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Editorial

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A90

Zanda, Matteo:

SYNFORM ISSUE 2015/07

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1427

Bour, Christophe; Gandon, Vincent:

New Procedures for Catalytic Carbophilic Activation by Gold and Gallium π-Acids

1437

Astruc, Didier; Ciganda, Roberto; Deraedt, Christophe; Gatard, Sylvain; Liang, Liyuan; Li, Na; Ornelas, Catia; Rapakousiou, Amalia; Ruiz, Jaime; Wang, Dong; Wang, Yanlan; Zhao, Pengxiang:

Click Metallodendrimers and Their Functions

1450

Krauße, Nico; Butenschön, Holger:

New Phenoxy[4]ferrocenophanedienes: First Case of a Boat Conformation of a Diazacyclohexene 1,4-Capped by a Ferrocene

Supporting Information (PDF)

1455

Hurst, Timothy E.; Kitching, Matthew O.; da Frota, Lívia C. R. M.; Guimarães, Keller G.; Dalziel, Michael E.; Snieckus, Victor:

Metal-Free Synthesis of Dibenzoxazepinones via a One-Pot S_NAr and Smiles Rearrangement Process: Orthogonality with Copper-Catalyzed Cyclizations

Image for article: Metal-Free Synthesis of Dibenzoxazepinones via a One-Pot S<sub>N</sub>Ar and Smiles Rearrangement Process: Orthogonality with Copper-Catalyzed Cyclizations

Supporting Information (PDF)

1461

Li, Zhiqiang; Li, Qingjiang; Liu, Guo-Kai; Chen, Weimin; Peng, Xiao-Shui; Wong, Henry N. C.:

Gold(I)-Catalyzed Domino Cyclization for the Synthesis of Tricyclic Chromones

Supporting Information (PDF)

1465

Ni, Qijian; Xiong, Jiawen; Song, Xiaoxiao; Raabe, Gerhard; Enders, Dieter:

N-Heterocyclic Carbene Catalyzed Enantioselective Annulation of Benzothiazolyl Ethyl Acetates with 2-Bromoenals

Supporting Information (PDF)

1470

Hafner, Andreas; Ley, Steven V.:

Generation of Reactive Ketenes under Flow Conditions through Zinc-Mediated Dehalogenation

Supporting Information (PDF)

1475

Osako, Takao; Uozumi, Yasuhiro:

Mechanistic Insights into Copper-Catalyzed Azide–Alkyne Cycloaddition (CuAAC): Observation of Asymmetric Amplification

1480

Hylland, Knut T.; Øien-Ødegaard, Sigurd; Lillerud, Karl Petter; Tilset, Mats:

Efficient, Scalable Syntheses of Linker Molecules for Metal-Organic Frameworks

Supporting Information (PDF)

1486

Dash, Jyotirmayee; Trawny, Daniel; Rabe, Jürgen P.; Reissig, Hans-Ulrich:

C₃-Symmetric Pyridine and Bipyridine Derivatives: Simple Preparation by Cyclocondensation and 2D Self-Assembly at a Solution–Graphite Interface

Image for article: C<sub>3</sub>-Symmetric Pyridine and Bipyridine Derivatives: Simple Preparation by Cyclocondensation and 2D Self-Assembly at a Solution–Graphite Interface

Supporting Information (PDF)

1490

Ye, Baihua; Cramer, Nicolai:

Chiral Cyclopentadienyl Ligands Enable a Rhodium(III)-Catalyzed Enantioselective Access to Hydroxychromanes and Phthalides

Image for article: Chiral Cyclopentadienyl Ligands Enable a Rhodium(III)-Catalyzed Enantioselective Access to Hydroxychromanes and Phthalides

Supporting Information (PDF)

1496

Tanaka, Shota; Ashida, Kana; Tatsuta, Go; Mori, Atsunori:

Preparation of Fluorescent Materials from Biomass-Derived Furfural and Natural Amino Acid Cysteine through Cross-Coupling Reactions for Extended π-Conjugation

Image for article: Preparation of Fluorescent Materials from Biomass-Derived Furfural and Natural Amino Acid Cysteine through Cross-Coupling Reactions for Extended π-Conjugation

Supporting Information (PDF)

1501

Lennartson, Anders; Quant, Maria; Moth-Poulsen, Kasper:

A Convenient Route to 2-Bromo-3-chloronorbornadiene and 2,3-Dibromonorbornadiene

1505

Mayer, Camilla; Romek, Alexandra; Bach, Thorsten:

Synthesis of (+)-Methyl Dihydropalustramate and of the Pyrido[1,2-a]azepine Core of Stemona Alkaloids

Image for article: Synthesis of (+)-Methyl Dihydropalustramate and of the Pyrido[1,2-<i>a</i>]azepine Core of <i>Stemona</i> Alkaloids

