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60 Years of the Matteson Reaction: Modern Boronate Rearrangements
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Development and Applications of Novel Ligands/Catalysts and Mechanistic Studies on Catalysis
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Perspectives on Organoheteroatom and Organometallic Chemistry
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Issue eFirst
Dahiwadkar, Rahul; Kaloo, Masood A.; Kanvah, Sriram:
Functional α-Cyanostilbenes: Sensing to Imaging
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Chiu, Kuei-Wei; Chein, Rong-Jie:
Exploring the Power of Sulfur, Silicon, and Organocatalysis: Innovative Strategies for Asymmetric Synthesis and Advanced Synthetic Methodology
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PDF (467 kb)
Long, Peng-Wei; He, Tao; Klare, Hendrik F. T.; Oestreich, Martin:
Skeletal Rearrangements Involving Cyclopropyl- and Alkene-Stabilized Silylium Ions
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PDF (649 kb)
Toshima, Kazunobu; Takahashi, Daisuke; Isozaki, Yuka:
Photo-Induced Glycosylations Using Organophotoacids: A New Environmentally Benign Carbohydrate Synthesis
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PDF (682 kb)
Yadav, Bharti; Ravikanth, Mangalampalli:
Functionalized Aza-BODIPYs and Their Use in the Synthesis of Aza-BODIPY-Based Complex Systems
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PDF (1622 kb)
Kouklovsky, Cyrille; Poupon, Erwan; Evanno, Laurent; Vincent, Guillaume:
Total Synthesis of Mavacuran Alkaloids via Bioinspired and Non-Bioinspired Strategies
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PDF (1008 kb)
Sreenivasulu, Chinnabattigalla; Kishore, Dakoju Ravi; Basuli, Suchand; Satyanarayana, Gedu:
Palladium-Catalyzed Acylation Strategies and Their Applications Towards Biologically Relevant Products
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Hong, Xiaoling; Chen, Peng; Li, Huilin; She, Xuegong:
Bioinspired Total Syntheses of Gymnothelignans
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Yang, Xiao-Guang; Hu, Ze-Nan; Jia, Meng-Cheng; Du, Feng-Huan; Zhang, Chi:
Recent Advances and the Prospect of Hypervalent Iodine Chemistry
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Cong, Xuefeng; Zeng, Xiaoming:
Chromium-Catalyzed Cross-Coupling Reactions by Selective Activation of Chemically Inert Aromatic C–O, C–N, and C–H Bonds
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PDF (488 kb)
Gao, Yanqun; Cheng, Lu; Shi, Wei; Ouyang, Yuejun; Han, Wei:
New Paradigms in Catalysis Inspired by Cytochromes P450
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Sassi, Mauro; Mattiello, Sara; Fappani, Alice; Beverina, Luca:
Polyconjugated Materials for Printed (Opto)Electronics: Introducing Sustainability
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Yu, Changjiang; Sun, Yingzhu; Jiao, Lijuan; Hao, Erhong:
Recent Advances in Highly Fluorescent Hydrazine-Inserted Pyrrole-Based Diboron-Anchoring Fluorophores: Synthesis and Properties
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Liu, Ting; Wang, Congyang:
Manganese-Catalyzed C(sp
2
)–H Addition to Polar Unsaturated Bonds
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Wei, Jingjing; Liang, Shuaishuai; Jiang, Lvqi; Yi, Wenbin:
Direct Fluoroalkylthiolation Based on Fluoroalkanesulfite Derivatives
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Čarný, Tomáš; Šebesta, Radovan:
Comparison of Diastereoselective
ortho
-Metalations and C–H Activations of Chiral Ferrocenes
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PDF (1006 kb)
Qin, Yang:
Pt(II)-Bisacetylide ‘Roller Wheels’: Molecular Engineering towards Small Bandgap, High Crystallinity, and Controlled Triplet Exciton Processes
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PDF (3129 kb)
Wang, Zhao-Li; Liu, An-Di; Liu, Li; Cheng, Liang:
Recent Advances in the Synthesis of 5-(Hetero)aryl Uracil Derivatives
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Kim, Woo Hee; Park, Jin Hyun; Lee, Sun Bu; Israr, Muhammad; Koo, Byeong Jun; Kim, Soo Bok; Kim, Soyeon; Bae, Han Yong:
Sustainable Organocatalytic Processes to Access Alkyl SuFEx Click Hubs and Tetrasubstituted Carbon Centers: Potential Libraries for Multidisciplinary Applications
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Zhang, Fan; Chen, Chongchong; Hu, Xiangdong:
Investigations on Biomimetic Dimerization in Natural Product Synthesis
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PDF (766 kb)
Fujihara, Tetsuaki:
Borylative Difunctionalization of Unsaturated Hydrocarbons Using Borylcopper Species
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PDF (597 kb)
Aggarwal, Varun; Bala, Ekta; Saima, Saima; Pathan, Sameer; Guleria, Saksham; Sharma, Sakshi; Selvaraj, Manickam; Verma, Praveen Kumar:
Recent Developments in Photocatalytic Reduction of Nitro Compounds to Valuable Scaffolds
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Li, Ying; Feng, Kongling; Zhao, Ruinan; Zhu, Cuiju; Xu, Hao:
Dearomatization of α-Unsubstituted β-Naphthols
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Johnson, Colton E.; Li, Shangyu; Arora, Ramon; Mirabi, Bijan; Lautens, Mark:
Nickel-Catalyzed sp
3
C–H Activation
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PDF (729 kb)
Martínez, Sebastián; Lichtenberg, Crispin:
Bismuth-Centered Radical Species: Access and Applications in Organic Synthesis
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PDF (921 kb)
Kondo, Yuta; Morimoto, Hiroyuki; Ohshima, Takashi:
Development of Novel Catalytic Direct Syntheses of N-Unsubstituted Ketimines and Their Applications to One-Pot Reactions
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PDF (695 kb)
Kashyap, Sauvik; Phukan, Prodeep:
Bromamine-T (TsNBrNa): A Biologically Significant, Versatile Bromo-Organic Reagent
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PDF (1900 kb)
Pang, Xiaobo; Shu, Xing-Zhong:
Titanium: A Unique Metal for Radical Dehydroxylative Functionalization of Alcohols
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PDF (528 kb)
Chen, David Yu-Kai:
Adventures in Total Synthesis – The Next Chapter
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PDF (864 kb)
Greb, Lutz:
p-Block Element Catecholates: Lewis Superacidic, Constitutionally Dynamic, and Redox Active
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PDF (6219 kb)
Evano, Gwilherm; Theunissen, Cédric:
Copper-(Photo)Catalyzed Radical Reactions with Organic Halides
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PDF (1601 kb)
Wang, Linqing; Yang, Dongxu:
Strategies of In Situ Generated Magnesium Catalysis in Asymmetric Reactions
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PDF (880 kb)
Hu, Deqing; Jiang, Xuefeng:
Perspectives for Uranyl Photoredox Catalysis
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PDF (555 kb)
Zheng, Kuan; Zhang, Bingbing; Hong, Ran:
Embracing the Imperfectness of Nature using Highly Reactive
N
-Acyl Azahexatrienes
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PDF (595 kb)
Cruz, Carlos M.; Campaña, Araceli G.:
Nanographenes Out of Planarity
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PDF (1779 kb)
Huang, Jing; He, Long; Wang, Jiaoliang; Xu, Junchao; Yuan, Lin:
Near-Infrared Hemicyanine Fluorophores with Optically Tunable Groups: A ‘Leap Forward’ for
in Vivo
Sensing and Imaging
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PDF (3748 kb)
Hasegawa, Masashi; Mazaki, Yasuhiro:
Stereogenic π-Conjugated Macrocycles: Synthesis, Structure, and Chiroptical Properties Including Circularly Polarized Luminescence
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PDF (3912 kb)
Kong, Lingbing; Cui, Chunming:
Perspective on Organoboron Chemistry
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PDF (546 kb)
Gilbert, Audrey; Bach, Thorsten:
The Awakening of a Sleeping Beauty: The
ortho
Photocycloaddition in the Total Synthesis of Protoilludane- and Prezizaene-Type Sesquiterpenes
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PDF (652 kb)
Galeote, Oriol; Kennington, Stuart C. D.; Mellado-Hidalgo, Miguel; Costa, Anna M.; Romea, Pedro; Urpí, Fèlix:
Stereocontrolled Aldol-Like Reactions Involving Oxocarbenium Intermediates
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Nishimoto, Yoshihiro; Yasuda, Makoto:
Acetate/Alkoxide/Halide Shuttle Systems Mediated by Lewis Acid Catalysts for Insertion Reaction of a One-Carbon Unit into Carbon–Carbon or Carbon–Halogen Bonds
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Miñoza, Shinje; Librando, Ivy L.; Liao, Hsuan-Hung:
Ketone-Derived Pro-aromatic Reagents for Radical Group Transfer Reactions and Deconstructive Functionalizations
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On, Ivan K. W.; Zhu, Ye:
Enantioselective Palladium-Catalyzed Suzuki–Miyaura Reactions Enabled by Ionic Ligand–Substrate Interactions
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PDF (370 kb)
Banoun, Camille; Magnier, Emmanuel; Dagousset, Guillaume:
Recent Uses of Photogenerated Oxygen-Centered Radicals in Intermolecular C–O Bond Formation
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PDF (695 kb)
Song, Jin; Gong, Liu-Zhu:
Lewis Base/3d Transition-Metal Cooperatively Catalyzed Asymmetric Reactions
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PDF (889 kb)
Koike, Takashi:
Small Aromatics Bearing Two Diarylamino Termini: Highly Reducing Organic Photocatalysts
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PDF (450 kb)
Fuwa, Haruhiko:
Total Synthesis of Marine Macrolide Natural Products by the Macrocyclization/Transannular Pyran Cyclization Strategy
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PDF (500 kb)
Li, Jinling; Zhao, Junjie; Loh, Teck-Peng:
Photoredox-Catalyzed C(sp
2
)–H Bond Functionalization Reactions: A Short Account
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PDF (859 kb)
Song, Chunlan; Liu, Kun; Dong, Xin; Chiang, Chien-Wei; Lei, Aiwen:
Recent Advances in Electrochemical Oxidative Cross-Coupling for the Construction of C–S Bonds
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PDF (851 kb)
Cheng, Junfeng; Lei, Zuhai:
New High-Performance Fluorescent Dye Scaffolds: Applications for Bioimaging and Biosensing
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PDF (2141 kb)
Issue Accepted Manuscripts
Genetics, Annemieke Aartsma-Rus Human:
Applying lessons learned from developing exon skipping for Duchenne to developing individualized exon skipping therapy for patients with neurodegenerative diseases
PDF (575 kb)
Bag, Subhendu Sekhar; Banerjee, Aniket; Sinha, Sayantan:
Expansion of Genetic Alphabets: Designer Nucleobases and Their Applications
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Sib, Anna; Derdau, Volker:
Method Development and Syntheses Examples of Isotopically Labeled Compounds to Foster Operational Excellence in Pharma Industry
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Dhameliya, Tejas M.; Raghani, Neha R.; Desai, Meet S.; Chudasma, Shrdhhaba J.; Virani, Kumkum D.:
Coverage of Ionic Liquids Assisted Synthetic Construction of Nitrogen- and Oxygen-Containing Heterocyclic Scaffolds Reported during 2022
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Hudait, Nandagopal; Sikander, Noreen; Kundu, Sanchari; Rasool, Bisma; Sengupta, Jhimli; Mukherjee, Debaraj:
A succinct description on the synthesis of modified C-nucleosides of therapeutic significant
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Blaszczyk, Stephanie A.; Li, Xiaolei; Wen, Peng; Tang, Weiping:
Stereo- and Site-selective Acylation in Carbohydrate Synthesis
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Issue 20/2023
Park, Jinjae; Kim, Tae Lyn; Cheon, Cheol-Hong:
Total Syntheses of 2,2′-Biindolyl Alkaloids via Cyanide-Catalyzed Imino-Stetter Reaction
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PDF (629 kb)
Mori, Shogo; Sakurai, Shu; Naka, Hiroshi; Saito, Susumu:
Metal-Loaded Semiconductor-Photocatalysis of Alcohols for Selective Organic Synthesis: A Personal Account
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Sohail, Muhammad; Tanaka, Fujie:
Synthesis of Functionalized Spirooxindole Polycycles: Use of Cyclic 1,3-Diones as Reactants or as Condition-Tuning Molecules
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PDF (609 kb)
Tan, Jiajing; Feng, Xiaoying; Fan, Rong; Zhuang, Zhe; Guo, Yifeng:
When Aryne Chemistry Meets Organosulfur Compounds
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PDF (551 kb)
Issue 19/2023
Lu, Xi; Wang, Yini; Xie, Kailin; Zhang, Jian:
Cross-Coupling Reactions between Alkenes by C–H Cyclometalation
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PDF (1224 kb)
Sakamoto, Jukiya; Ishikawa, Hayato:
Bioinspired Total Syntheses of Secologanin-Related Natural Products: A Demonstration of the Power of Secologanin in the Flask
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PDF (561 kb)
Issue 18/2023
Essman, Jake Z.; Sharma, Hayden A.; Jacobsen, Eric N.:
Development of Enantioselective Lithium-Isothiourea-Boronate–Catalyzed Matteson Homologations
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PDF (2599 kb)
Bao, Zhicheng; Wang, Jianbo:
Transition-Metal-Free Insertion of Diazo Compounds,
N
-Arylsulfonylhydrazones or Ylides into Organoboronic Acids or Their Derivatives
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PDF (662 kb)
Wang, Dong; XU, Tao:
Recent Advances in the Preparation and Asymmetric Transformation of α-Haloboron Compounds
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PDF (565 kb)
Chen, Lili; Xu, Senmiao:
Ligand-Enabled Regio- and/or Stereoselective Hydroboration of Alkenes
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PDF (370 kb)
Gillions, Joseph P.; Elsherbeni, Salma A.; Winfrey, Laura; Yun, Lei; Melen, Rebecca L.; Morrill, Louis C.; Pulis, Alexander P.:
Recent Advances in Catalysis Using Organoborane-Mediated Hydride Abstraction
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Monteiro, Sofia A. G.; Gois, Pedro M. P.; António, João P. M.:
Boronic Acids and Beyond: ROS-Responsive Prodrugs as Tools for a Safer and More Effective Cancer Chemotherapy
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PDF (1670 kb)
Issue 17/2023
Langer, Peter:
Small and Smart: Adventures in Epihalohydrin Chemistry
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PDF (406 kb)
Sankara, Chenikkayala Siva; Gaikwad, Shweta Prakash; Namboothiri, Irishi N. N.:
Synthesis of Natural Products, Carbocycles, and Heterocycles by Hauser–Kraus Annulation
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Shimajiri, Takuya; Jacquot de Rouville, Henri-Pierre; Heitz, Valérie; Akutagawa, Tomoyuki; Fukushima, Takanori; Ishigaki, Yusuke; Suzuki, Takanori:
Crystal Engineering, Electron Conduction, Molecular Recognition and Reactivity by Chalcogen Bonds in Tetracyanoquinodimethanes Fused with [1,2,5]Chalcogenadiazoles
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Issue 16/2023
Dodds, Amy C.; Waddell, Lachlan J. N.; Sutherland, Andrew:
Regioselective Functionalization of Arenes Using Iron Triflimide Catalysis
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PDF (918 kb)
Compain, Philippe:
From Sweet Molecular Giants to Square Sugars and Vice Versa
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PDF (2066 kb)
Issue 15/2023
Münzer, Lukas; Schmalz, Hans-Günther:
Lessons from the Total Synthesis of Highly Substituted Benzophenone Natural Products
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PDF (792 kb)
Langer, Peter:
Adventures in the Chemistry of 1,1-Diacylcyclopropanes
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PDF (448 kb)
Issue 14/2023
Chen, Yang; Chen, Weihao; Gu, Xiao; Ho, Chun-Yu:
Our Voyage from Catalytic Cross-Hydroalkenylation to Transfer-Dehydroaromatization of Cyclic π-Systems: Reactivity and Selectivity Changes Enabled by NHC-Ni and NHC-Pd Hydride Equivalents
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PDF (748 kb)
Oliva, Monica; Chernobrovkina, Viktoriia V.; Van der Eycken, Erik V.; Sharma, Upendra Kumar:
Boronic Acids and Their Derivatives as Continuous-Flow-Friendly Alkyl Radical Precursors
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PDF (1952 kb)
Issue 13/2023
Rivas, Mónica; Gevorgyan, Vladimir:
Advances in Selected Heterocyclization Methods
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PDF (537 kb)
Robins, Jacob G.; Johnson, Jeffrey S.:
Development of New Reactions Driven by N–O Bond Cleavage: from
O
-Acyl Hydroxylamines to Tetrodotoxin
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PDF (683 kb)
Issue 12/2023
Iziumchenko, Valeriia; Gevorgyan, Vladimir:
Recent Advances in Dual Triplet Ketone/Transition-Metal Catalysis
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PDF (941 kb)
Ren, Mi; Lu, Ming-Zhu; Loh, Teck-Peng:
Catalyst-Free Reactions under Biocompatible Conditions
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PDF (783 kb)
Sokolova, Olga O.; Dalling, Andrew G.; Bower, John F.:
C–C Bond Activations of Minimally Activated Cyclopropanes
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PDF (307 kb)
Pradhan, Suman; Das, Shoubhik:
Recent Advances on the Carboxylations of C(sp
3
)–H Bonds Using CO
2
as the Carbon Source
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PDF (802 kb)
Lee, Jeonghyo; Chang, Sukbok:
Versatile Utility of Cp*Co(III) Catalysts in C–H Amination under Inner- and Outer-Sphere Pathway
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PDF (1679 kb)
Jagtap, Rahul A.; Kanai, Motomu:
Sustainable and Mild Catalytic Acceptorless Dehydrogenations
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PDF (790 kb)
Issue 11/2023
Wang, Liu-Yang; Yang, Lan; Chen, Jie; Zhou, Ling:
Chiral Phosphoric Acid Catalyzed Asymmetric Cycloadditions: from Alkenes to Alkynes
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PDF (1055 kb)
Tong, Rongbiao:
The Untold Journey of Total Synthesis of Natural Products
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PDF (594 kb)
Issue 10/2023
Odagi, Minami; Nagasawa, Kazuo:
Total Synthesis of Fused Polycyclic Alkaloids Based on Oxidative Phenolic Couplings and Aza-Michael Reactions
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PDF (611 kb)
Yuan, Binbin; Oliveira, João C. A.; Ackermann, Lutz:
Understanding and Describing London Dispersion Effects in Transition-Metal-Catalyzed C–H Activations
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PDF (3031 kb)
Issue 09/2023
Ueda, Yohei; Tsurugi, Hayato; Mashima, Kazushi:
Cobalt-Catalyzed Alkynylation of Organic Compounds: Hydroalkynylation, Dehydrogenative Alkynylation, and Reductive Alkynylation
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PDF (682 kb)
Sumino, Shuhei; Ryu, Ilhyong:
Bromine-Radical-Mediated Bromoallylation of C–C Unsaturated Bonds: A Facile Access to 1,4-, 1,5-, 1,6-, and 1,7-Dienes and Related Compounds
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PDF (550 kb)
Issue 08/2023
Cai, Bin; Toh, Ren Wei; Ang, Hwee Ting; Wu, Jie; Panek, James S.:
Stereo- and Regioselective Synthesis of (
E
,
E
)-Dienes: Evolution from the Transition-Metal-Catalyzed Cross-Coupling to Titanium Alkoxide-Based Alkyne–Alkyne Reductive Coupling
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Sahu, Rajesh; Kapdi, Anant R.:
PTABS: A Unique Water-Soluble π-Acceptor Caged Phosphine
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PDF (1063 kb)
Issue 07/2023
Ambegave, Shivhar B.; Patil, Nitin T.:
Gold-Catalyzed Cross-Coupling and 1,2-Difunctionalization Reactions: A Personal Account
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Shivam, Shivam.; Chavan, Kailas A.; Chauhan, Amar N. S.; Erande, Rohan D.:
Recent Advances in [3+2]-Cycloaddition-Enabled Cascade Reactions: Application to Synthesize Complex Organic Frameworks
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PDF (974 kb)
Sahoo, Jigyansa; Panda, Jeetendra; Sahoo, Gokarneswar:
Unravelling the Development of Non-Covalent Organocatalysis in India
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PDF (1767 kb)
Basak, Shubhajit; Paul, Tripti; Maharana, Prabhat Kumar; Debnath, Bijoy; Punniyamurthy, Tharmalingam:
Transition-Metal-Catalyzed Directing-Group-Assisted C4-H Carbon–Carbon Bond Formation of Indole
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PDF (903 kb)
Neena, Neena; Chaudhri, Vishwas; Singh, Fateh V.; China, Hideyasu; Dohi, Toshifumi; Kumar, Ravi:
Synthetic Utility of the Vilsmeier–Haack Reagent in Organic Synthesis
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PH, Krushnamurthy; KS, Subramanya; Das, Simita; G., Dhananjaya; Mahanta, Nilkamal:
Recent Advancements in Bottromycin Biosynthesis
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PDF (838 kb)
Issue 06/2023
Parida, Keshaba N.; Moorthy, Jarugu Narasimha:
Catalytic Oxidations with
ortho
-Substituted Modified IBXs
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PDF (680 kb)
Saikia, Anil K.:
Synthesis of Heterocyclic Scaffolds via Prins, Oxonium-Ene and Related Cyclization Reactions
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PDF (1921 kb)
Kotha, Sambasivarao; Ansari, Saima; Gupta, Naveen Kumar:
Selectivity: A Goal for Synthetic Economy
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PDF (1560 kb)
Singh, Ajit Kumar; Kumar, Deepak; Singh, Baghendra; Indra, Arindam:
Replacing Anodic Oxygen Evolution Reaction with Organic Oxidation: The Importance of Metal (Oxy)Hydroxide Formation as the Active Oxidation Catalyst
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PDF (2569 kb)
Singh, Anupam Kumar; Shinde, Rupali Dasharath; Kumar, Jogendra; Bhadra, Sukalyan:
Functionalization of Alkyl Groups Adjacent to Azoles: Application to the Synthesis of α-Functionalized Carboxylic Acids
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PDF (826 kb)
Sunny, Steeva; Maingle, Mohit; Seth, Kapileswar:
Advances in Bifunctional Squaramide-Catalyzed Asymmetric Sulfa-Michael Addition: A Decade Update
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PDF (2946 kb)
Ranu, Brindaban C.; Adak, Laksmikanta; Mukherjee, Nirmalya; Ghosh, Tubai:
Benign-Metal-Catalyzed Carbon–Carbon and Carbon–Heteroatom Bond Formation
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PDF (1154 kb)
Issue 05/2023
Kretzschmar, Martin; Gulder, Tanja:
Discovering the Site-Selective Umpolung of Ketones Triggered by Hypervalent Fluoro-Iodanes – Why Investigating Side Reactions Matters!
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PDF (652 kb)
Langer, Peter:
Adventures in 1,1-Diphenylacetone Dianion Chemistry
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PDF (395 kb)
Issue 04/2023
Streuff, Jan:
Reductive Umpolung and Defunctionalization Reactions through Higher-Order Titanium(III) Catalysis
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PDF (490 kb)
Xu, Jing:
Total Synthesis of the Caged Diterpenoid Atropurpuran
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PDF (376 kb)
Issue 03/2023
Wei, Kua-Fei; Jiang, Xiao-Lei; Ru, Guang-Xin; Zhu, Xiu-Hong; Shen, Wen-Bo:
Recent Progress towards the Transition-Metal-Catalyzed Dearomatizing Spirocyclization Reactions of Indolyl Ynones
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PDF (761 kb)
Zard, Samir Z.:
Meanderings of a Curious Chemist
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PDF (520 kb)
Issue 02/2023
Zhou, Han; Liu, Yin-Ling; Tang, Shi:
Recent Advances on Radical-Mediated Cyanoalkylation/Cyanation using AIBN and Analogues as the Radical Sources
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PDF (811 kb)
Issue 01/2023
Hilt, Gerhard:
A Twenty-Year Survey in Low-Valent Cobalt-Catalyzed Transformations Comes to an End – A Farewell
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Cao, Jin; Zhu, Shou-Fei:
Chiral Proton-Transfer Shuttle Catalysts Promoted Enantioselective Nazarov Cyclization
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Issue 20/2022
Tan, Shen; Chen, Qi; Lan, Ping; Banwell, Martin G.:
Troponoid Compounds as Therapeutic Agents and as Targets and Templates for Chemical Synthesis
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Xiang, Shao-Hua; Cheng, Jun Kee; Tan, Bin:
The Application of 2-Naphthols in Asymmetric Synthesis of Atropisomers
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Issue 19/2022
Yudin, Andrei K.:
Synthetic Tools that Enable Synthesis and Understanding of Bioactive Macrocycles
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Driver, Tom G.:
Unlocking Electrophilic
N
-Aryl Intermediates from Aryl Azides, Nitroarenes, and Aryl Amines in Cyclization–Migration Reactions
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Issue 18/2022
Liu, Wei; Wang, Donglei; Zhang, Dekun; Yang, Xiaoyu:
Catalytic Kinetic Resolution and Desymmetrization of Amines
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Issue 17/2022
Taylor, Scott D.:
A Decade of Research on Daptomycin
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Langer, Peter:
Synthesis of Nitrogen Heterocycles by a C–C Cross-Coupling/Cycloisomerization Strategy
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Issue 16/2022
Langer, Peter:
Synthesis of Nitrogen Heterocycles by Domino C–N Coupling/Hydroamination Reactions
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Yu, Zhen; Wang, Li; Liu, Li; Wang, Meng; Yang, Hong:
No Sacrifice No Gain: Construction of Cleavable Bridged Macrobicyclic Olefins for Precision Polymers
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Issue 15/2022
Lu, Chao; Chen, Xi:
Flexible Piezoionic Strain Sensors toward Artificial Intelligence Applications
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Hirao, Toshikazu; Amaya, Toru:
Transformations of Main-Group Organometallics Induced by Transition Metals
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Issue 13/2022
Langer, Peter:
Palladium-Catalyzed Synthesis of Heterocyclic Ring Systems by Combination of Regioselective C–C with Twofold C–N Couplings
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Hajinasiri, Rahimeh:
Acetylenic Esters in Organic Synthesis
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Issue 12/2022
Lücke, Daniel; Kalesse, Markus:
Chiral Polyoxygenated Tertiary Alcohols through Kiyooka Aldol Reaction
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Kandappa, Sunil Kumar; Ahuja, Sapna; Singathi, Ravichandranath; Valloli, Lakshmy Kannadi; Baburaj, Sruthy; Parthiban, Jayachandran; Sivaguru, Jayaraman:
Using Restricted Bond Rotations to Enforce Excited-State Behavior of Organic Molecules
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Issue 11/2022
Wei, Yunlong; Wu, Xinxin; Zhu, Chen:
Radical Heteroarylation of Alkenes and Alkanes via Heteroaryl Migration
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Langer, Peter:
Cross-Coupling Reactions of Polyhalogenated Heterocycles
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Issue 10/2022
Bennett, Clay S.:
Evolution of a Reagent-Controlled Strategy for β-Selective
C
-Glycoside Synthesis
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Tian, Bing; Chen, Pinhong; Liu, Guosheng:
Palladium-Catalyzed Intermolecular Carbonylation-Based Difunctionalization of Alkenes
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Tom, Mai-Jan; Evans, P. Andrew:
Asymmetric Rhodium-Catalyzed Allylic Substitution Reactions with Nitrile-Stabilized Carbanions
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Issue 09/2022
Ghashghaei, Ouldouz; Rodríguez, Pau Nadal; Lavilla, Rodolfo:
Development of Heterocyclic Multicomponent Reactions through Guided Exploration: Direct, Reasonable and Unpredictable Processes
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Liu, Jingchun; Xi, Shuang; Tang, Yefeng:
Biomimetic Diels–Alder Reactions in Natural Product Synthesis: A Personal Retrospect
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O’Neill, Robert T.; Boulatov, Roman:
The Contributions of Model Studies for Fundamental Understanding of Polymer Mechanochemistry
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Issue 08/2022
Wan, Caiwen; Shi, Jiarong; Li, Yang:
Reactions of Sulfoxides with Benzynes
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Langer, Peter:
Adventures in 1,3-Selenazole Chemistry
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Esser, Birgit; Wössner, Jan S.; Hermann, Mathias:
Conjugated Nanohoops with Dibenzo[
a
,
e
]pentalenes as Nonalternant and Antiaromatic π-Systems
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Issue 07/2022
Laali, Kenneth K.; Kalkhambkar, Rajesh G.; Sutar, Suraj M.:
Recent Advances in the Synthesis of Diverse Libraries of Small-Molecule Building Blocks in Ionic Liquids (ILs)
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Wørmer, Gustav J.; Poulsen, Thomas B.:
The [4.3.0] Piperidine Alkaloids: Architectures, Biology, Biosyntheses, and the Complete Details of the Asymmetric Syntheses of Streptazone A and Abikoviromycin
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Issue 06/2022
Sekiya, Ryo; Harada, Kentaro; Nitta, Natsumi; Haino, Takeharu:
Resorcinarene-Based Supramolecular Capsules: Supramolecular Functions and Applications
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Shindo, Mitsuru; Iwata, Takayuki:
Cycloaddition Initiated by Ynolates: High-Energy Dianion Equivalents as a Molecular Glue
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Issue 05/2022
Bols, Mikael; Frihed, Tobias Gylling; Pedersen, Martin Jæger; Pedersen, Christian Marcus:
Silylated Sugars – Synthesis and Properties
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Ohmori, Ken; Suzuki, Keisuke:
Group-Selective Approaches to Complex Natural Product Synthesis: Three Examples of Diastereotopos-Selective Reactions
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Langer, Peter:
Synthesis of Purines and Related Molecules by Cyclization Reactions of Heterocyclic Enamines
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Issue 04/2022
Kiss, Loránd; Ouchakour, Lamiaa; Nonn, Melinda; Remete, Attila M.:
Application of Oxidative Ring Opening/Ring Closing by Reductive Amination Protocol for the Stereocontrolled Synthesis of Functionalized Azaheterocycles
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Berger, Florian; Ritter, Tobias:
Site-Selective Late-Stage C–H Functionalization via Thianthrenium Salts
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Issue 03/2022
Langer, Peter:
Domino Reactions of Chromones with Heterocyclic Enamines
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He, Yuli; Tao, Ran; Zhu, Shaolin:
Nickel Hydride Catalyzed Remote Hydroarylation of Olefins
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Hafezi, Nema; Mascal, Mark:
Chemistry of the Heterotriquinanes and Heterotriquinacenes
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Issue 02/2022
Mateos, Javier; Cuadros, Sara; Vega-Peñaloza, Alberto; Dell’Amico, Luca:
Unlocking the Synthetic Potential of Light-Excited Aryl Ketones: Applications in Direct Photochemistry and Photoredox Catalysis
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Cauwenbergh, Robin; Das, Shoubhik:
Photocatalysis: A Green Tool for Redox Reactions
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Issue 01/2022
Rugen, Christian J.; Alcarazo, Manuel:
α-Cationic Phosphines: from Curiosities to Powerful Ancillary Ligands
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Li, Xuechen:
Long Journey on Daptomycin
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Issue 20/2021
Carreiras, Maria do Carmo; Marco-Contelles, José:
Five-Membered-Ring-Fused Tacrines as Anti-Alzheimer’s Disease Agents
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Crusats, Joaquim; Moyano, Albert:
Absolute Asymmetric Catalysis, from Concept to Experiment: A Narrative
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Langer, Peter:
Synthesis and Reactions of 1,3,5-Tri- and 1,3,5,7-Tetracarbonyl Compounds
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Issue 19/2021
Kumar, Vinod:
Designed Synthesis of Diversely Substituted Hydantoins and Hydantoin-Based Hybrid Molecules: A Personal Account
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Benke, Zsanett; Nonn, Melinda; Remete, Attila M.; Fustero, Santos; Kiss, Loránd:
Diversity-Oriented Synthesis of Highly Functionalized Alicycles across Dipolar Cycloaddition/Metathesis Reaction
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Issue 18/2021
Iqbal, Shoaib; Sharif, Muhammad; Langer, Peter:
Suzuki–Miyaura Coupling Reactions of Fluorohalobenzenes
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Zhong, Zhuliang; Lyu, Mao-Yun; Ma, Hao-Ran; Wong, Henry N. C.; Peng, Xiao-Shui:
Pivotal Reactions in the Creation of the Polycyclic Skeleton of Cryptotrione
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Goetzke, F. Wieland; Fletcher, Stephen P.:
Additions to Racemates: A Strategy for Developing Asymmetric Cross-Coupling Reactions
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Issue 17/2021
Schulz, Stefan; Poth, Dennis; Peram, Pardha Saradhi; Hötling, Susann; Menke, Markus; Melnik, Kristina; Röpke, René:
Chemical Diversity of Volatile Macrocylic Lactones from Frogs
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Shear, Trevor A.; Johnson, Darren W.:
Main Group Supramolecular Chemistry Led to Surprising New Directions in the Self-Assembly of Organic Macrocycles, Cages, and Cyclophanes
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Issue 16/2021
Lipshutz, Bruce H.:
Illuminating a Path4914. Copyright 2016 Wiley for Organic Synthesis Towards Sustainability. No One Said It Would Be Easy…
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Issue 14/2021
Romero-Ibañez, Julio; Fuentes, Lilia; Sartillo-Piscil, Fernando:
Transition-Metal-Free Functionalization of Saturated and Unsaturated Amines to Bioactive Alkaloids Mediated by Sodium Chlorite
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Rubtsov, Aleksandr E.; Malkov, Andrei V.:
Developing a Methodology for Catalytic Asymmetric Crotylation of Aldehydes
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Floreancig, Paul E.:
Perrhenate Esters as Intermediates in Molecular Complexity-Increasing Reactions
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Tong, Shuo; Wang, Mei-Xiang:
Domino Reactions of Tertiary Enamides in Organic Synthesis
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Issue 12/2021
Sanford, Amberly B.; Jarvo, Elizabeth R.:
Harnessing C–O Bonds in Stereoselective Cross-Coupling and Cross-Electrophile Coupling Reactions
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Tucker, Zachary D.; Ashfeld, Brandon L.:
(4+1)-Cycloadditions Exploiting the Biphilicity of Oxyphosphonium Enolates and Rh
II
/Pd
II
-Stabilized Metallocarbenes for the Construction of Five-Membered Frameworks
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Issue 11/2021
Lübcke, Marvin; Szabó, Kálmán J.:
Diazocarbonyl Compounds in Organofluorine Chemistry
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Kuzuhara, Daiki; Yamada, Hiroko:
Porphyrinoids with Vinylene Bridges
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Issue 10/2021
Chen, Wufeng; Li, Jianfeng; Cui, Chunming:
Rare-Earth-Catalyzed Hydrosilylation and Dehydrogenative Coupling of Hydrosilanes
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Scholtes, Jan Felix; Trapp, Oliver:
Asymmetric Induction and Amplification in Stereodynamic Catalytic Systems by Noncovalent Interactions
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Issue 09/2021
Fleurisson, Claire; Benedetti, Erica; Micouin, Laurent:
Cyclic
cis
-1,3-Diamines Derived from Bicyclic Hydrazines: Synthesis and Applications
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Glueck, David S.:
Catalytic Asymmetric Synthesis of P-Stereogenic Phosphines: Beyond Precious Metals
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van Gemmeren, Manuel; List, Benjamin:
How and Why Crowd Reviewing Works
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Issue 08/2021
Rodríguez, Manuel R.; Díaz-Requejo, M. Mar; Pérez, Pedro J.:
Development of Molecular Complexity through Nitrene-Transfer Reactions Catalyzed by Copper and Silver Scorpionate Complexes
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Renata, Hans:
Exploration of Iron- and α-Ketoglutarate-Dependent Dioxygenases as Practical Biocatalysts in Natural Product Synthesis
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Issue 07/2021
Campillo-Alvarado, Gonzalo; MacGillivray, Leonard R.:
Opportunities Using Boron to Direct Reactivity in the Organic Solid State
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Tan, Dong-Xing; Han, Fu-She:
Synthetic Studies towards the Total Synthesis of Indole Alkaloids Containing Indolyl Lactam Frameworks
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Issue 06/2021
Ielo, Laura; Pillari, Veronica; Miele, Margherita; Castiglione, Davide; Pace, Vittorio:
Carbenoid-Mediated Homologation Tactics for Assembling (Fluorinated) Epoxides and Aziridines
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Orian, Laura; Bickelhaupt, F. Matthias:
Designing Rh(I)-Half-Sandwich Catalysts for Alkyne [2+2+2] Cycloadditions
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Taniguchi, Tsuyoshi:
Strategy for the Use of Molecular Oxygen in Organic Synthesis
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Issue 05/2021
Berthold, Dino; Breit, Bernhard:
Total Syntheses of Cylindrocyclophanes Exemplifying the Power of Transition-Metal Catalysis in Natural-Product Synthesis
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Gansäuer, Andreas:
From Enantioselective to Regiodivergent Epoxide Opening and Radical Arylation – Useful or Just Interesting?
