Synfacts
Issue 05 · May 2010
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SYNFORM
ISSUE 2010/05
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Synthesis of Natural Products and Potential Drugs
z501
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0501
Synthesis of Palau’amine
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0502
Synthesis of a Botulinum Protease Inhibitor
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0503
Synthesis of Montelukast
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0504
Synthesis of Polyrhacitides A and B
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0505
Synthesis of (-)-Lycoperine A
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0506
Synthesis of (
R
)-Olodaterol
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0507
Synthesis of Nankakurines A and B via Luciduline
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0508
Synthesis of a Cathepsin S Inhibitor
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0509
Synthesis of Iso- and Bongkrekic Acids
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0510
Synthesis of
ent
-Hyperforin
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0511
Synthesis of (-)-Mersicarpine
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0512
Synthesis of a BACE-1 Inhibitor
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0513
Synthesis of BMS-561392
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Synthesis of Heterocycles
z515
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0515
Copper-Catalyzed Synthesis of Triazolyl-α-CF
3
-α-Aminophosphonates
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0516
Silver-Catalyzed Heteroannulation Route to Indoles
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0517
Zinc Halide Mediated Synthesis of 3-Amidoindoles
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0518
Rhodium-Catalyzed Carbonylative Addition-Cyclization Approach to Furans
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0519
Synthesis of 1,2-Benzisoxazoles by 1,3-Dipolar Cycloaddition
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0520
One-Pot Synthesis of Benzisothiazoles from
ortho
-Mercaptoacylphenones
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0521
Pyrrolo[2,3-
b
]quinolines via a Rhodium-Catalyzed Pauson-Khand-Type Reaction
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0522
Triazolopyridines via Selective Palladium-Catalyzed Monoarylation of Hydrazides
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0523
Palladium-Catalyzed Synthesis of Five-Membered Heterocycles from 1,6-Enynes
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0524
Silver-Mediated Synthesis of Furo[3,2-
b
]-β/γ-Lactams
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0525
Ligand-Free Cyclocarbonylation of
ortho
-Iodophenols and Acetylenes to Chromones
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0526
Palladium-Catalyzed Synthesis of Pyrrolo-Fused Compounds from Nitroarenes
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0527
Tandem Conjugate Addition-Cyclization Synthesis of 1,5-Benzodiazepines
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0528
Copper/
l
-Proline-Catalyzed Synthesis of Phenothiazines
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Synthesis of Materials and Unnatural Products
z529
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0529
Conformation Switching
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0530
Stable Triplet TMM Diradical
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0531
Phenanthroline-Porphyrin Hybrid as a Fluorescence Sensor for Magnesium(II)
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0532
Decarboxylative Cross-Coupling
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0533
Self-Entangling in a [1]Rotaxane
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0534
Switchable Electrochromic Polymers
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0535
Radical Corannulene
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0536
Furan Oligomers
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0537
1,2-Diborylation of Arynes
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0538
Self-Assembled Cryptands with Sulfur-Phosphorus Bonds
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0539
New Heteroarene Cores for Organic Semiconductors
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0540
Alleno-Acetylenic Oligomers
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0541
High Molecular Weight Polypyrene
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0542
Reversible Conversion between Linear and Cross-Linked Supramolecular Polymers
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0543
Active Material and Photoresist in One Novel Polymer
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z545
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0545
Stereospecific Suzuki Cross-Coupling
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0546
Asymmetric Hydroboration of Trisubstituted Alkenes
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0547
Asymmetric Hydrogenation of N-Protected Indoles Catalyzed by Iridium Complexes
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0548
Calcium-PyBox Catalyzed Asymmetric Mannich Reaction of Imines
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0549
Kinetic Resolution of Alcohols Through Si-O Coupling
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0550
Gold-Catalyzed Cascade Reaction of Tethered Nitrone-Propargyl Alcohols
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0551
Diastereoselective Zinc-Catalyzed Propargylation of Chiral Imines
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0552
Expedient Total Synthesis of Kinamycin F
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0553
Asymmetric Dieckmann-Type Annulation
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0554
Iridium-Catalyzed Asymmetric Hydrogenation of Benzophenone N-H Imines
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0555
Rhodium-Catalyzed Asymmetric Cycloisomerization of 1,6-Enynes
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0556
Copper-Catalyzed Stereoselective Ring Expansion of Vinyl Oxiranes
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0557
Synthesis of Vinyl Sulfones by Isomerization of Allyl Sulfinates
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0558
Synthesis of Enantioenriched Allenes from 1,1-Cyclopropanediesters
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0559
Enantioselective Synthesis of Malhamensilipin A
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0560
Reverse Regioselectivity in Amino-halogenation of Electron-Deficient Olefins
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0561
Indium(I)-Catalyzed Allylation and Crotylation of Imines
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0562
Rhodium-Catalyzed [5+2] Cycloaddition-Nazarov Cyclization Strategy
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0563