Supporting Information (PDF) Primary Data (ZIP)

1510

Bai, Da-Chang; Wang, Wan-Ying; Ding, Chang-Hua; Hou, Xue-Long:

Kinetic Resolution of Unsymmetrical Acyclic Allyl Carbonates Using Trimethylsilyl Cyanide via Palladium-Catalyzed Asymmetric Allylic Alkylation

Image for article: Kinetic Resolution of Unsymmetrical Acyclic Allyl Carbonates Using Trimethylsilyl Cyanide via Palladium-Catalyzed Asymmetric Allylic Alkylation

Supporting Information (PDF)

1515

Haas, Diana; Hammann, Jeffrey M.; Moyeux, Alban; Cahiez, Gérard; Knochel, Paul:

Oxidative Homocoupling of Diheteroaryl- or Diarylmanganese Reagents Generated via Directed Manganation Using TMP₂Mn

Image for article: Oxidative Homocoupling of Diheteroaryl- or Diarylmanganese Reagents Generated via Directed Manganation Using TMP<sub>2</sub>Mn

Supporting Information (PDF)

1520

Davis, Tyler A.; Wang, Chuanqi; Rovis, Tomislav:

Rhodium(III)-Catalyzed C–H Activation: An Oxidative Intramolecular Heck-Type Reaction Directed by a Carboxylate

Supporting Information (PDF)

1525

Wang, Qinggang; List, Benjamin:

A Mukaiyama–Claisen Approach to 3,5-Diketo Esters

Supporting Information (PDF)

1528

Maji, Biplab; Yamamoto, Hisashi:

Asymmetric Synthesis of Tertiary α-Hydroxy Phosphonic Acid Derivatives under Aerobic Oxidation Conditions

Supporting Information (PDF)

1533

Matsushima, Yuji; Phillips, Eric M.; Bergman, Robert G.; Ellman, Jonathan A.:

Rhodium(I)-Catalyzed Cycloisomerization of 1,6-Enynes

Supporting Information (PDF)

1537

Komori, Takashi; Yokoshima, Satoshi; Fukuyama, Tohru:

Synthetic Studies on Plakinidines

1541

Davies, Stephen G.; Goddard, Euan C.; Roberts, Paul M.; Russell, Angela J.; Thomson, James E.:

Enantiopure 3-Amino-Substituted 1-Indanones, 1-Tetralones, and 1-Benzosuberones via Friedel–Crafts Cyclisation of ω-Aryl-β-benzamido Acids

Image for article: Enantiopure 3-Amino-Substituted 1-Indanones, 1-Tetralones, and 1-Benzosuberones via Friedel–Crafts Cyclisation of ω-Aryl-β-benzamido Acids

1545

Lu, Yan; Wang, Min; Zhao, Xiaohu; Liu, Xiaohua; Lin, Lili; Feng, Xiaoming:

Cooperative Chiral Guanidine/AgPF₆ Catalyzed Asymmetric Isocyanoacetate Aldol Reaction with Isatins

Image for article: Cooperative Chiral Guanidine/AgPF<sub>6</sub> Catalyzed Asymmetric Isocyanoacetate Aldol Reaction with Isatins

Supporting Information (PDF)

1549

Kober, Ute; Knölker, Hans-Joachim:

Palladium-Catalyzed Approach to Malasseziazole A and First Total Synthesis of Malasseziazole C

Supporting Information (PDF)

1553

Yu, Yang; Cornelissen, Loïc; Wong, Wing-Tak; Chiu, Pauline:

Cycloaddition Reactions of Carbonyl Ylides Derived From Enones

Supporting Information (PDF)

1557

Wysocki, Jędrzej; Schlepphorst, Christoph; Glorius, Frank:

Asymmetric Homogeneous Hydrogenation of 2-Pyridones

Supporting Information (PDF)

1563

Tranchier, Jean-Philippe; Dubarle-Offner, Julien; Peyroux, Laetitia; Gontard, Geoffrey; Riedel, Tina; Dyson, Paul J.; Amouri, Hani:

Iridium-Stabilized π-Selenocyclohexadienyls: Synthesis, Molecular Structure, and Cytotoxicity

Supporting Information (PDF)

1567

Unsworth, Phillip J.; Löffler, Lorenz E.; Noble, Adam; Aggarwal, Varinder K.:

Palladium-Catalyzed Reactions of Allylic Boronic Esters with Nucleophiles: Novel Umpolung Reactivity

Supporting Information (PDF)

1573

Brown, Michael; Delorme, Marion; Malmedy, Florence; Malmgren, Joel; Olofsson, Berit; Wirth, Thomas:

Synthesis of New Chiral Diaryliodonium Salts

Supporting Information (PDF)

