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Editorial

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2855

Heck, Richard F.:

Cobalt and Palladium Reagents in Organic Synthesis: The Beginning

2861

Schmidt, Alexander F.; Al Halaiqa, Ayman; Smirnov, Vladimir V.:

Interplays between Reactions within and without the Catalytic Cycle of the Heck Reaction as a Clue to the Optimization of the Synthetic Protocol

Image for article: Interplays between Reactions within and without the Catalytic Cycle of the Heck Reaction as a Clue to the Optimization of the Synthetic Protocol

2879

Lee, Youngu; Liang, Yongye; Yu, Luping:

The Heck Polycondensation for Functional Polymers

2894

Scherg, Tobias; Schneider, Sabine K.; Frey, Guido D.; Schwarz, Jürgen; Herdtweck, Eberhardt; Herrmann, Wolfgang A.:

Bridged Imidazolium Salts Used as Precursors for Chelating Carbene Complexes of Palladium in the Mizoroki-Heck Reaction

2908

Demchuk, Oleg M.; Yoruk, Bilge; Blackburn, Tom; Snieckus, Victor:

A Mixed Naphthyl-Phenyl Phosphine Ligand Motif for Suzuki, Heck, and Hydrodehalogenation Reactions

2914

Nierle, Jens; Kuck, Dietmar:

Synthesis of a Benzoannelated Spheriphane (Globular Cyclophane) on the Way to Potential Precursors of C₆₀-Fullerene

Image for article: Synthesis of a Benzoannelated Spheriphane (Globular Cyclophane) on the Way to Potential Precursors of C<SUB>60</SUB>-Fullerene

2921

Denmark, Scott E.; Smith, Russell C.:

Reduction of Allylpalladium(II)chloride Dimer by Formation of Allyloxysilanes

2929

Gibson, Susan E.; Lecci, Cristina; White, Andrew J. P.:

Application of the Heck Reaction in the Synthesis of Macrocycles Derived from Amino Alcohols

2935

Lemhadri, Mhamed; Doucet, Henri; Santelli, Maurice:

Synthesis of (E)-1-Aryl Alk-1-en-3-ones by Tetraphosphine/Palladium-Catalysed Heck Reactions of Alk-1-en-3-ones with Aryl Bromides

Image for article: Synthesis of (<EM EMTYPE="ITALIC">E</EM>)-1-Aryl Alk-1-en-3-ones by Tetraphosphine/Palladium-Catalysed Heck Reactions of Alk-1-en-3-ones with Aryl Bromides

2941

Larsen, Catharine H.; Anderson, Kevin W.; Tundel, Rachel E.; Buchwald, Stephen L.:

Palladium-Catalyzed Heck Alkynylation of Benzyl Chlorides

2947

Bernini, Roberta; Cacchi, Sandro; De Salve, Ilse; Fabrizi, Giancarlo:

The Heck Reaction of β-Arylacrylamides: An Approach to 4-Aryl-2-quinolones

2953

Leadbeater, Nicholas E.; Williams, Victoria A.; Barnard, Thomas M.; Collins Jr, Michael J.:

Solvent-Free, Open-Vessel Microwave-Promoted Heck Couplings: From the mmol to the mol Scale

2959

Alacid, Emilio; Nájera, Carmen:

Palladated Kaiser Oxime Resin as Precatalyst for the Heck Reaction in Organic and Aqueous Media

2965

Oestreich, Martin; Sempere-Culler, Fernando; Machotta, Axel B.:

An Enantioselective Access to an Anthracycline AB Synthon by a Desymmetrizing Heck Cyclization

2969

Alberico, Dino; Lautens, Mark:

Palladium-Catalyzed Alkylation-Alkenylation Reactions: Rapid Access to Tricyclic Mescaline Analogues

2973

Lee, Alison V.; Schafer, Laurel L.:

A Sequential C-N, C-C Bond-Forming Reaction: Direct Synthesis of α-Amino Acids from Terminal Alkynes

2977

Harrowven, David C.; Guy, Ian L.; Howell, Melanie; Packham, Graham:

The Synthesis of a Combretastatin A-4 Based Library and Discovery of New Cooperative ortho-Effects in Wittig Reactions Leading to (Z)-Stilbenes

Image for article: The Synthesis of a Combretastatin A-4 Based Library and Discovery of New Cooperative <EM EMTYPE="ITALIC">ortho</EM>-Effects in Wittig Reactions Leading to (<EM EMTYPE="ITALIC">Z</EM>)-Stilbenes

2981

Mohler, Debra L.; Kumaraswamy, Sriram; Stanger, Amnon; Vollhardt, K. Peter C.:

1,2,3,4-Tetraethynylbenzene as a Template for Cobalt-Catalyzed Alkyne Cocyclizations: Synthesis of 2,3,8,9-Tetrakis(trimethylsilyl) Angular [3]Phenylene and Bent [5]Phenylene (Benzo[1′′,2′′:3,4;3′′,4′′:3′,4′]dicyclobuta[1,2-b:1′,2′-b′]bisbiphenylene)

Image for article: 1,2,3,4-Tetraethynylbenzene as a Template for Cobalt-Catalyzed Alkyne Cocyclizations: Synthesis of 2,3,8,9-Tetrakis(trimethylsilyl) Angular [3]Phenylene and Bent [5]Phenylene (Benzo[1′′,2′′:3,4;3′′,4′′:3′,4′]dicyclobuta[1,2-<EM EMTYPE="ITALIC">b</EM>:1′,2′-<EM EMTYPE="ITALIC">b</EM>′]bisbiphenylene)

2985

Li, Min; Wu, Anmei:

Total Synthesis of Sphingofungin F

2989

Beccaria, Luca; Deagostino, Annamaria; Prandi, Cristina; Zavattaro, Chiara; Venturello, Paolo:

Heck Reaction on 1-Alkoxy-1,3-dienes in Ionic Liquids: A Superior Medium for the Regioselective Arylation of the Conjugated Dienic System

Image for article: Heck Reaction on 1-Alkoxy-1,3-dienes in Ionic Liquids: A Superior Medium for the Regioselective Arylation of the Conjugated Dienic System

2993

Aulenta, Francesca; Reissig, Hans-Ulrich:

Heck Reactions of Quinoline-Derived Nonaflates

2997

Hudson, Robert H. E.; Moszynski, Joanne M.:

A Facile Synthesis of Fluorophores Based on 5-Phenylethynyluracils

3001

Moreno-Mañas, Marcial; Pleixats, Roser; Serra-Muns, Anna:

Suzuki Cross-Couplings on Aryl (Heteroaryl) Bromides and Chlorides with Bulky Aliphatic Phosphines/Pd(0)-Triolefinic Macrocyclic Catalyst

Image for article: Suzuki Cross-Couplings on Aryl (Heteroaryl) Bromides and Chlorides with Bulky Aliphatic Phosphines/Pd(0)-Triolefinic Macrocyclic Catalyst

3005

Hierso, Jean-Cyrille; Picquet, Michel; Cattey, Hélène; Meunier, Philippe:

Palladium-Catalysed Heck Alkynylation of Aryl Bromides in an Imidazolium Ionic Liquid: An Unexpected Subsequent Alkyne Hydrogenation Reaction

Image for article: Palladium-Catalysed Heck Alkynylation of Aryl Bromides in an Imidazolium Ionic Liquid: An Unexpected Subsequent Alkyne Hydrogenation Reaction

3009

Lo, Mee Yoon; Sellinger, Alan:

Highly Fluorescent Blue-Emitting Materials from the Heck Reaction of Triphenylvinylsilane with Conjugated Dibromoaromatics

Image for article: Highly Fluorescent Blue-Emitting Materials from the Heck Reaction of Triphenylvinylsilane with Conjugated Dibromoaromatics

3013

Doi, Takashi; Fukuyama, Takahide; Minamino, Satoshi; Ryu, Ilhyong:

RuHCl(CO)(PPh₃)₃-Catalyzed Reductive Dimerization of α,β-Unsaturated Aldehydes Leading to α-Hydroxymethyl Ketones

Image for article: RuHCl(CO)(PPh<SUB>3</SUB>)<SUB>3</SUB>-Catalyzed Reductive Dimerization of α,β-Unsaturated Aldehydes Leading to α-Hydroxymethyl Ketones

3017

Alonso, Francisco; Osante, Iñaki; Yus, Miguel:

Conjugate Reduction of α,β-Unsaturated Carbonyl Compounds Promoted by Nickel Nanoparticles

3021

Grigg, Ronald; Kilner, Colin; Mariani, Edoardo; Sridharan, Visuvanathar:

Palladium-Catalysed Cyclisation-Anion Capture Processes: In situ ‘Zipper’ Generation via Intramolecular Nucleophilic Capture of π-Allylpalladium Species

Image for article: Palladium-Catalysed Cyclisation-Anion Capture Processes: In situ ‘Zipper’ Generation via Intramolecular Nucleophilic Capture of π-Allylpalladium Species

3025

Konno, Tsutomu; Yamada, Shigeyuki; Tani, Akinori; Miyabe, Tomotsugu; Ishihara, Takashi:

A Novel Synthesis of Trifluoromethylated Multi-Substituted Alkenes via Regio- and Stereoselective Heck Reaction of (E)-4,4,4-Trifluoro-1-phenyl-2-buten-1-one

Image for article: A Novel Synthesis of Trifluoromethylated Multi-Substituted Alkenes via Regio- and Stereoselective Heck Reaction of (<EM EMTYPE="ITALIC">E</EM>)-4,4,4-Trifluoro-1-phenyl-2-buten-1-one

3029

Declerck, Valérie; Martinez, Jean; Lamaty, Frédéric:

Microwave-Assisted Copper-Catalyzed Heck Reaction in PEG Solvent

3033

Belhadj, Tahar; Nowicki, Audrey; Moody, Christopher J.:

Synthesis of the ‘Northern-Hemisphere’ Fragments of the Thiopeptide Antibiotic Nosiheptide

3037

Inoue, Masayuki; Takahashi, Tomoaki; Furuyama, Hidetomo; Hirama, Masahiro:

Structural Factors Governing Stereoselective Heck Reaction for the Construction of the Oxindole Portion of TMC-95A

3041

González, Ivan; Roglans, Anna; Benet-Buchholz, Jordi; Roura, Pere:

New Unsaturated Azamacrocyclic Enediynes: Synthesis, Structural Analysis and Thermal Behavior

3045

Lory, Pedro M. J.; Agarkov, Anton; Gilbertson, Scott R.:

An Expedient Route to 3-Chlorothioxanthen-9-one-10,10-dioxide and Derivation by Palladium-Catalyzed Coupling

3049

de Oliveira, Ronaldo N.; Mendonça Jr, Francisco J. B.; Sinou, Denis; de Melo, Sebastiao J.; Srivastava, Rajendra M.:

Palladium(0)-Catalyzed Allylation of Heterocyclic Nucleophiles with Unsaturated Carbohydrates

3053

Itano, Wataru; Ohshima, Takashi; Shibasaki, Masakatsu:

Synthesis of the Tricyclic Core of 5α-Capnellenols Using Asymmetric Heck Reaction-Carbanion Capture Process

3057

Yang, Min; Yip, Kai-Tai; Pan, Jie-Hui; Chen, Ying-Chun; Zhu, Nian-Yong; Yang, Dan:

A Sterically Bulky Cyclic Thiourea as an Efficient Ligand for Palladium-Catalyzed Aerobic Oxidation of Alcohols

3061

Someya, Hidenori; Kondoh, Azusa; Sato, Akinori; Ohmiya, Hirohisa; Yorimitsu, Hideki; Oshima, Koichiro:

A New Approach to 4-Aryl-1,3-butanediols by Cobalt-Catalyzed Sequential Radical Cyclization-Arylation Reaction of Silicon-Tethered 6-Iodo-1-hexene Derivatives

Image for article: A New Approach to 4-Aryl-1,3-butanediols by Cobalt-Catalyzed Sequential Radical Cyclization-Arylation Reaction of Silicon-Tethered 6-Iodo-1-hexene Derivatives

3065

Nakai, Yasushi; Kimura, Tsutomu; Uozumi, Yasuhiro:

Alkylative Cyclization of 1,6-Enynes in Water with an Amphiphilic Resin-Supported Palladium Catalyst

3069

Kocharit, Chanitsara; Chaiyanurakkul, Arada; Gallagher, Timothy:

Diastereoselective Heck Arylation of Spirolactams: An Approach to Spiroamine-Based Nicotinic Ligands

3073

Pattenden, Gerald; Blake, Alexander J.; Reddy, L. Krishnakanth; Stoker, Davey A.:

An Attempted Cascade Radical-Mediated Cyclisation Approach to Ring-D Aromatic Steroids

3077

Fujioka, Hiromichi; Okitsu, Takashi; Sawama, Yoshinari; Ohnaka, Takuya; Kita, Yasuyuki:

Highly Chemoselective Alkylation of Acetals Using TESOTf-2,4,6-Collidine-Gilman Reagent Combination

3081

Garg, Neil K.; Caspi, Daniel D.; Stoltz, Brian M.:

The Utility of the Classical and Oxidative Heck Reactions in Natural Product Synthesis: Studies Directed toward the Total Synthesis of Dragmacidin F

Image for article: The Utility of the Classical and Oxidative Heck Reactions in Natural Product Synthesis: Studies Directed toward the Total Synthesis of Dragmacidin F

3088

Roland, Sylvain; Mangeney, Pierre; Jutand, Anny:

Reactivity of Pd(0)(NHC)₂ (NHC: N-Heterocyclic Carbene) in Oxidative Addition with Aryl Halides in Heck Reactions

