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Synthesis 2025; 57(06): 1117-1137
DOI: 10.1055/a-2383-6620
DOI: 10.1055/a-2383-6620
short review
Recent Advances in the Chemistry and Application of SF5-Compounds
Authors
This work is supported by the CNRS program Emergence@INC 2023. The authors acknowledge the University of Strasbourg for a doctoral contract to Lucas Popek and CNRS Chimie for post-doctoral contract of Dr Mariam Abd El Sater.
Abstract
This review article outlines the literature from 2022 to 2024 covering developments in SF5 chemistry. Recent synthetic methodologies of SF5-containing building blocks are reported. These methods include the synthesis of SF5Cl and its use in pentafluorosulfanylation reactions and oxidative fluorination reactions. Moreover, the reactivity of SF5-alkynes as versatile platform to access new SF5-compounds is described. Finally, the effects of the SF5 moiety are highlighted according to its application in different fields, such as biological/medicinal chemistry, catalysis, and material sciences.
1 Introduction
2 Access to SF5-Containing Building Blocks
2.1 By Means of SF5Cl
2.1.1 Generation of SF5Cl
2.2 By Means of Oxidative Fluorination
2.3 By Means of SF5-Alkynes
2.4 Other Miscellaneous Aromatic and Aliphatic SF5-Compounds
3 Applications
3.1 Medicinal and Biological Chemistry
3.2 Material Science
3.3 Catalysis
4 Conclusion
Key words
SF5Cl - pentafluorosulfanylation - SF5 building blocks - oxidative fluorination - medicinal chemistry - materials science - catalysisPublikationsverlauf
Eingereicht: 08. Juli 2024
Angenommen nach Revision: 09. August 2024
Accepted Manuscript online:
09. August 2024
Artikel online veröffentlicht:
26. September 2024
© 2024. Thieme. All rights reserved
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