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Synthesis 2006(24): 4159-4162  
DOI: 10.1055/s-2006-950340
PAPER
© Georg Thieme Verlag Stuttgart · New York

Non-Catalyzed, Atom-Economic, High-Yield Synthesis of Tertiary α-Hydroxyphosphane Selenides

Nina K. Gusarova, Nina I. Ivanova, Nataliya A. Konovalova, Boris G. Sukhov, Ludmila V. Baikalova, Lidiya M. Sinegovskaya, Dmitriy V. Pavlov, Boris A. Trofimov*
A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences, 1 Favorsky Street, 664033 Irkutsk, Russian Federation
Fax: +7(3952)419346; e-Mail: gusarova@irioch.irk.ru;
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Publication History

Received 12 July 2006
Publication Date:
02 November 2006 (online)

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Abstract

First examples of a facile hydroselenophosphorylation of aldehydes are reported. Nucleophilic addition of P,Se-ambident secondary phosphane selenides to a series of aldehydes proceeds under catalyst-free conditions at room temperature to give tertiary α-hydroxyphosphane selenides in high yield.

Key words

hydroselenophosphorylation - α-hydroxyphosphane selenides - aldehydes - nucleophilic addition

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