Synfacts
Issue 04 · April 2010
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Synform
A33
SYNFORM
ISSUE 2010/04
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Synthesis of Natural Products and Potential Drugs
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0375
Synthesis of (
E
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Z
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0376
Syntheses of (+)-Echinopine A and B
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0377
Synthesis of Eudesmane Terpenes by C-H Activation
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0378
Synthesis of SB-406725A
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0379
Synthesis of Arterolane and Analogues
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0380
Synthesis of Tamiflu
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0381
Asymmetric Synthesis of Palmerolide A
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0382
Syntheses of Isodomoic Acids G and H
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0383
Synthesis of (+)-Isatisine A
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0384
Synthesis of the Benzimidazole Fragment of BYK405879
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0385
Synthesis of PF-1247324, a Na
V
1.8 Sodium Channel Modulator
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0386
Syntheses of (-)-Renieramycin M and G and (-)-Jorumycin
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0387
Synthesis of (+)-Sertraline
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0388
Synthesis of (
S
)-(+)-Dapoxetine
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0389
Synthesis of (
R
)-Tolterodine
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0390
Synthesis of Iriomoteolide 3a
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0391
Syntheses of Isodomoic Acids G and H
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0392
Formal Synthesis of (+)-Erysotramidine
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0393
Synthesis of a TRPV1 Receptor Antagonist
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Synthesis of Heterocycles
z395
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0395
Gold-Catalyzed Synthesis of THFs and Pyrrolidines by Oxidative Coupling
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0396
Synthesis of C9-Functionalized Xanthenes and Acridines
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0397
Synthesis of Highly Substituted Furans from Alkynoates and 1,3-Dicarbonyls
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0398
Halo-Induced Heteroannulation Route to Quinolines
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0399
Copper-Catalyzed Synthesis of Pyrrolidines and Piperidines
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0400
Synthesis of 4-Aryl-4-trifluoromethyl-4
H
-1,3-oxa(thia)zines
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0401
Gold(I)-Catalyzed Hydroammoniumation and Methylamination of Alkynes to Indoles
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0402
Synthesis of Thiophenium Salts: A Trifluoromethylation Reagent
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0403
Synthesis of Substituted Quinolines from 2-Alkynylanilines
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0404
Enantioselective Synthesis of Lactone-[2,3-
b
]piperidines
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0405
Palladium-Catalyzed Synthesis of β-Lactams by Carbonylation of Vinyl Aziridines
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0406
Synthesis of Polysubstituted Pyrroles by Condensation of Acetylenes and Amines
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0407
Iodocyclization-Based Synthesis of Spiro Heterocycles
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0408
Palladium-Catalyzed C-N Coupling-Hydroamination Route to 4-Quinolones
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Synthesis of Materials and Unnatural Products
z409
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0409
A Twisted Perylene Semiconductor
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0410
Co(III) Operation Makes it Happen
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0411
Helicene and Double Helicene
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0412
Pyridyl Annelated Perylene Bisimides
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0413
Nine in a Row
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0414
Polyaromatic Oligomers
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0415
Thienothiophene-Based Organic Sensitizers
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0416
Fluoride-Induced Formation of Triphenylene Chemodosimeter
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0417
Fluorophore-Appended Resorcin[4]arene Cavitands
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0418
Planarized Cyclooctatetraenes
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0419
Versatile Monomers for Conjugated Polymer Synthesis
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0420
A Novel n-Type PPV
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0421
Concise Cycloparaphenylene Synthesis
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0422
Copper-Catalyzed Domino Formation of (Alkynyl)bromoarenes
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0423
Polyacenes from the Cyclotrimerization of Alkynes
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z425
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0425
Asymmetric Kumada Couplings of α-Bromo Ketones
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0426
Nickel-Catalyzed Denitrogenative Annulation
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0427
Allylation of N-Heteroaryl Hydrazones
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0428
Diastereoselective Negishi Coupling of Cycloalkylzinc Reagents
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0429
Asymmetric Synthesis of β-Aryloxy Alcohols via Dynamic Kinetic Resolution
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0430
Synthesis of Chiral Pyridones by Palladium-Catalyzed Rearrangement
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0431
Rhodium-Catalyzed Enantioselective Hydroamination of Alkenes
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0432
Synthesis of Chiral Silacarboxylic Acids and Esters
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0433
Copper-Catalyzed Asymmetric C-H Insertion of α-Diazosulfones
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0434
Asymmetric Conjugate Addition of Acetylene Nucleophiles
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0435
Catalytic Asymmetric Cycloaddition of Allene-Dienes
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0436
Metal-Catalyzed Ring-Opening Hydro-metalation of Alkylidenecyclopropanes
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0437
Metal-Controlled Reversal of Enantio-selectivity in the Alkylation of Indoles
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0438
Nickel-Catalyzed Reaction of Norbornene with Two Alkynes
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0439
Copper-Catalyzed Asymmetric Mono-borylation of 1,3-Dienes
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0440
Gold-Catalyzed Intramolecular Hydroamination and Hydroalkoxylation
