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Synlett 1997; 1997(2): 163-164
DOI: 10.1055/s-1997-750
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Palladium Catalysts for Cross-Coupling of Ortho-Substituted Aryl Triflates with Grignard Reagents

Takashi Kamikawa, Tamio Hayashi*
  • *Department of Chemistry, Faculty of Science, Kyoto University, Sakyo, Kyoto 606-01, Japan, Fax 81-75-753-3988; E-mail thayashi@th1.orgchem.kuchem.kyoto-u.ac.jp
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Publication History

Publication Date:
31 December 2000 (online)

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Dichloro[(2-dimethylamino)propyldiphenylphosphine]palladium (PdCl2(alaphos)) and dichloro[1,3-bis(diphenylphosphino)-propane]palladium (PdCl2(dppp)) were found to be much more effective catalysts than PdCl2(PPh3)2 and other palladium complexes for cross-coupling of sterically congested aryl triflates with aryl and alkynyl Grignard reagents.

cross-coupling - Grignard reagent - aryl triflate - palladium catalyst

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