Image for article: Reactivity of Pd(0)(NHC)<SUB>2</SUB> (NHC: N-Heterocyclic Carbene) in Oxidative Addition with Aryl Halides in Heck Reactions

3095

Gégout, Aline; Figueira-Duarte, Teresa M.; Nierengarten, Jean-François; Listorti, Andrea; Armaroli, Nicola:

Synthesis and Excited-State Properties of an Oligophenylenevinylene Heptamer Substituted with Two Fullerene Moieties

3100

Mitasev, Branko; Brummond, Kay M.:

Synthesis of Functionalized Δ³-Pyrrolines via a Ag(I)-Catalyzed Cyclization of Amino Acid Derived Allenes

Image for article: Synthesis of Functionalized Δ<SUP>3</SUP>-Pyrrolines via a Ag(I)-Catalyzed Cyclization of Amino Acid Derived Allenes

3105

de Lange, Ben; Lambers-Verstappen, Marielle H.; Schmieder-van de Vondervoort, Lizette; Sereinig, Natascha; de Rijk, Ron; de Vries, André H. M.; de Vries, Johannes G.:

Aromatic Amination of Aryl Bromides Catalysed by Copper/β-Diketone Catalysts: The Effect of Concentration

3110

Kawamura, Yasufumi; Imai, Takuro; Hosokawa, Takahiro:

Palladium(II)-Catalyzed Synthesis of 2-Alkoxytetrahydrofurans from Allylic Alcohols and Vinyl Ethers: Stereospecificity and Catalysis

Image for article: Palladium(II)-Catalyzed Synthesis of 2-Alkoxytetrahydrofurans from Allylic Alcohols and Vinyl Ethers: Stereospecificity and Catalysis

3115

Schwan, Adrian L.; Duspara, Petar A.; Paquette, Michelle M.; Merrill, A. Rod:

A BF₃-Mediated Nitrogen-to-Carbon Rearrangement of N-Protected 2,3-Dihydro-3-hydroxy-1H-benzisoindol-1-ones, and Its Interception for a Facile Preparation of 3-Substituted Benzisoindolones

Image for article: A BF<SUB>3</SUB>-Mediated Nitrogen-to-Carbon Rearrangement of N-Protected 2,3-Dihydro-3-hydroxy-1<EM EMTYPE="ITALIC">H</EM>-benzisoindol-1-ones, and Its Interception for a Facile Preparation of 3-Substituted Benzisoindolones

3120

Hopkins, J. Matthew; Gorobets, Evgueni; Wheatley, Bronwen M. M.; Parvez, Masood; Keay, Brian A.:

Applications of 3,3′-Disubstituted BINAP Derivatives in Inter- and Intramolecular Heck/Mizoroki Reactions

3125

Ackermann, Lutz; Althammer, Andreas:

One-Pot 2-Aryl/Vinylindole Synthesis Consisting of a Ruthenium-Catalyzed Hydroamination and a Palladium-Catalyzed Heck Reaction Using 2-Chloroaniline

Image for article: One-Pot 2-Aryl/Vinylindole Synthesis Consisting of a Ruthenium-Catalyzed Hydroamination and a Palladium-Catalyzed Heck Reaction Using 2-Chloroaniline

3130

Molnár, Árpád; Papp, Attila:

Heck Arylation of Maleic Anhydrides Using Arenediazonium Tetrafluoroborates: Synthesis of Mono- and Diarylated Maleic Anhydrides and of the Marine Alkaloids Prepolycitrin A and Polycitrin A

Image for article: Heck Arylation of Maleic Anhydrides Using Arenediazonium Tetrafluoroborates: Synthesis of Mono- and Diarylated Maleic Anhydrides and of the Marine Alkaloids Prepolycitrin A and Polycitrin A

3150

Fitzpatrick, Martin O.; Coyne, Anthony G.; Guiry, Patrick J.:

The Application of HETPHOX Ligands to the Intramolecular Asymmetric Heck Reaction

3155

Reddy Dubbaka, Srinivas; Zhao, Dongbin; Fei, Zhaofu; Rao Volla, Chandra M.; Dyson, Paul J.; Vogel, Pierre:

Palladium-Catalyzed Desulfitative Mizoroki-Heck Coupling Reactions of Sulfonyl Chlorides with Olefins in a Nitrile-Functionalized Ionic Liquid

Image for article: Palladium-Catalyzed Desulfitative Mizoroki-Heck Coupling Reactions of Sulfonyl Chlorides with Olefins in a Nitrile-Functionalized Ionic Liquid

3158

Shi, Min; Wang, Bao-Yu:

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