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Beaver, Matthew G.; Caille, Seb; Farrell, Robert P.; Rötheli, Andreas R.; Smith, Austin G.; Tedrow, Jason S.; Thiel, Oliver R.:
Building Complexity and Achieving Selectivity through Catalysis – Case Studies from the Pharmaceutical Pipeline
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Nicolai, Stefano; Orcel, Ugo; Muriel, Bastian; Greenwood, Phillip D. G.; Buzzetti, Luca; Puriņš, Mikus; Waser, Jerome:
Palladium-Catalyzed Functionalization of Olefins and Alkynes: From Oxyalkynylation to Tethered Dynamic Kinetic Asymmetric Transformations (DYKAT)
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Issue 04/2021
Liu, Dan; Zhang, Jing; Chen, Yiyun:
Investigations on the 1,2-Hydrogen Atom Transfer Reactivity of Alkoxyl Radicals under Visible-Light-Induced Reaction Conditions
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Issue 03/2021
Solinski, Amy E.; Wuest, William M.:
Collaboration in Natural Product Total Synthesis: Carolacton – A Decade of Discovery
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Wang, Hai-Xu; Wu, Kai; Che, Chi-Ming:
Metal-Quinoid Carbene Chemistry: From Bonding to C–H Activation Catalysis
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Nechmad, Noy B.; Lemcoff, N. Gabriel:
Sulfur-Chelated Ruthenium Olefin Metathesis Catalysts
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Issue 02/2021
Huang, Yangjie; Zhang, Mengjia; Lin, Qi; Weng, Zhiqiang:
[(bpy)CuSCF
3
]: A Practical and Efficient Reagent for the Construction of C–SCF
3
Bonds
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Deimling, Max; Zens, Anna; Park, Natja; Hess, Christine; Klenk, Simon; Dilruba, Zarfishan; Baro, Angelika; Laschat, Sabine:
Adventures and Detours in the Synthesis of Hydropentalenes
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Issue 01/2021
Yamashita, Yasuhiro; Kobayashi, Shū:
New Dimensions of Brønsted Base Catalyzed Carbon–Carbon Bond-Forming Reactions
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Wang, Nai-Xing; Zhang, Lei-Yang; Wu, Yue-Hua; Xing, Yalan:
C(sp
3
)–H Bond Functionalization of Alcohols, Ketones, Nitriles, Ethers and Amides using
tert
-Butyl Hydroperoxide as a Radical Initiator
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Vine, Logan E.; Zerull, Emily E.; Schomaker, Jennifer M.:
Taming Nitrene Reactivity with Silver Catalysts
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Issue 20/2020
Yokoshima, Satoshi:
Synthesis of Polycyclic Natural Products through Skeletal Rearrangement
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Kotha, Sambasivarao; Tangella, Yellaiah:
Modular Approaches to Cyclopentanoids and their Heteroanalogs
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Issue 19/2020
Bard, Jeremy P.; Johnson, Darren W.; Haley, Michael M.:
Bumpy Roads Lead to Beautiful Places: The Twists and Turns in Developing a New Class of PN-Heterocycles
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Issue 18/2020
Talavera, María; Braun, Thomas:
Rhodium(I) Complexes as Useful Tools for the Activation of Fluoroolefins
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Abou-Hamdan, Hussein; Kouklovsky, Cyrille; Vincent, Guillaume:
Dearomatization Reactions of Indoles to Access 3D Indoline Structures
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Issue 17/2020
Chiba, Yusuke; Nakamura, Takashi; Matsuoka, Ryota; Nabeshima, Tatsuya:
Synthesis and Functions of Oligomeric and Multidentate Dipyrrin Derivatives and their Complexes
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Huang, Pei-Qiang:
Procedure-Economical, Enantioselective Total Syntheses of Polycyclic Natural Products and Analogues Containing a 3a-Hydroxyhexahydropyrrolo[2,3-
b
]indole-2-carboxylic Acid Residue
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Issue 16/2020
Almohseni, Hasanain A. A.; Hodgson, David M.:
Evolution of a Cycloaddition–Rearrangement Approach to the Squalestatins: A Quarter-Century Odyssey
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Suresh, Kuthuru; López-Mejías, Vilmalí; Roy, Saikat; Camacho, Daniel F.; Matzger, Adam J.:
Leveraging Framework Instability: A Journey from Energy Storage to Drug Delivery
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Issue 15/2020
Hooley, Richard J.:
No, Not That Way, the Other Way: Creating Active Sites in Self-Assembled Host Molecules
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Wang, Yujie; Liu, Qiang:
Manganese-Catalyzed Dehydrogenative/Deoxygenative Coupling of Alcohols
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Issue 14/2020
Pietrasiak, Ewa; Lee, Eunsung:
Activation of C–F, Si–F, and S–F Bonds by N-Heterocyclic Carbenes and Their Isoelectronic Analogues
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Dondoni, Alessandro:
Selected Research Topics of the Dondoni Group over the Last Two Decades (2000–2020)
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Issue 13/2020
Watson, Allan J. B.:
The Problem with Problems: Fundamental to Applied Research Using Palladium
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Mori, Tadashi:
Relevance of the Entropy Factor in Stereoselectivity Control of Asymmetric Photoreactions
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Issue 12/2020
Peng, Jingying; Thomas, Stephen P.:
Activation Strategies for Earth-Abundant Metal Catalysis
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Padín, Damián; Varela, Jesús A.; Saá, Carlos:
Recent Advances in Ruthenium-Catalyzed Carbene/Alkyne Metathesis (CAM) Transformations
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Issue 11/2020
Feng, Jiyao; Zhang, Zhen; Li, Xuefeng; Zhang, Zhenhua:
Palladium-Catalyzed Carbonylation of Azides and Mechanistic Studies
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Li, Dongxu; Shao, Xiangfeng:
Chemistry of Hetera-buckybowl Trichalcogenasumanenes
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Issue 10/2020
Deb, Titas; Franzini, Raphael M.:
The Unique Bioorthogonal Chemistry of Isonitriles
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Christoffers, Jens; Wickleder, Mathias S.:
Synthesis of Aromatic and Aliphatic Di-, Tri-, and Tetrasulfonic Acids
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Issue 09/2020
Shaw, Jared T.:
C–H Insertion Reactions of Donor/Donor Carbenes: Inception, Investigation, and Insights
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Kiyokawa, Kensuke; Minakata, Satoshi:
Iodine-Based Reagents in Oxidative Amination and Oxygenation
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Issue 08/2020
Ghorai, Sourav; Lee, Daesung:
Aryne-Based Multicomponent Coupling Reactions
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Kobayashi, Yusuke; Takemoto, Yoshiji:
Reactions Catalyzed by 2-Halogenated Azolium Salts: From Halogen-Bond Donors to Brønsted-Acidic Salts
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Issue 07/2020
Kadokawa, Jun-ichi:
Synthesis of Amylosic Supramolecular Materials by Glucan Phosphorylase-Catalyzed Enzymatic Polymerization According to the Vine-Twining Approach
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Freeman, Jared L.; Li, Freda F.; Furkert, Daniel P.; Brimble, Margaret A.:
Synthetic Studies Towards Spirocyclic Imine Marine Toxins Using
N
-Acyl Iminium Ions as Dienophiles in Diels–Alder Reactions
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Issue 06/2020
Sohtome, Yoshihiro; Sodeoka, Mikiko:
Multiselective Catalytic Asymmetric Reactions Using α-Keto Esters as Pronucleophiles
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Rossi, Sergio; Benincori, Tiziana; Raimondi, Laura Maria; Benaglia, Maurizio:
3,3′-Bithiophene-Based Chiral Bisphosphine Oxides as Organocatalysts in Silicon-Derived Lewis Acid Mediated Reactions
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Issue 05/2020
Fernandes, Rodney A.; Kumari, Anupama; Pathare, Ramdas S.:
A Decade with Dötz Benzannulation in the Synthesis of Natural Products
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Takao, Ken-ichi; Ogura, Akihiro; Yoshida, Keisuke; Simizu, Siro:
Total Synthesis of Natural Products Using Intramolecular Nozaki–Hiyama–Takai–Kishi Reactions
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Issue 04/2020
Yusubov, Mekhman S.; Postnikov, Pavel; Yoshimura, Akira; Zhdankin, Viktor V.:
Benziodoxole-Derived Organosulfonates: The Strongest Hypervalent Iodine Electrophiles and Oxidants
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Clementson, Sebastian; Jessing, Mikkel; Vital, Paulo J.; Kristensen, Jesper L.:
Development of a Divergent Route to Erythrina Alkaloids
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Issue 03/2020
Zeng, Xiaoming:
Recent Advances in Chromium-Catalyzed Organic Transformations
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Liu, Junzhi; Feng, Xinliang:
Bottom-Up Synthesis of Nitrogen-Doped Polycyclic Aromatic Hydrocarbons
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Issue 02/2020
Leon, Noel J.; Yu, Hsien-Cheng; Mazzacano, Thomas J.; Mankad, Neal P.:
Pursuit of C–H Borylation Reactions with Non-Precious Heterobimetallic Catalysts: Hypothesis-Driven Variations on a Design Theme
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Stephens, Thomas C.; Unsworth, William P.:
Consecutive Ring-Expansion Reactions for the Iterative Assembly of Medium-Sized Rings and Macrocycles
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Issue 01/2020
Witzig, Reto M.; Sparr, Christof:
Synthesis of Enantioenriched Tetra-
ortho
-3,3′-substituted Biaryls by Small-Molecule-Catalyzed Noncanonical Polyketide Cyclizations
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Li, Li; Wei, Yun-Long; Xu, Li-Wen:
Organosilicon-Mediated Organic Synthesis (SiMOS): A Personal Account
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Issue 20/2019
Walker, Johannes C. L.; Oestreich, Martin:
Ionic Transfer Reactions with Cyclohexadiene-Based Surrogates
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Coates, Greg; Rekhroukh, Feriel; Crimmin, Mark R.:
Breaking Carbon–Fluorine Bonds with Main Group Nucleophiles
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Issue 19/2019
Xiao, Yan; Hu, Weiming; Sun, Song; Yu, Jin-Tao; Cheng, Jiang:
Recent Advances in the Synthesis of Acridines and Phenazines
