Utilization of a Copper on Iron Catalyst for the Synthesis of Biaryl Systems and Benzoxazines via Oxidative Arylation of Anilide Derivatives

Anna Székely; Ádám Sinai; Edina B. Tóth; Zoltán Novák

doi:10.1055/s-0033-1338642

Synthesis, Inhaltsverzeichnis

Synthesis 2014; 46(14): 1871-1880
DOI: 10.1055/s-0033-1338642

special topic

Utilization of a Copper on Iron Catalyst for the Synthesis of Biaryl Systems and Benzoxazines via Oxidative Arylation of Anilide Derivatives

Anna Székely

MTA-ELTE ‘Lendület’ Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Pázmány Péter stny. 1/A, 1117 Budapest, Hungary Fax: +36(1)3722592 eMail: novakz@elte.hu

,

Ádám Sinai

MTA-ELTE ‘Lendület’ Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Pázmány Péter stny. 1/A, 1117 Budapest, Hungary Fax: +36(1)3722592 eMail: novakz@elte.hu

,

Edina B. Tóth

MTA-ELTE ‘Lendület’ Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Pázmány Péter stny. 1/A, 1117 Budapest, Hungary Fax: +36(1)3722592 eMail: novakz@elte.hu

,

Zoltán Novák*

MTA-ELTE ‘Lendület’ Catalysis and Organic Synthesis Research Group, Institute of Chemistry, Eötvös Loránd University, Pázmány Péter stny. 1/A, 1117 Budapest, Hungary Fax: +36(1)3722592 eMail: novakz@elte.hu

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Abstract

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Abstract

Heterogeneous copper on iron catalyst serves as an efficient alternative copper source for arylation reactions using hypervalent iodonium salts. The copper(0) catalyst affords meta-arylation of pivalanilides, while 2-ethynylanilides undergo oxidative carboarylation–ring closure with diaryliodonium salts.

Key words

biaryls - copper - coupling - heterocycles - iron

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Referenzen

References

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