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https://www.thieme-connect.de/rss/thieme/en/10.1055-s-00000084.xml

DOI: 10.1055/s-00000084

Synthesis

Issue Golden_Issue · Volume · 2019 DOI: 10.1055/s-008-42090

Virtual Golden Anniversary Issue

50 Years SYNTHESIS

Paul, Knochel:

50 Years SYNTHESIS – Golden Anniversary Issue

Full Text PDF (11920 kb)

50 Years SYNTHESIS – Golden Anniversary Issue Part II

Full Text PDF (1994 kb)

Trost, Barry M.; Schultz, Johnathan E.:

Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters

Image for article: Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters

Grogg, Marcel; Hilvert, Donald; Beck, Albert K.; Seebach, Dieter:

Syntheses of Cyanophycin Segments for Investigations of Cell-Penetration

Image for article: Syntheses of Cyanophycin Segments for Investigations of Cell-Penetration

Murai, Masahito; Takai, Kazuhiko:

Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis

Image for article: Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis

Karageorgis, George; Waldmann, Herbert:

Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes

Image for article: Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes

Barrett, Anthony G. M.; Ma, Tsz-Kan; Mies, Thomas:

Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis

Image for article: Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis

Zhang, Heng; Lei, Aiwen:

Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H

Image for article: Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H

Piccardi, Riccardo; Turcaud, Serge; Benedetti, Erica; Micouin, Laurent:

Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents

Image for article: Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents

Kiefer, Alexander; Kazmaier, Uli:

Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis

Image for article: Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis

Wu, Xiang; Gong, Liu-Zhu:

Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective

Image for article: Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective

Yoshikai, Naohiko:

Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species

Image for article: Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species

Erb, William; Mongin, Florence:

Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations

Image for article: Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations

Lübken, Dennis; Saxarra, Marius; Kalesse, Markus:

Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications

Image for article: Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications

Barde, E.; Guérinot, A.; Cossy, J.:

α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions

Image for article: α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions

Kumagai, Naoya; Shibasaki, Masakatsu:

7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective C–C Bond-Forming Catalysis

Image for article: 7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective C–C Bond-Forming Catalysis

Stopka, Tobias; Adler, Pauline; Hagn, Gerhard; Zhang, Haoqi; Tona, Veronica; Maulide, Nuno:

Electrophilic Activation of Amides for the Preparation of Polysubstituted Pyrimidines

Image for article: Electrophilic Activation of Amides for the Preparation of Polysubstituted Pyrimidines

Supporting Information (PDF)

Bartlett, Samuel L.; Keiter, Kimberly M.; Zavesky, Blane P.; Johnson, Jeffrey S.:

Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones

Image for article: Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones

Supporting Information (PDF)

McCabe, Stephanie R.; Wipf, Peter:

Asymmetric Total Synthesis and Biological Evaluation of (+)-Cycloclavine

Image for article: Asymmetric Total Synthesis and Biological Evaluation of (+)-Cycloclavine

Supporting Information (PDF)

Endoma-Arias, Mary Ann A.; Makarova, Mariia; Dela Paz, Helen E.; Hudlicky, Tomas:

Chemoenzymatic Total Synthesis of (+)-Oxycodone from Phenethyl Acetate

Image for article: Chemoenzymatic Total Synthesis of (+)-Oxycodone from Phenethyl Acetate

Supporting Information (PDF)

Xue, Weichao; Oestreich, Martin:

Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

Image for article: Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution

Supporting Information (PDF)

Sato, Io; Yamashita, Yasuhiro; Kobayashi, Shū:

Alkylpotassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes

Image for article: Alkylpotassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes

Supporting Information (PDF)

Nitelet, Antoine; Kairouz, Vanessa; Lebel, Hélène; Charette, André B.; Evano, Gwilherm:

Continuous Flow Chlorination of Alkenyl Iodides Promoted by Copper Tubing

Image for article: Continuous Flow Chlorination of Alkenyl Iodides Promoted by Copper Tubing

Supporting Information (PDF)

Noguchi, Teppei; Nishii, Yuji; Miura, Masahiro:

Rhodium-Catalyzed Cascade Annulative Coupling of 3,5-Diarylisoxazoles with Alkynes

Image for article: Rhodium-Catalyzed Cascade Annulative Coupling of 3,5-Diarylisoxazoles with Alkynes

Supporting Information (PDF)

Wang, Han; Zhang, Duo; Cao, Mengwei; Bolm, Carsten:

Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents

Image for article: Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents

Supporting Information (PDF)

Gao, Wen-Chao; Xiong, Zi-Yue; Pirhaghani, Shafigh; Wirth, Thomas:

Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators

Image for article: Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators

Supporting Information (PDF)

Konstantinova, Olga V.; Koskinen, Ari M.P.:

Synthesis of the C1–C12 Fragment of Calyculin C

Image for article: Synthesis of the C1–C12 Fragment of Calyculin C

Supporting Information (PDF)

Bartolo, Nicole D.; Hornstein, Alana L.; Zhao, Annie Y.; Woerpel, K. A.:

Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration

Image for article: Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration

Supporting Information (PDF)

Krieck, Sven; Schüler, Philipp; Peschel, Jan M.; Westerhausen, Matthias:

Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method

Image for article: Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method

Supporting Information (PDF)

Stöckl, Yannick; Frey, Wolfgang; Lang, Johannes; Claasen, Birgit; Baro, Angelika; Laschat, Sabine:

Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst

Image for article: Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst

Supporting Information (PDF)

Schober, Lukas; Ratnam, Shahilan; Yamashita, Yasunobu; Adebar, Niklas; Pieper, Matthias; Berkessel, Albrecht; Hessel, Volker; Gröger, Harald:

An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode

Image for article: An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode

Gagosz, Fabien:

Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry

Image for article: Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry

Zard, Samir Z.:

Sulfur Betaines from S-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group

Image for article: Sulfur Betaines from <i>S</i>-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group

Baldauf, Simon; Bode, Jeffrey W.:

Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations

Image for article: Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations

Supporting Information (PDF)

Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R.; Mayr, Herbert:

Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?

