Synthesis, Inhaltsverzeichnis Synthesis 2023; 55(11): 1616-1641DOI: 10.1055/s-0040-1720035 review Special Issue dedicated to Prof. Cristina Nevado, recipient of the 2021 Dr. Margaret Faul Women in Chemistry Award SO2-Extrusive 1,4-(Het)Aryl Migration: Synthesis of α-Aryl Amides and Related Reactions Nicolas G.-Simonian , Amandine Guérinot ∗ , Janine Cossy ∗Artikel empfehlen Abstract Artikel einzeln kaufen Alle Artikel dieser Rubrik Abstract (Het)aryl migration has emerged as a key synthetic tool and has particularly been exploited for the synthesis of α-aryl amides. This method overcomes the existing α-arylation methods, which are not always compatible with the introduction of (het)aryl groups possessing bulky or electrophilic substituents. This review focuses on SO2-extrusive (het)aryl migration in the frame of α-aryl amide synthesis. Anion- and radical-mediated transformations are reported, including the synthesis of polycyclic compounds through cascade reactions. 1 Introduction 2 Anionic Aryl Migration 3 Radical Aryl Migration 4 Conclusion Key words Key wordsα-aryl amides - cascade reactions - Truce–Smiles rearrangement - anionic aryl migration - radical aryl migration - Meisenheimer complex Volltext Referenzen References 1a Fleming A. Br. J. Exp. Pathol. 1929; 10: 226 1b Ligon BL. Semin. Pediatr. Infect. Dis. 2004; 15: 52 2 Handsfield HH, Clark H, Wallace JF, Holmes KK, Turck M. Antimicrob. Agents Chemother. 1973; 3: 262 3 Hart FD, Huskisson EC. Drugs 1984; 27: 232 4a Jullian V, Quirion J.-C, Husson H.-P. Synthesis 1997; 1091 4b Honda T, Namiki H, Satoh F. Org. Lett. 2001; 3: 631 4c Wang M.-X, Zhao S.-M. Tetrahedron Lett. 2002; 43: 6617 5a Shaughnessy KH, Hamann BC, Hartwig JF. J. Org. Chem. 1998; 63: 6546 5b Culkin DA, Hartwig JF. Acc. Chem. Res. 2003; 36: 234 5c Cossy J, de Filippis A, Gomez-Pardo D. Org. 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