Synfacts

Issue 05 · May 2008

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A49
SYNFORM ISSUE 2008/05 FREE ACCESS

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Synthesis of Natural Products and Potential Drugs
0441
Synthesis of Thromboxane B₂

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0442
Synthesis of (+)-Didemniserinolipid B

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0443
Synthesis of (-)-Pseudolaric Acid B FREE ACCESS

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0444
Synthesis of (+)-Sch 642305

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0445
Synthesis of Norbadione A

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0446
Synthesis of Pasteurestin A and B

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0447
Synthesis of (-)-Okilactomycin

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0448
Synthesis of (+)-Upial

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0449
Synthesis of (-)-Pentalenene

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0450
Synthesis of (-)-Hennoxazole A

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0451
Synthesis of Shimalactone A

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0452
Synthesis of Three Lycopodium Alkaloids

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0453
Total Synthesis of (+)-Neopeltolide

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0454
Synthesis of (±)-Psychotrimine

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0455
Synthesis of Palmitoyl Caprazol

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Synthesis of Heterocycles
0457
Pyrazolidinones via Amination of Homoenolates Catalyzed by N-Heterocyclic Carbenes

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0458
Electrochemical Cyclization of 2-Alkynylanilines to Indole Derivatives

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0459
Palladium-Catalyzed Carbonylative 3-Component Synthesis of Quinazolinones

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0460
Silver-Catalyzed Synthesis of Spiroisoindole-butyrolactones

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0461
Iron-Catalyzed Friedel-Crafts Synthesis of Dihydro- and Tetrahydroisoquinolines

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0462
Palladium-Catalyzed Three-Component Synthesis of Phenothiazines

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0463
Aziridines in Heteroannulation. Synthesis of 1,4-Benzodiazepines

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0464
Diastereoselective Synthesis of Nitropiperidones from N-p-Tolylsulfinyl β-Nitroamines

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0465
Synthesis of Fluorinated Heteroaromatics by [3+2] Cycloaddition of N-Oxides with Hexafluoropropene

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0466
Synthesis of Fluorinated Quinolines and a Pyrazoloquinoline

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0467
Synthesis of 4-Hydroxypipecolic Acid β-Lactam Analogues from Oxoazetidines

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Synthesis of Materials and Unnatural Products
0469
Donor-Acceptor Complexes with High Quantum Yields and Large Stokes Shifts

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0470
A [2+2] Approach to Unsymmetrical Chlorins FREE ACCESS

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0471
Biocompatible Release Valve

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0472
A Chiral Metal-Organic Framework

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0473
Soluble and Conjugated Poly(2,6-anthrylene)

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0474
Double the Photons for Selectivity

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0475
C₆₀ Bound to a Shape-Persistent Aryl Amide Macrocycle

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0476
Carbon Dioxide Trap-Release Polymers

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0477
Well-Defined Liquid Crystal Gels

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0478
Acyclic Carbohydrate Receptor

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0479
An Organic Spin Cage

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0480
A ‘Natural’ Synthesis of Acenequinones

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0481
Cooperative Binding by a Bicyclic Calixpyrrole

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Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
0483
Catalytic Reformatsky Reaction

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0484
Strontium-Catalyzed Enantioselective Michael Reactions

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0485
Rhodium-Catalyzed Enantioselective Hydroacylation of Ketones FREE ACCESS

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0486
Aldol Additions to Aldehydes with an Indathiazolidinethione Auxiliary

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0487
Dinuclear Aluminum Salen Displays Expanded Substrate Scope with Conjugate Cyanation

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0488
Ni₂-Schiff Base Complex for Synthesis of α-Tetrasubstituted α,β-Diamino Acid Precursors

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0489
Chiral Bis-Sulfoxide/Rhodium(I) Catalyzed Asymmetric Addition of Arylboronic Acids

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0490
Direct Amination via Bifunctional Iridium Amido Complex

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0491
Nickel-Catalyzed Cross-Coupling of Benzyl Bromides and Trialkynylindium Reagents

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0492
Chiral N,N-Dioxide/Indium(III) Complex Catalyzed Asymmetric Hetero-Diels-Alder Reaction

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0493
Enantioselective Allylic Etherification Using Novel Ferrocenyl Ligand

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0494
Rhodium(I)-Catalyzed Cycloaddition of 1,6-Enynes and Electron-Deficient Ketones

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0495
Zinc-Catalyzed Asymmetric Addition of Allylboronates

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0496
Synthesis of Chiral Glutamic Acid By Conjugate Addition

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0497
Palladium-Catalyzed Asymmetric Heck Reactions with Aryl and Vinyl Chlorides

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0498
Diastereoselective Synthesis of Fluorinated Cyclopentene Derivatives

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0499
Cationic Dirhodium Carboxamidates for Lewis Acid Catalyzed Reactions