Asymmetric Oxazaborolidine-Catalyzed Diels-Alder Reaction of Maleimides
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0564
Chiral Cycloalkenes by an Asymmetric Allylic Alkylation-RCM Procedure
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0565
Ruthenium-Catalyzed Oxidative Cylization of 5,6-Dihydroxy Alkenes
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0566
Ru-Catalyzed Dynamic Kinetic Resolution of β-Keto Amides via Transfer Hydrogenation
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0567
Rh-Catalyzed Regio- and Diastereoselective Hydroformylation of Bishomoallylic Alcohols
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0568
Multicomponent Asymmetric Synthesis of γ-Hydroxy Ketones
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0569
Enantioselective Synthesis of Substituted Indanones
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0570
Rhodium-Catalyzed Asymmetric Cyclopropanation via Azavinyl Carbenoids
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0571
Iridium-Catalyzed Asymmetric Alkoxy-allylation of Aldehydes
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0572
Diastereoselective Hydrogenation of Substituted Quinolines
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0573
Synthesis of Tertiary Allylic Ethers by Gold(I) Catalysis
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Metal-Mediated Synthesis
z575
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0575
Pd-PEPPSI-IPent as Catalyst for the Synthesis of Highly Congested Biaryls
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0576
Direct Conversion of Aryl Amines to Pinacol Boronates
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0577
Zinc(II)-Catalyzed Chemoselective Reduction of Amides to Amines
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0578
Palladium-Catalyzed Intermolecular Addition of Formamides to Alkynes
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0579
Iron(II)-Catalyzed Radical Arylation of Arenes with Aryl and Heteroaryl Iodides
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0580
A General Catalyst System for Amination of Aryl Chlorides
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0581
Oxidative C-H/C-H Cross-Coupling of Heteroarenes
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0582
Bromine-Lithium Exchange on Cyano-Substituted Arenes Using Microreactors
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0583
Rhodium-Catalyzed Dehydrogenative Borylation of Cyclic Alkenes
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0584
Allyl Vinyl Ethers by Copper-Promoted Coupling of Vinyl Boronates to Alcohols
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0585
A New Phosphate Zinc Carbenoid
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0586
Iridium-Catalyzed Amine Alkylation with Alcohols in Water
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0587
Iridium-Catalyzed
ortho
-Borylation of Benzoate Esters with Bis(pinacolato)diboron
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0588
Simple Copper Chloride Catalyzed Arylation of Amines and Pyrrole in Water
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0589
Dehydrative Pd/Cu-Catalyzed Coupling of Heterocycles with Terminal Alkynes
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Organo- and Biocatalysis
z591
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0591
Asymmetric Synthesis of α-Halo Carboxylic Acids from α,α-Dihalo Aldehydes
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0592
Sulfa-Michael Addition Catalyzed by a Quinine-Derived Urea Catalyst
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0593
Enzyme-Catalyzed Carboligations by Thiamine Diphosphate Dependent YerE
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0594
Enantioselective Steglich Esterification for the Resolution of 1,2-Diols
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0595
Aza-Morita-Baylis-Hillman Reaction Using Aliphatic Imine Precursors
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0596
Desymmetrization of
meso
-Pyrrolidines via Biocatalytic C-H Oxidation
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0597
Organocatalytic Enantioselective Chlorolactonization
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0598
A Hydrogen Bonding Catalyzed Asymmetric Cascade to Tetrahydrocarbazoles
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0599
An Ionic Network as Catalyst for Asymmetric Benzylation
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0600
Synthesis of Amines Using Aminoalkane Surrogates
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0601
Asymmetric Povarov Reactions Cobalt-Catalyzed by Chiral Ureas/Achiral Acids
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0602
Kita’s Oxidative Spirolactonization Catalyzed by a Hypervalent Iodine(III) Species
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0603
NHC-Catalyzed Cycloaddition of Ketenes and 9,10-Phenanthrenequinone
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0604
Kinetic Resolution of Thioformamides
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Polymer-Supported Synthesis
z605
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0605
A Chiral Ionene for Asymmetric Benzylation
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0606
Solid-Phase Synthesis of Thiazolo[4,5-
b
]-pyridines
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0607
Graphene-Coated Cobalt Nanoparticles-Supported Palladium Catalyst
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0608
Buchwald-Hartwig Reaction with Amphiphilic Resin-Supported Palladium
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0609
Controlled Hydrogenation of ArNO
2
Using Carbon-Supported Platinum Colloid
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0610
Photocatalytic Synthesis of Benzimidazoles on Pt@TiO
2
Nanoparticles
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0611
One-Pot Reaction with Bifunctional Mesoporous Organosilicas
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0612
Oxidant-Free Dehydrogenation of Alcohols with Au/HT
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0613
Three-Component Strecker-Type Reaction with Al-MCM-41
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0614
Pd-SiO
2
@Fe
3
O
4
: A Catalyst for Cross-Coupling of Aryl Chlorides
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0615
Suzuki-Miyaura Coupling with Palladium(II) Phosphine Complexes on MNPs
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0616
Polymer-Supported Chiral Organocatalysts for Diels-Alder Reaction
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0617
Palladium Cross-Linked Crystal-Catalyzed Knoevenagel Reaction-Cyclization
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Addenda and Errata
0618
Asymmetric Addition of Deactivated Grignard Reagents to Aldehydes
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0618
Poly-Chirality
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