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Synthesis 2022; 54(24): 5409-5422
DOI: 10.1055/a-1900-8895
DOI: 10.1055/a-1900-8895
short review
Photoredox-Mediated Desulfonylative Radical Reactions: An Excellent Approach Towards C–C and C–Heteroatom Bond Formation
I. C. wishes to acknowledge the financial assistance from the Council of Scientific and Industrial Research, India (CSIR, 02 (0437)/21/EMR-II) and the Indian Institute of Technology Ropar (IIT Ropar). Biprajit and Hrishikesh want to acknowledge Prime Minister’s Research Fellows (PMRF), Ministry of Education (MOE), New Delhi, and University Grants Commission (UGC), New Delhi, respectively, for their research fellowships.
Abstract
In recent times, desulfonylative radical-cross-coupling (RCC) has come to the forefront in synthetic organic, bio, and material chemistry as a powerful strategy to form C–C and C–heteroatom bonds. Diverse functionalization through metal- and photoredox-catalyzed desulfonylation reactions has attracted the scientific community due to the mild reaction conditions, wide functional group tolerance, and excellent synthetic efficacy. In this review, we have highlighted photoredox-mediated desulfonylation reactions developed since 2000. This review will summarize the newly reported methodologies, with particular emphasis on their mechanistic aspects and selectivity issues which have paved a new way towards sustainable C–C and C–X (X = H or heteroatom) bond formation.
1 Introduction
2 Photoredox-Catalyzed C–C Bond Formation
2.1 Aryl Sulfones as Radical Precursor
2.2 Reactions of Allyl Sulfones
3 Photoredox-Catalyzed C–Heteroatom Bond Formation
4 Conclusion
Key words
desulfonylation - radical cross-coupling - photoredox catalysis - C–C bond formation - allyl sulfonePublication History
Received: 09 June 2022
Accepted after revision: 14 July 2022
Accepted Manuscript online:
14 July 2022
Article published online:
31 August 2022
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