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Synlett 1996; 1996(7): 615-616
DOI: 10.1055/s-1996-5578
DOI: 10.1055/s-1996-5578
letter
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Enzyme Mediated Synthesis of Stereoisomerically Pure α,ω-Diepoxides
Further Information
Publication History
Publication Date:
31 December 2000 (online)
The synthesis of stereoisomerically pure terminal diepoxides 2a and 2b was accomplished through enzyme catalyzed transesterification of bis(β-hydroxyalkyl)thioethers followed by S-alkylation and base promoted intramolecular displacement.
kinetic resolution - transesterification - PS-30 - β-hydroxyalkylsulfides - meso-selectivity - desymmetrization