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Synthesis 2019; 51(07): 1529-1544
DOI: 10.1055/s-0037-1612123
DOI: 10.1055/s-0037-1612123
short review
Silicon-Tethered Frameworks as Directing Groups for Carbon–Carbon and Carbon–Heteroatom Bond Formation
We gratefully acknowledge the National Natural Science Foundation of China (21602160, 21772148), the National Program for 1000 Young Talents of China, and Wuhan University for financial support.Further Information
Publication History
Received: 09 December 2018
Accepted after revision: 08 January 2019
Publication Date:
05 March 2019 (online)
Abstract
Recent advances in the use of silicon-tethered frameworks as directing groups for the efficient construction of C–C, C–B, C–O and C–X (X = halogen) bonds are discussed in this short review. In addition, mechanistic insights are briefly discussed. Hence, the goal of this short review is to give an overview of the state of the art in this field, encompassing the reactivity, selectivity and efficiency of different processes.
1 Introduction
2 Carbon–Carbon Bond Formation
2.1 Alkenylation
2.2 Arylation
2.3 Carbonylation
3 Carbon–Boron Bond Formation
4 Carbon–Oxygen and Carbon–Halogen Bond Formation
5 Conclusion
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For selected examples of the synthesis of dibenzooxasilines, see: