Oxygen- and Base-Free Oxidative Coupling of Arylboronic Acids with Olefins

doi:10.1055/s-2008-1072527

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Synfacts 2008(5): 0526-0526
DOI: 10.1055/s-2008-1072527

Metal-Mediated Synthesis

Oxygen- and Base-Free Oxidative Coupling of Arylboronic Acids with Olefins

Contributor(s): Paul Knochel, Tobias Thaler
J. Ruan, X. Li, O. Saidi, J. Xiao*
University of Liverpool, UK

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Publikationsverlauf

Publikationsdatum:
23. April 2008 (online)

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Significance

A novel method for the oxidative coupling of arylboronic acids with both electron-rich and electron-deficient olefins is reported. This protocol requires neither base nor oxygen and proceeds with good to excellent yields tolerating sensitive functional groups.