Cyclization of Alkenols Using Convoluted Polymeric Tungsten Catalysts
1343
Organocatalysis with Polystyrene-Supported PAMAM Dendrimers
1344
Huisgen 1,3-Dipolar Cycloaddition with an Ionic Polymer-Supported Copper(I) Catalyst
1345
Efficient Removal of Amines Using Polymer-Supported Cyclic Anhydride
1346
Oxidative Heck Reaction with Polyaniline-Supported Pd Catalyst
1347
Aerobic Oxidation of Alcohols with Gold Nanoparticles
1348
Olefin Metathesis with Immobilized Grubbs Catalyst
1349
TEMPO-Immobilized on Magnetic C/Co Nanoparticles for Alcohol Oxidation
1350
Au/PCPs-Catalyzed Aerobic Oxidation of Alcohols
1351
Aerobic Oxidation of Alcohols with Gold Nanoparticles
1352
π-Allylic Sulfonylation in Water with PS-PEG Pd-Phosphine Complexes