DOI: 10.1055/s-00000084

Synthesis

Issue 05 · Volume 51 · March 2019 DOI: 10.1055/s-009-42516

table of contents

  • V

    Linked PDF of Table of Contents

    • editorial

  • XV

    50 Years SYNTHESIS – Golden Anniversary Issue Part II

    • Synform

  • A31
    Zanda, Matteo:

    SYNFORM ISSUE 2019/3

    • review

  • 985
    Kurandina, Daria; Chuentragool, Padon; Gevorgyan, Vladimir:

    Transition-Metal-Catalyzed Alkyl Heck-Type Reactions

    Image for article: Transition-Metal-Catalyzed Alkyl Heck-Type Reactions
    Open Access

    • short review

  • 1006
    Zard, Samir Z.:

    Sulfur Betaines from S-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group

    Image for article: Sulfur Betaines from <i>S</i>-Propargyl Xanthates. Unusual Chemistry from a Simple Functional Group
    Open Access
  • 1021
    Crawford, Jennifer M.; Sigman, Matthew S.:

    Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?

    Image for article: Conformational Dynamics in Asymmetric Catalysis: Is Catalyst Flexibility a Design Element?
    Open Access
  • 1037
    Ferrer, Sofia; Echavarren, Antonio M.:

    Synthesis of Bullvalenes: Classical Approaches and Recent Developments

    Image for article: Synthesis of Bullvalenes: Classical Approaches and Recent Developments
    Open Access
  • 1049
    Maraswami, Manikantha; Loh, Teck-Peng:

    Transition-Metal-Catalyzed Alkenyl sp2 C–H Activation: A Short Account

    Image for article: Transition-Metal-Catalyzed Alkenyl sp<sup>2</sup> C–H Activation: A Short Account
    Open Access
  • 1063
    Sun, Alexandra C.; McAtee, Rory C.; McClain, Edward J.; Stephenson, Corey R. J.:

    Advancements in Visible-Light-Enabled Radical C(sp)2–H Alkylation of (Hetero)arenes

    Image for article: Advancements in Visible-Light-Enabled Radical C(sp)<sup>2</sup>–H Alkylation of (Hetero)arenes
    Open Access
  • 1073
    Hu, Fan; Ng, Jerome P. L.; Chiu, Pauline:

    Pyrroles as Dienes in (4+3) Cycloadditions

    Image for article: Pyrroles as Dienes in (4+3) Cycloadditions
    Open Access
  • 1087
    Gagosz, Fabien:

    Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry

    Image for article: Gold Vinylidenes as Useful Intermediates in Synthetic Organic Chemistry
    Open Access
  • 1100
    Groso, Emilia J.; Schindler, Corinna S.:

    Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles

    Image for article: Recent Advances in the Application of Ring-Closing Metathesis for the Synthesis of Unsaturated Nitrogen Heterocycles
    Open Access

    • feature

  • 1115
    Krieck, Sven; Schüler, Philipp; Peschel, Jan M.; Westerhausen, Matthias:

    Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method

    Image for article: Straightforward One-Pot Syntheses of Silylamides of Magnesium and Calcium via an In Situ Grignard Metalation Method
    Open Access
    Supporting Information (PDF)
  • 1123
    Stöckl, Yannick; Frey, Wolfgang; Lang, Johannes; Claasen, Birgit; Baro, Angelika; Laschat, Sabine:

    Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst

    Image for article: Asymmetric Organocatalysis Revisited: Taming Hydrindanes with Jørgensen–Hayashi Catalyst
    Open Access
    Supporting Information (PDF)
  • 1135
    Radtke, M. Alex; Dudley, Caroline C.; O’Leary, Jacob M.; Lambert, Tristan H.:

    A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene

    Image for article: A Scalable, One-Pot Synthesis of 1,2,3,4,5-Pentacarbomethoxycyclopentadiene
    Open Access
  • 1139
    Matsuoka, Seiya; Nakamura, Kayo; Ohmori, Ken; Suzuki, Keisuke:

    General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual SNAr Cyclizations of Aryl Fluorides

    Image for article: General Synthetic Approach to Rotenoids via Stereospecific, Group-Selective 1,2-Rearrangement and Dual S<sub>N</sub>Ar Cyclizations of Aryl Fluorides
    Open Access
    Supporting Information (PDF)
  • 1157
    Leonov, Artem I.; Timofeeva, Daria S.; Ofial, Armin R.; Mayr, Herbert:

    Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?

