Synthesis 2019; 51(07): 1529-1544
DOI: 10.1055/s-0037-1612123
short review
© Georg Thieme Verlag Stuttgart · New York

Silicon-Tethered Frameworks as Directing Groups for Carbon–Carbon and Carbon–Heteroatom Bond Formation

,
Xiao-Wen Zhang
,
Wen-Bo Liu*
Engineering Research Center of Organosilicon Compounds & Materials, Ministry of Education, College of Chemistry and Molecular Sciences, Wuhan University, 299 Bayi Rd, Wuhan 430072, Hubei, P. R. of China   Email: [email protected]
› Author Affiliations
We gratefully acknowledge the National Natural Science Foundation of China (21602160, 21772148), the National Program for 1000 Young Talents of China, and Wuhan University for financial support.
Further Information

Publication History

Received: 09 December 2018

Accepted after revision: 08 January 2019

Publication Date:
05 March 2019 (online)


Abstract

Recent advances in the use of silicon-tethered frameworks as directing groups for the efficient construction of C–C, C–B, C–O and C–X (X = halogen) bonds are discussed in this short review. In addition, mechanistic insights are briefly discussed. Hence, the goal of this short review is to give an overview of the state of the art in this field, encompassing the reactivity, selectivity and efficiency of different processes.

1 Introduction

2 Carbon–Carbon Bond Formation

2.1 Alkenylation

2.2 Arylation

2.3 Carbonylation

3 Carbon–Boron Bond Formation

4 Carbon–Oxygen and Carbon–Halogen Bond Formation

5 Conclusion

 
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