Recent Advances in Dual Triplet Ketone/Transition-Metal Catalysis

This Account is dedicated to Professor Masahiro Murakami’s excellent contributions to science.

Abstract

Dual light-excited ketone/transition-metal catalysis is a rapidly developing field of photochemistry. It allows for versatile functionalizations of C–H or C–X bonds enabled by triplet ketone acting as a hydrogen-atom-abstracting agent, a single-electron acceptor, or a photosensitizer. This review summarizes recent developments of synthetically useful transformations promoted by the synergy between triplet ketone and transition-metal catalysis.

1 Introduction

2 Triplet Ketone Catalysis via Hydrogen Atom Transfer

2.1 Triplet Ketones with Nickel Catalysis

2.2 Triplet Ketones with Copper Catalysis

2.3 Triplet Ketones with Other Transition-Metal Catalysis

3 Triplet Ketone Catalysis via Single-Electron Transfer

4 Triplet Ketone Catalysis via Energy Transfer

5 Conclusions

Key words

dual catalysis - triplet ketone - transition-metal catalysis - photocatalysis - photosensitizer - C–H functionalization

Publication History

Received: 30 January 2023

Accepted after revision: 21 March 2023

Article published online:
25 May 2023

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