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Niquille, David L.; Hansen, Douglas A.; Hilvert, Donald:
Reprogramming Nonribosomal Peptide Synthesis by Surgical Mutation
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Issue 18/2019
Tan, Tong-De; Chen, Yang-Bo; Fan, Xin-Yang; Ye, Long-Wu:
Recent Progress in the Copper-Catalyzed Cascade Cyclization Involving Intramolecular Hydroamination of Terminal Alkynes
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Xiao, Yan; Sun, Song; Yu, Jin-Tao; Cheng, Jiang:
Recent Advances in the Synthesis of Thiadiazoles
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Kilbinger, Andreas F. M.:
Fun
c
tional End Groups in Living Ring-Opening Metathesis Polymerization
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Issue 17/2019
Li, Zhen; Li, Xin; Cheng, Jin-Pei:
Recent Progress in Equilibrium Acidity Studies of Organocatalysts
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Issue 16/2019
Weinreb, Steven M.:
Nitrosoalkenes: Underappreciated Reactive Intermediates for Formation of Carbon–Carbon Bonds
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Mai, Juri; Ott, Sascha:
The Fascinating World of Phosphanylphosphonates: From Acetylenic Phosphaalkenes to Reductive Aldehyde Couplings
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Issue 15/2019
Bakhtiari, Atefeh; Safaei-Ghomi, Javad:
Effects of Chiral Ligands on the Asymmetric Carbonyl-Ene Reaction
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Ghadwal, Rajendra S.:
Stable Carbon-Centered Radicals Based on N-Heterocyclic Carbenes
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Issue 14/2019
Arisawa, Mieko; Yamaguchi, Masahiko:
Rhodium-Catalyzed Synthesis of Organosulfur Compounds using Sulfur
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Lacharity, Jacob J.; Zakarian, Armen:
Evolution of a Chemical Strategy Toward the Synthesis of Unsymmetrically Oxidized
Nuphar
Alkaloids
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PDF (511 kb)
Issue 13/2019
Li, Chao-Jun; Huang, Jianlin; Dai, Xi-Jie; Wang, Haining; Chen, Ning; Wei, Wei; Zeng, Huiying; Tang, Jianting; Li, Chenchen; Zhu, Dianhu; Lv, Leiyang:
An Old Dog with New Tricks: Enjoin Wolff–Kishner Reduction for Alcohol Deoxygenation and C–C Bond Formations
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Zhou, Zhe; Kürti, László:
Electrophilic Amination: An Update
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Issue 12/2019
Yoshino, Tatsuhiko; Matsunaga, Shigeki:
Cp*Co
III
-Catalyzed C–H Functionalization and Asymmetric Reactions Using External Chiral Sources
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Giannis, Athanassios; Mousavizadeh, Farnoush:
On Artemisinin, Cyclopamine, D-Isocitric acid, Hyperforin, Epigenetics, Sialic Acid, and More
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Issue 11/2019
Schitter, Theresa; Reding, Andreas; Werz, Daniel B.:
Cascades Involving
anti
-Carbopalladation Steps: From Our Initial Hypothesis to Natural Product Synthesis
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Servatius, Phil; Junk, Lukas; Kazmaier, Uli:
Peptide Modifications: Versatile Tools in Peptide and Natural Product Syntheses
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Issue 10/2019
Hu, Ben-Lin; Baumgarten, Martin:
Thiadiazoloquinoxalines
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Kamitanaka, Tohru; Morimoto, Koji; Dohi, Toshifumi; Kita, Yasuyuki:
Controlled-Coupling of Quinone Monoacetals by New Activation Methods: Regioselective Synthesis of Phenol-Derived Compounds
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Issue 09/2019
Kiraly, Peter; Morris, Gareth A.; Quanxiu, Liu; Nilsson, Mathias:
Sharpening Up Your Spectra: Broadband Homonuclear Decoupling in HSQC by Real-Time Pure Shift Acquisition
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Liu, Xiang; Huang, Yu; Meng, Xu; Li, Jihui; Wang, Dong; Chen, Yongxin; Tang, Dong; Chen, Baohua:
Recent Developments in the Synthesis of Nitrogen-Containing Heterocycles through C–H/N–H Bond Functionalizations and Oxidative Cyclization
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Mathew, Thomas; Gurung, Laxman; Roshandel, Sahar; Munoz, Socrates B.; Prakash, G. K. Surya:
Halotrimethylsilane-Nitrite/Nitrate Salts: Efficient and Versatile Reagent System for Diverse Organic Synthetic Transformations
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Issue 08/2019
Tang, Jie; Chen, Dan; Zhang, Gen; Yang, Hongwei; Cheng, Guangbin:
A “Green” Primary Explosive: Design, Synthesis, and Testing
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Martinez-Cuezva, Alberto; Lopez-Leonardo, Carmen; Alajarin, Mateo; Berna, Jose:
Stereocontrol in the Synthesis of β-Lactams Arising from the Interlocked Structure of Benzylfumaramide-Based Hydrogen-Bonded [2]Rotaxanes
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Issue 07/2019
Zhang, Yuebao; Lu, Ji; Li, Hongze; Sun, Xianwei; Gao, Lu; Song, Zhenlei:
Total Synthesis of Bryostatin 8 and (–)-Exiguolide: Applications of an Organosilane Strategy
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Brewster, James T.; Anguera, Gonzalo; Sessler, Jonathan L.:
Expanding the Porphycene Core: Modification and Metalation
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Issue 06/2019
Canesi, Sylvain:
Rapid Formation of Advanced Scaffolds from Phenols and Anilines
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Hassan, Zahid; Langer, Peter:
Synthesis of Chlorinated Arenes and Hetarenes by One-Pot Cyclizations of 1,3-Bis-silyl Enol Ethers
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Lim, Hee Nam; Xing, Dong; Dong, Guangbin:
Transition-Metal-Catalyzed Ketone α-Alkylation and Alkenylation with Simple Alkenes and Alkynes through a Dual Activation Strategy
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Zhou, Bo; Lu, Ailan; Zhang, Yanghui:
Pd-Catalyzed C–H Silylation Reactions with Disilanes
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Issue 05/2019
Harmata, Michael:
Fun with (4+3)-Cycloadditions
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Wang, Kang; Wang, Jianbo:
Transition-Metal-Catalyzed Cross-Coupling with Non-Diazo Carbene Precursors
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Issue 04/2019
Xiao, Li-Jun; Ye, Meng-Chun; Zhou, Qi-Lin:
Nickel-Catalyzed Highly Atom-Economical C–C Coupling Reactions with π Components
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Kato, Kenta; Segawa, Yasutomo; Itami, Kenichiro:
Symmetric Multiple Carbohelicenes
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Issue 03/2019
Kräutler, Bernhard:
Chlorophyll Breakdown – How Chemistry Has Helped to Decipher a Striking Biological Enigma
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Schulz, Lara; Waldvogel, Siegfried R.:
Solvent Control in Electro-Organic Synthesis
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Issue 02/2019
Zhao, Kun; Ding, Linlin; Gu, Zhenhua:
Development of New Electrophiles in Palladium/Norbornene-Catalyzed
ortho
-Functionalization of Aryl Halides
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Åkerbladh, Linda; Odell, Luke R.; Larhed, Mats:
Palladium-Catalyzed Molybdenum Hexacarbonyl-Mediated Gas-Free Carbonylative Reactions
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Issue 01/2019
Wu, Xiaopeng; Sun, Song; Yu, Jin-Tao; Cheng, Jiang:
Recent Applications of α-Carbonyl Sulfoxonium Ylides in Rhodium- and Iridium-Catalyzed C–H Functionalizations
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Cocq, Kévin; Barthes, Cécile; Rives, Arnaud; Maraval, Valérie; Chauvin, Remi:
Synthesis of Functional
Carbo
-benzenes with Functional Properties: The C
2
Tether Key
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Issue 20/2018
Karanam, Praneeth; Reddy, Ganapuram Madhusudhan; Lin, Wenwei:
Strategic Exploitation of the Wittig Reaction: Facile Synthesis of Heteroaromatics and Multifunctional Olefins
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Cai, Xinpei; Bai, Yu; Dai, Mingji:
Total Syntheses of Spinosyn A
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Issue 19/2018
Han, Xiuling; Lu, Xiyan:
Palladium(II)-Catalyzed Redox-Neutral Cyclizations of Alkynes Containing Alkenyl or Electrophilic Functional Groups: A Convenient Synthesis of Carbocycles and Heterocycles
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Shockley, Samantha E.; Hethcox, J. Caleb; Stoltz, Brian M.:
Intermolecular Stereoselective Iridium-Catalyzed Allylic Alkylation: An Evolutionary Account
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Issue 18/2018
Kotha, Sambasivarao; Lahiri, Kakali; Sreevani, Gaddamedi:
Design and Synthesis of Aromatics through [2+2+2] Cyclotrimerization
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Panchal, Santosh P.; Reddy, Baddigam Kiran; Anand, Venkataramanarao G.:
Syntheses and Redox Chemistry of Antiaromatic Core-Modified Isophlorinoids
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Issue 17/2018
García-Morales, Cristina; Echavarren, Antonio M.:
From Straightforward Gold(I)-Catalyzed Enyne Cyclizations to more Demanding Intermolecular Reactions of Alkynes with Alkenes
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te Grotenhuis, Colet; de Bruin, Bas:
Radical-type Reactions Controlled by Cobalt: From Carbene Radical Reactivity to the Catalytic Intermediacy of Reactive
o
-Quinodimethanes
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Issue 16/2018
Kuninobu, Yoichiro:
Development of Novel C–H Bond Transformations and Their Application to the Synthesis of Organic Functional Molecules
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Barbazanges, Marion; Fensterbank, Louis:
The Invention of New Methodologies: An Opportunity for Dating Natural Products
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Issue 15/2018
Kumar, Pradeep; Sharma, Brijesh M.:
Proline-Catalyzed Asymmetric α-Amination in the Synthesis of Bioactive Molecules
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Himmel, Hans-Jörg:
Guanidines as Reagents in Proton-Coupled Electron-Transfer Reactions and Redox Catalysts
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Issue 14/2018
Wang, Bingbing; Sun, Song; Cheng, Jiang:
The
n
-
dig
-Cyclization (
n