1578

Nishimura, Hidetaka; Eliseeva, Maria N.; Wakamiya, Atsushi; Scott, Lawrence T.:

1,3,5,7-Tetra(Bpin)azulene by Exhaustive Direct Borylation of Azulene and 5,7-Di(Bpin)azulene by Selective Subsequent Deborylation

Image for article: 1,3,5,7-Tetra(Bpin)azulene by Exhaustive Direct Borylation of Azulene and 5,7-Di(Bpin)azulene by Selective Subsequent Deborylation

Supporting Information (PDF)

1581

Mao, Jie; Bong, Dennis:

Synthesis of DNA-Binding Peptoids

Supporting Information (PDF)

1586

Zhou, Yijun; Zhang, Zhigao; Jiang, Yongwen; Pan, Xianhua; Ma, Dawei:

Synthesis of 1,2,4-Benzotriazines via Copper(I) Iodide/1H-Pyrrole-2-carboxylic Acid Catalyzed Coupling of o-Haloacetanilides and N-Boc Hydrazine

Image for article: Synthesis of 1,2,4-Benzotriazines via Copper(I) Iodide/1<i>H</i>-Pyrrole-2-carboxylic Acid Catalyzed Coupling of <i>o</i>-Haloacetanilides and <i>N</i>-Boc Hydrazine

Supporting Information (PDF)

1591

Acosta, Paola; Becerra, Diana; Goudedranche, Sébastien; Quiroga, Jairo; Constantieux, Thierry; Bonne, Damien; Rodriguez, Jean:

Exploiting the Reactivity of 1,2-Ketoamides: Enantioselective Synthesis of Functionalized Pyrrolidines and Pyrrolo-1,4-benzodiazepine-2,5-diones

Image for article: Exploiting the Reactivity of 1,2-Ketoamides: Enantioselective Synthesis of Functionalized Pyrrolidines and Pyrrolo-1,4-benzodiazepine-2,5-diones

Supporting Information (PDF)

1596

Moselage, Marc; Sauermann, Nicolas; Koeller, Julian; Liu, Weiping; Gelman, Dmitri; Ackermann, Lutz:

Cobalt(III)-Catalyzed Allylation with Allyl Acetates by C–H/C–O Cleavage

Supporting Informations (PDF)

1601

Hisaki, Ichiro; Kometani, Eriko; Shigemitsu, Hajime; Tohnai, Norimitsu; Miyata, Mikiji:

Synthesis of Chiral Assembly from Achiral Octadehydrotribenzo[14]annulene Derivative by Using a Twofold Helical Hydrogen-Bonding Template

Image for article: Synthesis of Chiral Assembly from Achiral Octadehydrotribenzo[14]annulene Derivative by Using a Twofold Helical Hydrogen-Bonding Template

Supporting Information (PDF)

1606

Zhao, Wenjun; Yin, Xiaopeng; Gupta, Anil K.; Zhang, Xin; Wulff, William D.:

The Nature of meso- and pyro-Borate Precatalysts to the VANOL and VAPOL BOROX Catalysts

Image for article: The Nature of <i>meso</i>- and <i>pyro</i>-Borate Precatalysts to the VANOL and VAPOL BOROX Catalysts

Supporting Information (PDF) Primary Data (ZIP)

1615

Kayahara, Eiichi; Patel, Vijay Kumar; Xia, Jianlong; Jasti, Ramesh; Yamago, Shigeru:

Selective and Gram-Scale Synthesis of [6]Cycloparaphenylene

Supporting Information (PDF)

1620

Körte, Fabian; Bruhn, Clemens; Faust, Rüdiger:

A Fourfold Benzodehydroannuleno-Fused Porphyrazine

Supporting Information (PDF)

1625

Ji, Qing; Do, Loi H.; Miljanić, Ognjen Š.:

Cyclotribenzoin

Supporting Information (PDF)

1628

Matheis, Christian; Wang, Minyan; Krause, Thilo; Goossen, Lukas J.:

Metal-Free Trifluoromethylthiolation of Alkyl Electrophiles via a Cascade of Thiocyanation and Nucleophilic Cyanide–CF₃ Substitution

Image for article: Metal-Free Trifluoromethylthiolation of Alkyl Electrophiles via a Cascade of Thiocyanation and Nucleophilic Cyanide–CF<sub>3</sub> Substitution

Supporting Information (PDF)

1633

Rodríguez-Lojo, Diego; Peña, Diego; Pérez, Dolores; Guitián, Enrique:

Straightforward Synthesis of Novel Acene-Based Aryne Precursors

Supporting Information (PDF)

1638

Gilani, Mazhar Amjad; Rais, Eduard; Wilhelm, René:

Chiral Imidazolinium Salts with TIPS Groups for the Palladium-Catalyzed α-Arylation and as Chiral Solvating Agents

Supporting Information (PDF)

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