Image for article: Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?

Supporting Information (PDF)

Crawford, Jennifer M.; Sigman, Matthew S.:

Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

Image for article: Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

Koeller, Julian; Gandeepan, Parthasarathy; Ackermann, Lutz:

Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature

Image for article: Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature

Supporting Information (PDF)

Karlinskii, Bogdan Ya.; Romashov, Leonid V.; Galkin, Konstantin I.; Kislitsyn, Pavel G.; Ananikov, Valentine P.:

Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block

Image for article: Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block

Supporting Information (PDF)

Ueda, Mitsuhiro; Maeda, Ayami; Hamaoka, Kanako; Sasano, Mika; Fukuyama, Takahide; Ryu, Ilhyong:

Bromine-Radical-Mediated Site-Selective Allylation of C(sp³)–H Bonds

Image for article: Bromine-Radical-Mediated Site-Selective Allylation of C(sp<sup>3</sup>)–H Bonds

Supporting Information (PDF)

Ferrer, Sofia; Echavarren, Antonio M.:

Synthesis of Bullvalenes: Classical Approaches and Recent Developments

Image for article: Synthesis of Bullvalenes: Classical Approaches and Recent Developments

McLellan, Ross; Uzelac, Marina; Bole, Leonie J.; Gil-Negrete, Jose María; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; Hevia, Eva:

Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH₂SiMe₃)₃ Metalation Reactions

Image for article: Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH<sub>2</sub>SiMe<sub>3</sub>)<sub>3</sub> Metalation Reactions

Supporting Information (PDF)

Hu, Fan; Ng, Jerome P. L.; Chiu, Pauline:

Pyrroles as Dienes in (4+3) Cycloadditions

Image for article: Pyrroles as Dienes in (4+3) Cycloadditions

Dohi, Toshifumi; Sasa, Hirotaka; Dochi, Mio; Yasui, Chihiro; Kita, Yasuyuki:

Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst

Image for article: Oxidative Coupling of <i>N</i>-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst

Lanza, Francesco; Pérez, Juana M.; Jumde, Ravindra P.; Harutyunyan, Syuzanna R.:

Lewis Acid Promoted Trapping of Chiral Aza-enolates

Image for article: Lewis Acid Promoted Trapping of Chiral Aza-enolates

Supporting Information (PDF)

Wiegand, Anja; Wiese, Vera; Glowacki, Britta; Iovkova, Ljuba; Schirrmacher, Ralf; Jurkschat, Klaus; Krause, Norbert:

GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for ¹⁸F-Positron Emission Tomography (PET)

Image for article: GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for <sup>18</sup>F-Positron Emission Tomography (PET)

Supporting Information (PDF)

Kurandina, Daria; Chuentragool, Padon; Gevorgyan, Vladimir:

Transition-Metal-Catalyzed Alkyl Heck-Type Reactions

Image for article: Transition-Metal-Catalyzed Alkyl Heck-Type Reactions

Sun, Alexandra C.; McAtee, Rory C.; McClain, Edward J.; Stephenson, Corey R. J.:

Advancements in Visible-Light-Enabled Radical C(sp)²–H Alkylation of (Hetero)arenes

Image for article: Advancements in Visible-Light-Enabled Radical C(sp)<sup>2</sup>–H Alkylation of (Hetero)arenes

Cecchini, Chiara; Lanzi, Matteo; Cera, Gianpiero; Malacria, Max; Maestri, Giovanni:

Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids

Image for article: Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids

Supporting Information (PDF)

Spránitz, Péter; Sőregi, Petra; Botlik, Bence Béla; Berta, Máté; Soós, Tibor:

Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation

Image for article: Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation

Matsuoka, Seiya; Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke:

General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual S_NAr Cyclizations of Aryl Fluorides

Image for article: General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual S<sub>N</sub>Ar Cyclizations of Aryl Fluorides

Supporting Information (PDF)

Groso, Emilia J.; Schindler, Corinna S.:

Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles

Image for article: Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles

Radtke, M. Alex; Dudley, Caroline C.; O’Leary, Jacob M.; Lambert, Tristan H.:

A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene

Image for article: A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene

Maraswami, Manikantha; Loh, Teck-Peng:

Transition-Metal-Catalyzed Alkenyl sp² C–H Activation: A Short Account

Image for article: Transition-Metal-Catalyzed Alkenyl sp<sup>2</sup> C–H Activation: A Short Account

Blank, Lena; Fagnoni, Maurizio; Protti, Stefano; Rueping, Magnus:

Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

Image for article: Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

Supporting Information (PDF)

Blieck, Rémi; Perego, Luca Alessandro; Ciofini, Ilaria; Grimaud, Laurence; Taillefer, Marc; Monnier, Florian:

Copper-Catalysed Hydroamination of N-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups

Image for article: Copper-Catalysed Hydroamination of <i>N</i>-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups

Supporting Information (PDF)