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0441
Zn(II) Complexes Catalyzed Asymmetric Friedel-Crafts Alkylation of Pyrroles
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0442
Enantioselective Allylic Etherification Using a Novel COP Catalyst
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0443
Preparation of Chiral-Bridged Dienes - Ligands for Enantioselective Catalysis
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0444
Copper(I)-Catalyzed Desymmetrization of
meso
-2-Alkene-1,4-diol Derivatives
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0445
Asymmetric Direct Mannich-Type Reaction Catalyzed by Chiral Lithium Complexes
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0446
Synthesis of Chiral Benzoazepines through Allylic Substitution
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0447
Rhodium-Catalyzed Asymmetric Reductive Cyclization of Alkynals
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0448
Asymmetric Hydrophosphonylation of Aldehydes
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0449
Asymmetric Addition of Aromatic Nucleophiles to Isatins
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0450
Chiral Phosphate Counteranion Directed Enantioselective Expoxidation
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0451
Pyrrolidine Synthesis from Copper-Catalyzed 1,3-Dipolar Cycloadditions
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0452
Ruthenium-Catalyzed Asymmetric Allylic Substitution with Metal Carboxylates
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0453
Stereochemistry of the Prins-Pinacol Rearrangement
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0454
Iridium-Catalyzed Allylic Substitution with Aromatic and Aliphatic Sulfinates
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Metal-Mediated Synthesis
z455
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0455
Diaryl Sulfates as Electrophiles in Kumada Cross-Coupling Reactions
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0456
Manganese(III)-Mediated Biaryl Synthesis
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0457
Nickel-Catalyzed Reductive Cross-Coupling of Aryl Halides with Alkyl Halides
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0458
Palladium-Catalyzed Carbonylation/Acyl Migratory Insertion Sequence
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0459
Decarboxylative Coupling of Aryl Tosylates with Aromatic Carboxylate Salts
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0460
1,3-Diketone Synthesis via a Novel Tandem Reaction
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0461
Decarboxylative Benzylation of Diphenyl-glycinate Imines
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0462
Stereoselective Reduction of Alkynes to
cis
- and
trans
-Alkenes Using Pd/HSiEt
3
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0463
Tandem One-Pot Diels-Alder/Cross-Coupling Reactions of Organoindium Reagents
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0464
Re- and Mn-Catalyzed Formal Cycloaddition of 1,3-Dicarbonyl Compounds and Alkynes
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0465
Domino Palladium-Catalyzed Generation and Arylation of Sulfenate Anions
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0466
Decarboxylative Coupling of Cinnamic Acids with Vinyl Bromides
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0467
Simple and Selective Deprotection of MOM Ethers
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0468
Palladium-Catalyzed Copper-Free Wacker Oxidation of Internal Olefins
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0469
A New Ligand for Copper-Catalyzed Cross-Coupling of Heterocycles and Phenols
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Organo- and Biocatalysis
z471
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0471
A Biocatalytic Equivalent to the Nef Reaction
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0472
Trisimidazolines in Asymmetric Conjugate Additions
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0473
Enantioselective Transfer Hydrogenation of Quinoxalines and Quinoxalinones
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0474
Iminium-Allenamine Cascade
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0475
Vinylogous Aldol Reaction of Furanones
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0476
Benzoheterocycle Synthesis via Diphosphine Catalysis
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0477
α-Chlorination of β-Keto Esters Catalyzed by a Bifunctional
N
-Oxide/Amide Catalyst
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0478
Asymmetric Additions to α,β-Unsaturated Acyl Phosphonates
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0479
Catalytic Enantioselective Synthesis of Cyclic α-Amino Acids
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0480
Phase-Transfer-Catalyzed Intramolecular Cyclization of Phenyl Ether Derivatives
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0481
3-Halopropenals as β-Acylvinyl Anion Equivalents
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0482
Michael Addition Catalyzed by Chiral Bifunctional Thioureas Based on Saccharides
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0483
Hydrogen-Bonding Catalysts are Hard to Predict
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0484
Chiral Base-Catalyzed Reductive Aldol Reaction with Trichlorosilane
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0485
Formal [4+2] Cycloadditions Promoted by a Chiral Amine Urea Catalyst
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Polymer-Supported Synthesis
z487
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0487
A Mesoporous Silica-Supported Ruthenium Catalyst for Metathesis
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0488
Synthesis of Propargyl Amines with Ni-Y Zeolite
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0489
Solid-Phase Synthesis of Peptide Alcohols
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0490
Solid-Phase Synthesis of NOTA-Functionalized Peptides
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0491
Epoxidation of Styrene with Au
25
Clusters Grafted on Hydroxyapatite
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0492
Reduction of Nitroarenes with Hydrogen Transfer Catalysis
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0493
N-Arylation of Amides with Cu
2
O Nano-particles
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0494
Cross-Coupling of Aryl Halides and Triarylbismuths with PS-Supported Palladium
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0495
Dihydroxylation of Olefins with a Dendrimer-Supported Osmium Catalyst
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0496
Gold Nanoclusters as a Catalyst for Intramolecular Hydroamination
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0497
Polymer-Supported Synthesis of Stilbenes
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0498
Copper-Free Sonogashira Coupling in Water with a PS-PEG Palladium Complex
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0499
Synthesis of Tetrazoles with Mesoporous ZnS Nanospheres
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Addenda and Errata
0500
Synthesis of Englerin A
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