= 5, 6) of Alkynes Involving Fixation of CO
2
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Herzon, Seth B.:
Emergent Properties of Natural Products
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Issue 13/2018
Zhang, Xiaheng; Yu, Biao:
Tackling the Challenge of the Total Synthesis of Periploside A
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Issue 12/2018
Gu, Yueqing; Tan, Ceheng; Gong, Jianxian; Yang, Zhen:
Diversity-Oriented Synthesis of Natural Products via Gold-Catalyzed Cascade Reactions
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Issue 11/2018
Zuo, Ziqing; Wen, Huanan; Liu, Guixia; Huang, Zheng:
Cobalt-Catalyzed Hydroboration and Borylation of Alkenes and Alkynes
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Issue 10/2018
Kawato, Yuji; Hamashima, Yoshitaka:
Enantioselective Bromocyclization of Allylic Amides Mediated by Phosphorus Catalysis
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Issue 09/2018
Abdelraheem, Eman M. M.; Shaabani, Shabnam; Dömling, Alexander:
Artificial Macrocycles
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Issue 08/2018
Xie, Xiaoni; Zu, Liansuo:
Skeletal Rearrangements as Strategies for the Total Syntheses of Indole Alkaloids
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Issue 07/2018
Chen, Juan; Liu, Bo:
Total Synthesis of Natural Terpenoids: Inspired but Not Limited by Biohypothesis
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Issue 06/2018
Jessen, H. J.:
The Hitchhiker’s Guide to Organophosphate Chemistry
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Issue 05/2018
Liu, Xiao-Fang; Li, Xiao-Ya; Qiao, Chang; He, Liang-Nian:
Transition-Metal-Free Catalysis for the Reductive Functionalization of CO
2
with Amines
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Issue 04/2018
Shintani, Ryo:
Recent Progress in Catalytic Enantioselective Desymmetrization of Prochiral Organosilanes for the Synthesis of Silicon-Stereogenic Compounds
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Moore, Bradley S.:
Asymmetric Alkene and Arene Halofunctionalization Reactions in Meroterpenoid Biosynthesis
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Issue 03/2018
Curti, Claudio; Sartori, Andrea; Battistini, Lucia; Zanardi, Franca:
Exploring the Remote Reactivity of π-Extended Carbonyl Compounds: The Vinylogous Alkylidene Malononitrile Activation Strategy
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Naidu, Gonna Somu; Singh, Rekha; Ghosh, Sunil K.:
[3]Dendralenes: Synthesis, Reactivity Studies and Employment in Diversity-Oriented Synthesis of Complex Polycyclic Scaffolds
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Issue 02/2018
Meng, Lingkui; Zeng, Jing; Wan, Qian:
Interrupted Pummerer Reaction in Latent/Active Glycosylation
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Liu, Ren-Rong; Liang, Ren-Xiao; Jia, Yi-Xia:
Construction of Benzylic Stereogenic Carbon Centers through Enantioselective Arylation Reactions
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Issue 01/2018
Li, Lei:
Using Organic Synthesis and Chemical Analysis to Understand the Photochemistry of Spore Photoproduct and Other Pyrimidine Dimers
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Gueyrard, David:
Extension of the Modified Julia Olefination on Carboxylic Acid Derivatives: Scope and Applications
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Issue 20/2017
Quiclet-Sire, Béatrice; Zard, Samir Z.:
Convergent Routes to Pyrroles Exploiting the Unusual Radical Chemistry of Xanthates – An Overview
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Davies, Stephen G.; Fletcher, Ai M.; Roberts, Paul M.; Thomson, James E.:
Asymmetric Synthesis of Pyrrolizidines, Indolizidines and Quinolizidines via a Double Reductive Cyclisation Protocol
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Shaaban, Saad; Maulide, Nuno:
Metal-Free Redox Transformations for C–C and C–N Bond Construction
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Liu, Wenbo; Li, Chao-Jun:
Recent Synthetic Applications of Catalyst-Free Photochemistry
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Issue 19/2017
Bull, James A.; Degennaro, Leonardo; Luisi, Renzo:
Straightforward Strategies for the Preparation of NH-Sulfoximines: A Serendipitous Story
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Prabagar, B.; Ghosh, Nayan; Sahoo, Akhila K.:
Cyclization and Cycloisomerization of π-Tethered Ynamides: An Expedient Synthetic Method to Construct Carbo- and Heterocycles
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Issue 18/2017
Husain, Syed Masood; Müller, Michael:
Fungal Dihydroxynaphthalene-Melanin: Diversity-Oriented Biosynthesis through Enzymatic and Non-enzymatic Transformations
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Paraja, Miguel; Plaza, Manuel; Valdés, Carlos:
Transition-Metal-Free Reactions Between Boronic Acids and
N
-Sulfonylhydrazones or Diazo Compounds: Reductive Coupling Processes and Beyond
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Issue 17/2017
Saha, Mrinmoy; Carter, Rich G.:
Lycopodium
Alkaloids: An Intramolecular Michael Reaction Approach
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PDF (607 kb)
Wang, Qiang; Shi, Min:
Synthesis of Cyclic and Heterocyclic Compounds via Gold-Catalyzed Reactions
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Issue 16/2017
Do, Jean-Louis; Friščić, Tomislav:
Chemistry 2.0: Developing a New, Solvent-Free System of Chemical Synthesis Based on Mechanochemistry
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May, Jeremy A.; Nguyen, Thien S.; Nguyen, Truong N.; Le, Phong Q.; Chen, Po-An; Vallakati, Ravikrishna:
Pursuit of Enantioselective Synthesis of Heterocycle-Bearing Stereocenters: The Development of a Stereocontrolled BINOL-Catalyzed Conjugate Addition of Organoboron Nucleophiles
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Issue 15/2017
Komiyama, Takeshi; Minami, Yasunori; Hiyama, Tamejiro:
Recent Progress in the Cross-Coupling Reaction Using Triorganosilyl-Type Reagents
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Biafora, Agostino; Gooßen, Lukas J.:
Thieme Chemistry Journals Awardees – Where Are They Now? New Reaction Mode in Carboxylate-Directed C–H Functionalizations: Carboxylates as Deciduous Directing Groups
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Issue 14/2017
Morimoto, Koji; Dohi, Toshifumi; Kita, Yasuyuki:
Metal-free Oxidative Cross-Coupling Reaction of Aromatic Compounds Containing Heteroatoms
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Deng, Yongming; Cheng, Qing-Qing; Doyle, Michael P.:
Asymmetric [3+3] Cycloaddition for Heterocycle Synthesis
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Issue 13/2017
Macmillan, Derek:
Going Round in Circles with N→S Acyl Transfer
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Caruana, Lorenzo; Fochi, Mariafrancesca; Bernardi, Luca:
Enantioselective Approaches to 3,4-Annulated Indoles Using Organocatalytic Domino Reactions
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PDF (423 kb)
Issue 12/2017
Du, Guangyan; Wang, Gaopeng; Ma, Wenjing; Yang, Qianqian; Bao, Wenli; Liang, Xuefeng; Zhu, Lizhi; Lee, Chi-Sing:
Syntheses of Diverse Natural Products via Dual-Mode Lewis Acid Induced Cascade Cyclization Reactions
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Amyes, Tina L.; Richard, John P.:
Substituent Effects on Carbon Acidity in Aqueous Solution and at Enzyme Active Sites
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Issue 11/2017
Yamamoto, Yoshihiko:
Synthesis of Fused Furans and Thiophenes via Ruthenium-Catalyzed Atom-Transfer [2+2+1] Cycloadditions of α,ω-Diynes
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Yamamoto, Eiji; Maeda, Satoshi; Taketsugu, Tetsuya; Ito, Hajime:
Transition-Metal-Free Boryl Substitution Using Silylboranes and Alkoxy Bases
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Issue 10/2017
Chen, Lei; Chen, Fen-Er:
Total Synthesis of Camptothecins: An Update
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Singh, Priyanka; Guo, Qi; Kohen, Amnon:
Chemoenzymatic Synthesis of Ubiquitous Biological Redox Cofactors
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Issue 09/2017
Beeck, Sebastian; Wegner, Hermann A.:
Thieme Chemistry Journals Awardees – Where Are They Now? Aromaticity as a Source for Strain Energy? Synthesis of Curved Polycyclic Aromatic Structures via [2+2+2] Cycloaddition Reactions
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Vidal, Fernando; Chen, Eugene Y.-X.:
Precision Polymer Synthesis via Chemoselective, Stereoselective, and Living/Controlled Polymerization of Polar Divinyl Monomers
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Issue 08/2017
Glavač, Danijel; Gredičak, Matija:
Organocatalytic Asymmetric Transformations of 3-Substituted 3-Hydroxyisoindolinones
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Oliveira, Joana; Mateus, Nuno; de Freitas, Victor:
Wine-Inspired Chemistry: Anthocyanin Transformations for a Portfolio of Natural Colors
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Issue 07/2017
Ouyang, Jie; Mi, Xianwei; Wang, Yan; Hong, Ran:
Crossing the Ring: A Journey of the Nitroso-ene Reaction
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Schmid, Thibault E.; Dumas, Adrien; Colombel-Rouen, Sophie; Crévisy, Christophe; Baslé, Olivier; Mauduit, Marc:
From Environmentally Friendly Reusable Ionic-Tagged Ruthenium-Based Complexes to Industrially Relevant Homogeneous Catalysts: Toward a Sustainable Olefin Metathesis
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Issue 06/2017
Chen, Kai; Zhu, Shifa:
NHC–AuCl/Selectfluor: An Efficient Catalytic System for π-Bond Activation
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Petermichl, Markus; Schobert, Rainer:
3-Acyltetramic Acids: A Decades-Long Approach to a Fascinating Natural Product Family
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Issue 05/2017
Rajasekhar, Sreerama; Maiti, Barnali; Chanda, Kaushik:
A Decade Update on Benzoxazoles, a Privileged Scaffold in Synthetic Organic Chemistry
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Haghshenas, Pouyan; Langdon, Steven M.; Gravel, Michel:
Thieme Chemistry Journals Awardees – Where Are They Now?
