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Synlett 1998; 1998(5): 543-545
DOI: 10.1055/s-1998-1719
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Kinetic Resolution of Racemic Allenes by Using Chiral (Salen)manganese(III) Complex as a Catalyst

Yukiko Noguchi* , Hiroyuki Takiyama, Tsutomu Katsuki
  • *Department of Chemistry, Faculty of Science, Kyushu University 33, Hakozaki, Higashi-ku, Fukuoka 812-8581, Japan; Fax + 81 92 642 2607
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Publication Date:
31 December 2000 (online)

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Enantiomer-differentiating oxidation of racemic 1,3-diarylallenes using optically active (salen)manganese(III) complex (1) as a catalyst, was found to proceed with high relative rate constants (up to 23), providing the enantiomerically enriched 1,3-diarylallenes.

allene - kinetic resolution - (salen)manganese(III) complex

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