Synfacts
Issue 01 · January 2010
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SYNFORM
ISSUE 2010/01
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Synthesis of Natural Products and Potential Drugs
z1
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0001
Synthesis of (+)-Haplophytine
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0002
Synthesis of Aspercyclide B
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0003
Synthesis of (+)-Haplophytine
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0004
Synthesis of Antibiotic TAN-1085
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0005
Synthesis of Cyathin A
3
and Cyathin B
2
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0006
Synthesis of (-)-Tetrahydrolipstatin
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0007
Synthesis of Gloeosporone
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0008
Synthesis of Berkelic Acid
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0009
Synthesis of Haterumalide NA
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0010
Synthesis of Ravuconazole
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0011
CXCR4 Antagonist (GSK812397)
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0012
Synthesis of (
R
)-Sitagliptin
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0013
Synthesis of (-)-Bestatin
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0014
Synthesis of (±)-Pallavicinolide
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0015
Synthesis of (-)-Gymnodimine
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0016
Synthesis of Resolvin E2
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0017
Synthesis of Kendomycin
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0018
Synthesis of Vannusal B
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0019
Synthesis of (+)-Polyanthellin A
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0020
Formal Synthesis of (±)-Platencin
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Synthesis of Heterocycles
z21
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0021
Copper-Catalyzed Synthesis of 1,2,4-Triazoles
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0022
FeCl
3
-Mediated Synthesis of Benzo[
b
]furans from α-Aryl Ketones
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0023
Palladium-Catalyzed Synthesis of Pyrroloisoquinolines and Isoindoles
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0024
Cs
2
CO
3
-Promoted Synthesis of Substituted Oxazoles
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0025
Rhodium-Catalyzed Synthesis of Pyrroles by [4+1] Cycloaddition
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0026
Iron-Catalyzed Synthesis of 2-Aminobenzo-thiazoles
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0027
Cerium(III)-Catalyzed Synthesis of
N
-Arylpyrrolidines
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0028
Rhodium-Catalyzed Enantioselective Synthesis of Phthalides
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0029
Hydroamination Route to Pyridines and Pyrazines
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0030
Gold-Catalyzed Synthesis of Quinolines
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0031
CuBr-Catalyzed Synthesis of 2-Aminobenzo-thiazoles
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0032
Acid-Mediated Synthesis of Benzofurans from Arylhydroxylamines
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0033
One-Step Synthesis of Polysubstituted Pyrimidines
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0034
Iodine-Catalyzed One-Pot Synthesis of 6
H
-Indoloquinoline Derivatives
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0035
Gold-Catalyzed Synthesis of Pyrroles and Furans
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Synthesis of Materials and Unnatural Products
z37
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0037
One Pot per Generation
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0038
High Degree of Functionality from Click Chemistry Polymers
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0039
Very High Short-Circuit Currents in Squaraine Solar Cells
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0040
Programmable Tetraarylthiophenes
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0041
Fullerene Allylation
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0042
And ”Then There Was White"
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0043
Packing-In Negative Charge with Azulenes
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0044
High Fluorescent Quantum Yield Bis-N-Annulated Quatterylenebis(dicarboximide)
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0045
Mechanofluorochromism in Organic Donor-Acceptor Dyes
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0046
Reversing the Trend in Oxidative Addition
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0047
Quinone-ly You
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0048
An Easy Way to Trifluoromethanesulfanyls
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0049
Ring Around the Porphyrins
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0050
Synthesis of a Quinoidal Bisanthene
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0051
Small Hydrocarbon Cages
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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
z53
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0053
cis
-Selective Hydroboration of Allenes
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0054
Asymmetric Diaza-Cope Rearrangement Employing α-Keto Esters
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0055
Enantioselective Cyclopropanation of Allenes Catalyzed by a Rhodium(II) Complex
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0056
Enantioselective Ring Opening of Propargyl Epoxides
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0057
Zr- and Hf-Catalyzed Asymmetric Friedel-Crafts Alkylation of Indoles with Endiones
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0058
Synthesis of Chiral Cyclobutenes with All-Carbon Quaternary Stereocenters
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0059
Ir-Catalyzed Asymmetric Hydrogenation of 2-Aryl- and 2-Alkylquinolinium Salts
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0060
Chiral 2,5-Dihydrofurans Via Tandem Lipase/Gold Catalysis
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0061
Zirconium-Catalyzed Enantioselective Ring Opening of
meso
-Aziridines
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0062
Palladium-Catalyzed Stereoselective Construction of Chromans
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0063
Stereoselective Synthesis of 2-Methyl-3-butene-1,2-diols
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0064
Diastereoselective Synthesis of Axially Chiral Biaryls
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0065
Asymmetric Stereoablative Alkylation of 3-Halooxindoles
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0066
Enantioselective Reduction of Quinoxalines
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0067
Tandem Asymmetric Aza-Darzens/Ring-Opening Reactions
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0068
Reduction of Lactones with Samarium Iodide
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0069
Rhodium-Catalyzed Addition of Arylboroxines to
