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Synthesis 1997; 1997(11): 1309-1314
DOI: 10.1055/s-1997-1339
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Enantioselective Catalyses 110.1 New Chiral Phosphanes Derived from Substituted Quinolines

H. Brunner* , T. Rückert
  • *Institut für Anorganische Chemie, Universität Regensburg, D-93040 Regensburg, Germany, Fax (0941)9434439, E-mail: henri.brunner@chemie.uni-regensburg.de
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Publication Date:
31 December 2000 (online)

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Optically active, two-layer phosphanes were obtained by reaction of quinolineamines with metalated 1,2-bisphosphanylbenzene and chiral monodentate quinolinephosphanes were synthesized by reaction of optically active quinolineamines with lithium diphenylphosphide. The precursors were built up from quinoline derivatives containing bromomethyl groups and chiral secondary amines.

Chiral two-layer phosphanes derived from optically active quinolineamines