Synlett 2006(18): 3095-3099  
DOI: 10.1055/s-2006-947327
LETTER
© Georg Thieme Verlag Stuttgart · New York

Synthesis and Excited-State Properties of an Oligophenylenevinylene Heptamer Substituted with Two Fullerene Moieties

Aline Gégouta, Teresa M. Figueira-Duartea, Jean-François Nierengarten*a, Andrea Listortib, Nicola Armaroli*b
a Groupe de Chimie des Fullerènes et des Systèmes Conjugués, Laboratoire de Chimie de Coordination du CNRS, 205 route de Narbonne, 31077 Toulouse Cedex 4, France
Fax: +33(5)61553003; e-Mail: jfnierengarten@lcc-toulouse.fr;
b Istituto per la Sintesi Organica e la Fotoreattività, Molecular Photoscience Group, Consiglio Nazionale delle Ricerche, Via Gobetti 101, 40129 Bologna, Italy
Fax: +39(051)6399844; e-Mail: armaroli@isof.cnr.it;
Further Information

Publication History

Received 7 April 2006
Publication Date:
04 August 2006 (eFirst)

Abstract

An oligophenylenevinylene (OPV) derivative substituted with two fullerene subunits has been prepared starting from a fullerene carboxylic acid derivative and an OPV heptamer bearing two alcohol functions. Photophysical investigations have revealed the occurrence of intramolecular photoinduced energy- and electron-transfer processes in this hybrid compound.