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Synlett 1999; 1999(4): 453-455
DOI: 10.1055/s-1999-2651
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Construction of Three Building Blocks for the Total Synthesis of Microsclerodermins

Shigekazu Sasaki* , Yasumasa Hamada, Takayuki Shioiri
  • *Faculty of Pharmaceutical Sciences, Nagoya City University, Tanabe-dori, Mizuho-ku, Nagoya 467-8603, Japan; Fax +81-52-8 34-41 72; E-mail: shioiri@phar.nagoya-cu.ac.jp
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Publikationsdatum:
31. Dezember 1999 (online)

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Three building blocks 2, 3 and 4 for the total synthesis of microsclerodermins (1) have been efficiently constructed from carboxylic acid 6, 14, and 20, respectively.

microsclerodermin (R)-tryptophan - asymmetric alkylation - 2-hydroxy-3-pinanone - GABOB

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