    Image for article: Metal Enolates – Enamines – Enol Ethers: How Do Enolate Equivalents Differ in Nucleophilic Reactivity?
    Open Access
    Supporting Information (PDF)
  • 1171
    Ueda, Mitsuhiro; Maeda, Ayami; Hamaoka, Kanako; Sasano, Mika; Fukuyama, Takahide; Ryu, Ilhyong:

    Bromine-Radical-Mediated Site-Selective Allylation of C(sp3)–H Bonds

    Image for article: Bromine-Radical-Mediated Site-Selective Allylation of C(sp<sup>3</sup>)–H Bonds
    Open Access
    Supporting Information (PDF)
  • 1178
    Schober, Lukas; Ratnam, Shahilan; Yamashita, Yasunobu; Adebar, Niklas; Pieper, Matthias; Berkessel, Albrecht; Hessel, Volker; Gröger, Harald:

    An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode

    Image for article: An Asymmetric Organocatalytic Aldol Reaction of a Hydrophobic Aldehyde in Aqueous Medium Running in Flow Mode
    Open Access
  • 1185
    Dohi, Toshifumi; Sasa, Hirotaka; Dochi, Mio; Yasui, Chihiro; Kita, Yasuyuki:

    Oxidative Coupling of N-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst

    Image for article: Oxidative Coupling of <i>N</i>-Methoxyamides and Related Compounds toward Aromatic Hydrocarbons by Designer μ-Oxo Hypervalent Iodine Catalyst
    Open Access
  • 1196
    Wiegand, Anja; Wiese, Vera; Glowacki, Britta; Iovkova, Ljuba; Schirrmacher, Ralf; Jurkschat, Klaus; Krause, Norbert:

    GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for 18F-Positron Emission Tomography (PET)

    Image for article: GlucoSiFA and LactoSiFA: New Types of Carbohydrate-Tagged Silicon-Based Fluoride Acceptors for <sup>18</sup>F-Positron Emission Tomography (PET)
    Open Access
    Supporting Information (PDF)
  • 1207
    McLellan, Ross; Uzelac, Marina; Bole, Leonie J.; Gil-Negrete, Jose María; Armstrong, David R.; Kennedy, Alan R.; Mulvey, Robert E.; Hevia, Eva:

    Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH2SiMe3)3 Meta­lation Reactions

    Image for article: Alkali Metal Effects in Trans-Metal-Trapping (TMT): Comparing LiTMP with NaTMP in Cooperative MTMP/Ga(CH<sub>2</sub>SiMe<sub>3</sub>)<sub>3</sub> Meta­lation Reactions
    Open Access
    Supporting Information (PDF)
  • 1216
    Cecchini, Chiara; Lanzi, Matteo; Cera, Gianpiero; Malacria, Max; Maestri, Giovanni:

    Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids

    Image for article: Complementary Reactivity of 1,6-Enynes with All-Metal Aromatic Trinuclear Complexes and Carboxylic Acids
    Open Access
    Supporting Information (PDF)

    • paper

  • 1225
    Blieck, Rémi; Perego, Luca Alessandro; Ciofini, Ilaria; Grimaud, Laurence; Taillefer, Marc; Monnier, Florian:

    Copper-Catalysed Hydroamination of N-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups

    Image for article: Copper-Catalysed Hydroamination of <i>N</i>-Allenylsulfonamides: The Key Role of Ancillary Coordinating Groups
    Open Access
    Supporting Information (PDF)
  • 1235
    Karlinskii, Bogdan Ya.; Romashov, Leonid V.; Galkin, Konstantin I.; Kislitsyn, Pavel G.; Ananikov, Valentine P.:

    Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block

    Image for article: Synthesis of 2-Azidomethyl-5-ethynylfuran: A New Bio-Derived Self-Clickable Building Block
    Open Access
    Supporting Information (PDF)
  • 1243
    Blank, Lena; Fagnoni, Maurizio; Protti, Stefano; Rueping, Magnus:

    Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions

    Image for article: Visible Light-Promoted Formation of C–B and C–S Bonds under Metal- and Photocatalyst-Free Conditions
    Open Access
    Supporting Information (PDF)
  • 1253
    Lanza, Francesco; Pérez, Juana M.; Jumde, Ravindra P.; Harutyunyan, Syuzanna R.:

    Lewis Acid Promoted Trapping of Chiral Aza-enolates

    Image for article: Lewis Acid Promoted Trapping of Chiral Aza-enolates
    Open Access
    Supporting Information (PDF)
  • 1263
    Spránitz, Péter; Sőregi, Petra; Botlik, Bence Béla; Berta, Máté; Soós, Tibor:

    Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation

    Image for article: Organocatalytic Desymmetrisation of Fittig’s Lactones: Deuterium as a Reporter Tag for Hidden Racemisation
    Open Access
  • 1273
    Baldauf, Simon; Bode, Jeffrey W.:

    Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations

    Image for article: Synthesis and Evaluation of Cyclic Acetals of Serine Hydroxylamine for Amide-Forming KAHA Ligations
    Open Access
    Supporting Information (PDF)
  • 1284
    Koeller, Julian; Gandeepan, Parthasarathy; Ackermann, Lutz:

    Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature

    Image for article: Visible-Light-Induced Decarboxylative C–H Adamantylation of Azoles at Ambient Temperature
    Open Access
    Supporting Information (PDF)