N
-Phosphinoyl Aldimines
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0070
Rhodium-Catalyzed Conjugate Alkynylation with TMS-acetylene
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0071
Palladium-Catalyzed Tandem Annulation of 2-Formylarylboronic Acids with Allenoates
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0072
Addressing Selectivity in the Formation and Reactions of Spirodiepoxides
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0073
Asymmetric Synthesis of Chiral 3,4-Dihydro-quinolin-2-ones
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0074
Aluminum-Catalyzed Asymmetric Strecker Reaction
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0075
Three-Component Diastereoselective Synthesis of Pyrrolidinones
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0076
Catalytic Oxidative Desymmetrization of
meso
-Secondary Diols
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0077
Copper-Catalyzed Asymmetric Allylic Arylation with Grignard Reagents
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0078
Rhodium-Catalyzed Asymmetric Conjugate Alkynylation
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0079
[2+2] Cycloadditions by Visible Light Photocatalysis
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0080
Rhodium-Catalyzed β-Boration of α,β-Unsaturated Carbonyl Compounds
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0081
Cationic Rh(I)/Ag(I) Complexes Catalyzed the Synthesis of Tetrasubstituted Alkenes
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0082
Dicationic Pd(II)-Catalyzed Alkenylation of Glyoxylate with Vinylsilanes
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Metal-Mediated Synthesis
z83
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0083
Titanium-Mediated Reductive Cross-Coupling of Aliphatic Imines
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0084
Ni-Catalyzed Neopentylglycolborylation of Aryl Chlorides
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0085
Palladium-Catalyzed Conversion of Aryl Triflates to Aryl Fluorides
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0086
Fe-Catalyzed C-H Functionalization and Coupling of Alcohols with Alkenes
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0087
Palladium-Catalyzed Newman-Kwart Rearrangement of Thiocarbamates
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0088
Heteroarylsulfonates in Iron-Catalyzed Coupling with Alkyl Grignard Reagents
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0089
Iron-Catalyzed sp
²
-sp
³
Cross-Coupling of Alkenylzinc Compounds
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0090
Nucleophilic Addition of Alenylsilanes at the β-Position
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0091
C=C Double Bond Formation via Coupling of
N
-Tosylhydrazones with Benzyl Halides
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0092
Ru-Catalyzed Isomerization of Alkynediols and in situ Cyclization
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0093
A Facile Gold-Catalyzed Synthesis of Heterocycles from Propargyl Alcohols
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0094
Olefin Cyclopropanation by Sequential Radical Addition/Dechlorination
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0095
CuX
2
-Mediated [4+2] Benzannulation for the Synthesis of Haloaromatic Compounds
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0096
A Simple Cu-Catalyzed Synthesis of Phenols from Aryl Halides
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0097
ZnCl
2
-Catalyzed Enantiospecific C(sp
³
)-C(sp
³
) Cross-Coupling Giving (Oligo)deoxypropionates
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Organo- and Biocatalysis
z99
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0099
Combining Organo- and Biocatalysis
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0100
A New Approach to Asymmetric DMAP Catalysis
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0101
Cross-Aldol Reactions of Enolizable Aldehydes
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0102
A Highly Efficient Chiral Amine-Thiourea Catalyst
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0103
Desymmetrization of
meso
-Aziridines with Thiols
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0104
Styrylisoxazoles as Cinnamate Equivalents
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0105
Combining Gold- and Organocatalysis
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0106
Enantioselective Base-Free Phase-Transfer Reaction
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0107
Catalysts in a Bottle
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0108
Gram-Scale Strecker Synthesis of Unnatural α-Amino Acids
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0109
Enantioselective Steglich Rearrangement Using Isothiourea Catalysts
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0110
Cascade Reactions of Amphoteric Amino Aldehydes
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0111
Mechanistic Insight in an Improved Allylboration of Ketones
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0112
Enantioselective Sulfonylation of Polyols
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Polymer-Supported Synthesis
z113
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0113
Mukaiyama Aldol Reaction with Sc(III)-USY
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0114
Huisgen Reaction of Organic Azides and Alkynes with Cu(OH)
x
/TiO
2
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0115
Parallel Solid-Phase Synthesis of Iodinated Analogues of Rimonabant
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0116
Base-Controlled Sequential C-S Bond Formation by CuSO
4
/Al
2
O
3
Catalyst
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0117
Silica-Alumina-Supported Catalysts for Efficient 1,4-Addition Reactions
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0118
Amide Synthesis from Alcohols and Amines with Ag/Al
2
O
3
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0119
Three-Component Synthesis of Substituted Pyridines with Silica Nanoparticles
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0120
Asymmetric Aldol Reaction with Polystyrene-Supported Proline-Based Catalysts
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0121
Aerobic Oxidation of Alcohols with Gold Nanoparticles Supported on Cs
2
CO
3
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0122
Carbon-Carbon Multiple Bond Reduction by MOF with Hydrazine
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0123
Suzuki Coupling in Water with Pd-NHC Immobilized on Fe
3
O
4
/Ionic Liquid
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0124
C-N/C-O Bond Formation with CuI Nanoparticles
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0125
Suzuki-Miyaura Coupling with Sn
6
O
6
-Pd Nanocomposites
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0126
Aerobic Oxidation of Alcohols with Ruthenium on Carbon
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Addenda and Errata
0127
Ni-Catalyzed Sonogashira Coupling of Nonactivated Alkyl Halides
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0127
Synthesis of Kapakahines B and F
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0127
Biaryl Cross Coupling Catalyzed by Fe/Co/Ni-Fluorides and NHC Ligands
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