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0500
Iridium-Catalyzed Asymmetric Allylic Etherification

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0501
Zinc-Catalyzed Asymmetric Friedel-Crafts Alkylation of Pyrroles

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0502
Asymmetric Hydrogenation of Farnesol and O-Protected Derivatives

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0503
Ru(II)-Catalyzed Highly Enantioselective Hydrogenation of Acyl Silanes

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0504
Stereoselective Synthesis of Highly Substituted Cyclopropanes

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0505
Iridium-Promoted C-C Coupling through Transfer Hydrogenation

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0506
Oxaziridines as Nitrone Precursors for [2+3] Cycloadditions

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0507
Rhodium-Catalyzed Desymmetrization of Diazabicycles with Chemodivergence

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0508
Gold- and Palladium-Cocatalyzed Vinylstannylation of Alkynes

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0509
Asymmetric Allylic Alkylation with ‘Hard’ Amide Carbanions

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0510
Rhodium-Catalyzed Stereoselective Synthesis of Nitrile-Substituted Cyclopropanes

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0511
Solvent-Dependent Chemodivergent Synthesis of Cyclic Ethers

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0512
Rhodium-Catalyzed Conjugate Addition of Sterically Bulky Silylacetylene to Enones

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Metal-Mediated Synthesis
0513
One-Pot Sonogashira and Decarboxylative Coupling of sp and sp² Carbons

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0514
Palladium-Catalyzed Arylation of (Het)arenes with Arylboronic Acids

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0515
Carbonylation of Aryl Tosylates and Mesylates FREE ACCESS

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0516
Copper-Catalyzed 1,2-Double Amination of 1-Halo-1-alkynes

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0517
Indium(I)-Catalyzed Allylation of Acylhydrazones with Pinacolyl Allylboronates

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0518
Synthesis of Salt-Free Diorganozinc Reagents and Their Use in Asymmetric Reactions

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0519
Palladium-Catalyzed 1,2- and 1,1-Aryl-halogenation of Alkenes

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0520
Phosphinamide-Directed Stereoselective Benzylic Lithiation

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0521
Copper-Catalyzed Coupling of Hydroxylamines with Aryl Iodides

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0522
C-C Bond-Formation Catalyzed by Nickel on Graphite

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0523
Synthesis of Oxazolones via Copper(II)- and Gold(I)-Catalyzed Transformations

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0524
Silver(I)-Catalyzed Benzylation and Allylation Reactions of Alkyl Halides

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0525
Syntheses of Three- and Five-Membered Carbocycles via Diene-Titanium Complexes

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0526
Oxygen- and Base-Free Oxidative Coupling of Arylboronic Acids with Olefins

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Organo- and Biocatalysis
0527
Vinylogous Umpolung with Nitrosobenzene

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0528
Three-Component Cyclization to Dihydropyridines

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0529
Desymmetrization of Meso Anhydrides

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0530
Asymmetric Morita-Baylis-Hillman Reaction of Aryl Aldehydes

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0531
Enantioselective Reduction of N-Arylketimines with S-Chiral Catalysts

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0532
Asymmetric Mannich Reaction of Acetaldehyde

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0533
Direct Crossed-Aldol Reaction of Acetaldehyde FREE ACCESS

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0534
Kinetic Resolution of Aryl Alkanols by Homobenzotetramisole

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0535
Biginelli Reaction via Dual Activation

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0536
Brønsted Acid Catalyzed Enantioselective 1,3-Dipolar Cycloaddition

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0537
Diels-Alder Reaction of 2-Pyrones and α,β-Unsaturated Ketones

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Polymer-Supported Synthesis
0539
Transfer Hydrogenation of Carbonyl Compounds Using Nickel Nanoparticles

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0540
Monoesterfication of Alkylphosphonic Acids by DCC-Celite

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0541
Suzuki-Miyaura Coupling Reaction Using Palladium Nanoparticles Immobilized on SPB FREE ACCESS

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0542
Asymmetric Alkylation Using Polymer-Supported Cinchona Ammonium Salts

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0543
m-Iodosylbenzoic Acid Mediated Iodo-Functionalization

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0544
Siloxane-Supported Bisoxazoline Ligands

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0545
Polymer-Supported (Salen)Al Catalysts

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0546
Hydrothiolation of Alkynes Using a Solid-Supported Catalyst

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0547
Aerobic Oxidation of Primary Amines by DPPH-WO₃/Al₂O₃ Catalyst

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0548
Asymmetric Michael Additions with Polymer-Supported Pyrrolidine Derivatives

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0549
Ring-Opening of Epoxides with Amines by Zn(ClO₄)/Al₂O₃

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0550
Heck Reaction with Silica Gel Supported Palladium Nanoparticles

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