Download PDF
Synthesis 1996; 1996(3): 361-366
DOI: 10.1055/s-1996-4222
paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthetic Potentialities of Alkyl and Aryl Cyclopropylidenealkyl Sulfides: Access to 1-(Arylthio)vinylcyclopropanes by a 1,3-Shift of an Arylthio Group

Angela M. Bernard, Maria T. Cocco, Cenzo Congiu, G. Luca Franzone, Pier P. Piras*
  • *Dipartimento di Scienze Chimiche, Università di Cagliari, Via Ospedale 72, I-09100 Cagliari, Italy, Fax +39(70)669272
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

Alkyl and aryl cyclopropylidenealkyl sulfides 2, 4 and 5 were converted to give access to 1-(arylthio)vinylcyclopropanes 3 by light induced or acid catalyzed 1,3-shift of the arylthio group. Some results on the reactivity of sulfides 2, 4 and 5 are reported.

thia-allylic rearrangement - vinylcyclopropanes - cyclopropylidenealkylthioethers - sulphonium salts - Pd(0) catalyzed allylic nucleophilic substitutions