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Synlett 2000; 2000(4): 495-496
DOI: 10.1055/s-2000-6582
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Preparation of Germyl-Substituted Dizinciomethanes and Their Reactions with Electrophiles

Seijiro Matsubara* , Hideaki Yoshino, Kiitiro Utimoto, Koichiro Oshima
  • *Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Yoshida, Sakyo, Kyoto 606-8501, Japan; Fax 75-7 53-48 63; E-mail: matsubar@mc.kyoto-u.ac.jp
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Publication History

Publication Date:
31 December 2000 (online)

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Triethylgermyl-substituted bis(bromozincio)methane, prepared from the corresponding dibromides by Pb catalyzed reaction with zinc, reacted with aldehydes to afford alkenylgermanes; sequential coupling reactions with organic halides also showed the new route to prepare organogermyl compounds.

zinc - germane - olefination - coupling

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