Carbene Organocatalysis for Stetter, Benzoin, Domino, and Ring-Expansion Reactions
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Issue 04/2017
Bai, Cui-Bing; Wang, Nai-Xing; Xing, Yalan; Lan, Xing-Wang:
Progress on Chiral NAD(P)H Model Compounds
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Levens, Alison; Lupton, David W.:
All-Carbon (4
+
2) Annulations Catalysed by N-Heterocyclic Carbenes
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PDF (752 kb)
Issue 03/2017
McCallum, Terry; Rohe, Samantha; Barriault, Louis:
Thieme Chemistry Journals Awardees – Where Are They Now?
What’s Golden: Recent Advances in Organic Transformations Using Photoredox Gold Catalysis
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Renzi, P.; Bella, M.:
Design of Experiments: A Rational Approach Toward Non-Covalent Asymmetric Organocatalysis
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PDF (402 kb)
Issue 02/2017
Cheng, Ming-Xing; Yang, Shang-Dong:
Recent Advances in the Enantioselective Oxidative α-C–H Functionalization of Amines
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PDF (1073 kb)
Peng, Jin-Bao; Qi, Xinxin; Wu, Xiao-Feng:
Recent Achievements in Carbonylation Reactions: A Personal Account
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Issue 01/2017
Susick, Robert B.; Morrill, Lucas A.; Picazo, Elias; Garg, Neil K.:
Pardon the Interruption: A Modification of Fischer’s Venerable Reaction for the Synthesis of Heterocycles and Natural Products
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PDF (1442 kb)
Pascal, Robert; Pross, Addy:
A Roadmap toward Synthetic Protolife
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PDF (402 kb)
Hud, Nicholas V.:
Our Odyssey to Find a Plausible Prebiotic Path to RNA: The First Twenty Years
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Agerschou, Emil Dandanell; Mast, Christof B.; Braun, Dieter:
Emergence of Life from Trapped Nucleotides? Non-Equilibrium Behavior of Oligonucleotides in Thermal Gradients
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Issue 20/2016
Waser, Jerome:
Benziodoxol(on)e Reagents as Tools in Organic Synthesis: The Background behind the Discovery at the Laboratory of Catalysis and Organic Synthesis
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Liang, Hanbing; Liu, Hui; Jiang, Xuefeng:
Research on the Conversion of α-Hydroxy Ketones into 1,2-Diketones and Subsequent Transformations
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Issue 19/2016
Wu, Shuke; Liu, Ji; Li, Zhi:
Organic Synthesis via Oxidative Cascade Biocatalysis
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PDF (2795 kb)
Sun, Xiaoyang; Yu, Shouyun:
Visible-Light-Promoted and Photoredox-Catalyzed Radical Addition to Triple Bonds
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Issue 18/2016
Meng, Guangrong; Shi, Shicheng; Szostak, Michal:
Cross-Coupling of Amides by N–C Bond Activation
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Metternich, J. B.; Gilmour, R.:
Photocatalytic
E
→
Z
Isomerization of Alkenes
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Issue 17/2016
Land, Michael A.; Clyburne, Jason A. C.:
N
-Heterocyclic Carbenes, Ionic Liquids, and Reactive Small Molecules: A Conversation between a Student and His Professor
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Nair, Divya K.; Kumar, Tarun; Namboothiri, Irishi N. N.:
α-Functionalization of Nitroalkenes and Its Applications in Organic Synthesis
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Issue 16/2016
Nemoto, Tetsuhiro; Hamada, Yasumasa:
Synthesis of Spirocyclic and Fused Cyclic Compounds by Transition-Metal-Catalyzed Intramolecular Friedel–Crafts-Type Reactions of Phenol Derivatives
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Pannecoucke, Xavier; Poisson, Thomas:
Introduction of Functionalized Difluoromethylated Building Blocks Mediated or Catalyzed by Copper
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PDF (588 kb)
Issue 15/2016
Li, Chengxi; Chen, Dongping; Tang, Wenjun:
Addressing the Challenges in Suzuki–Miyaura Cross-Couplings by Ligand Design
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PDF (3915 kb)
Issue 14/2016
Unsworth, William P.; Taylor, Richard J. K.:
Direct Imine Acylation: A Versatile Method for the Synthesis of Nitrogen-Containing Heterocycles, Spirocycles and Natural Products
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Sygula, Andrzej:
Corannulene-Adorned Molecular Receptors for Fullerenes Utilizing the π–π Stacking of Curved-Surface Conjugated Carbon Networks. Design, Synthesis and Testing
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Issue 13/2016
Hashim, Mohamed I.; Hsu, Chia-Wei; Le, Ha T. M.; Miljanić, Ognjen Š.:
Organic Molecules with Porous Crystal Structures
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Gobbo, Pierangelo; Workentin, Mark S.:
Maleimide-Modified Gold Nanoparticles (AuNPs): A Versatile Platform for Interfacial Click Reactions Leading to Chemically Modified AuNPs
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Issue 12/2016
Yorimitsu, Hideki; Vasu, Dhananjayan; Bhanuchandra, M.; Murakami, Kei; Osuka, Atsuhiro:
Aromatic Metamorphosis of Dibenzothiophenes
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Granzhan, Anton; Ihmels, Heiko:
Playing Around with the Size and Shape of Quinolizinium Derivatives: Versatile Ligands for Duplex, Triplex, Quadruplex and Abasic Site-Containing DNA
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Issue 11/2016
Rajbongshi, Kamal Krishna; Borah, Arun Jyoti; Phukan, Prodeep:
N
,
N
-Dibromo-
p
-Toluenesulfonamide (TsNBr
2
): A Promising Alternative Bromo-Organic Reagent
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PDF (1372 kb)
Li, Hongji; Miao, Tao; Wang, Min; Li, Pinhua; Wang, Lei:
Recent Advances in Exploring Diverse Decarbonylation, Decarboxylation and Desulfitation Coupling Reactions for Organic Transformations
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Issue 10/2016
Aradi, Klára; Tóth, Balázs L.; Tolnai, Gergely L.; Novák, Zoltán:
Diaryliodonium Salts in Organic Syntheses: A Useful Compound Class for Novel Arylation Strategies
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Dolfen, Jeroen; De Kimpe, Norbert; D’hooghe, Matthias:
Deployment of Small-Ring Azaheterocycles as Building Blocks for the Synthesis of Organofluorine Compounds
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Issue 09/2016
Allen, Matthew J.:
Aqueous Lanthanide Chemistry in Asymmetric Catalysis and Magnetic Resonance Imaging
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Dong, Weipeng; Chen, Zhengkai; Xu, Jianfeng; Miao, Maozhong; Ren, Hongjun:
Synthesis of Benzo-Fused Cyclic Compounds via Intramolecular Cyclization of Aryltriazenes
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Issue 08/2016
Wan, Kanny K.; Shenvi, Ryan A.:
Conjuring a Supernatural Product – DelMarine
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Suess, Alison M.; Lalic, Gojko:
Copper-Catalyzed Hydrofunctionalization of Alkynes
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Gravel, Edmond; Namboothiri, Irishi N. N.; Doris, Eric:
Supramolecular Assembly of Gold Nanoparticles on Carbon Nanotubes and Catalysis of Selected Organic Transformations
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