Synthesis
Issue 01 · January 2019
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Paul, Knochel:
50 Years SYNTHESIS – Golden Anniversary Issue
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Zanda, Matteo:
SYNFORM
ISSUE 2019/1
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Trost, Barry M.; Schultz, Johnathan E.:
Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters
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31
Grogg, Marcel; Hilvert, Donald; Beck, Albert K.; Seebach, Dieter:
Syntheses of Cyanophycin Segments for Investigations of Cell-Penetration
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40
Murai, Masahito; Takai, Kazuhiko:
Unsymmetrical Difunctionalization of Two Different C–H Bonds in One Pot Under Transition-Metal Catalysis
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55
Karageorgis, George; Waldmann, Herbert:
Guided by Evolution: Biology-Oriented Synthesis of Bioactive Compound Classes
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67
Barrett, Anthony G. M.; Ma, Tsz-Kan; Mies, Thomas:
Recent Developments in Polyene Cyclizations and Their Applications in Natural Product Synthesis
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83
Zhang, Heng; Lei, Aiwen:
Electrochemical/Photochemical Aminations Based on Oxidative Cross-Coupling between C–H and N–H
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97
Piccardi, Riccardo; Turcaud, Serge; Benedetti, Erica; Micouin, Laurent:
Synthesis and Reactivity of Mixed Dimethylalkynylaluminum Reagents
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107
Kiefer, Alexander; Kazmaier, Uli:
Syntheses of Cyclomarins – Interesting Marine Natural Products with Distinct Mode of Action towards Malaria and Tuberculosis
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122
Wu, Xiang; Gong, Liu-Zhu:
Palladium(0)-Catalyzed Difunctionalization of 1,3-Dienes: From Racemic to Enantioselective
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135
Yoshikai, Naohiko:
Recent Advances in Enantioselective C–C Bond Formation via Organocobalt Species
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146
Erb, William; Mongin, Florence:
Twofold Ferrocene C–H Lithiations For One-Step Difunctionalizations
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161
Lübken, Dennis; Saxarra, Marius; Kalesse, Markus:
Tris(acetylacetonato) Iron(III): Recent Developments and Synthetic Applications
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178
Barde, E.; Guérinot, A.; Cossy, J.:
α-Arylation of Amides from α-Halo Amides Using Metal-Catalyzed Cross-Coupling Reactions
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185
Kumagai, Naoya; Shibasaki, Masakatsu:
7-Azaindoline Auxiliary: A Versatile Attachment Facilitating Enantioselective C–C Bond-Forming Catalysis
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feature
194
Stopka, Tobias; Adler, Pauline; Hagn, Gerhard; Zhang, Haoqi; Tona, Veronica; Maulide, Nuno:
Electrophilic Activation of Amides for the Preparation of Polysubstituted Pyrimidines
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Supplementary Material
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203
Bartlett, Samuel L.; Keiter, Kimberly M.; Zavesky, Blane P.; Johnson, Jeffrey S.:
Formation of Complex α-Imino Esters via Multihetero-Cope Rearrangement of α-Keto Ester Derived Nitrones
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213
McCabe, Stephanie R.; Wipf, Peter:
Asymmetric Total Synthesis and Biological Evaluation of (+)-Cycloclavine
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225
Endoma-Arias, Mary Ann A.; Makarova, Mariia; Dela Paz, Helen E.; Hudlicky, Tomas:
Chemoenzymatic Total Synthesis of (+)-Oxycodone from Phenethyl Acetate
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233
Xue, Weichao; Oestreich, Martin:
Silicon Grignard Reagents as Nucleophiles in Transition-Metal-Catalyzed Allylic Substitution
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240
Sato, Io; Yamashita, Yasuhiro; Kobayashi, Shū:
Alkylpotassium-Catalyzed Benzylic C–H Alkylation of Alkylarenes with Alkenes
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251
Nitelet, Antoine; Kairouz, Vanessa; Lebel, Hélène; Charette, André B.; Evano, Gwilherm:
Continuous Flow Chlorination of Alkenyl Iodides Promoted by Copper Tubing
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258
Noguchi, Teppei; Nishii, Yuji; Miura, Masahiro:
Rhodium-Catalyzed Cascade Annulative Coupling of 3,5-Diarylisoxazoles with Alkynes
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271
Wang, Han; Zhang, Duo; Cao, Mengwei; Bolm, Carsten:
Electrophilic Sulfoximidations of Thiols by Hypervalent Iodine Reagents
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276
Gao, Wen-Chao; Xiong, Zi-Yue; Pirhaghani, Shafigh; Wirth, Thomas:
Enantioselective Electrochemical Lactonization Using Chiral Iodoarenes as Mediators
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285
Konstantinova, Olga V.; Koskinen, Ari M.P.:
Synthesis of the C1–C12 Fragment of Calyculin C
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Bartolo, Nicole D.; Hornstein, Alana L.; Zhao, Annie Y.; Woerpel, K. A.:
Diastereoselectivities in Reductions of α-Alkoxy Ketones Are Not Always Correlated to Chelation-Induced Rate Acceleration
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