Synlett 1995; 1995(12): 1249-1251
DOI: 10.1055/s-1995-5248
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Free-Radical Carbonylation Using a Zn(Cu) Induced Reduction System

Shinji Tsunoi, Ilhyong Ryu1 , Hiroshi Fukushima, Minoru Tanaka, Mitsuo Komatsu, Noboru Sonoda2
  • 1Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565, Japan, Fax: +81 6 879 7402; E-mail: ryu@chem.eng.osaka-u.ac.jp
  • 2Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565, Japan, Fax: +81 6 879 7402
Further Information

Publication History

Publication Date:
31 December 2000 (online)

Carbonylation of organic iodides (RI) was studied using the Zn(Cu) reduction system. Carbonylation products, including aldehydes, unsymmetrical ketones, and cyclopentanone derivatives, were obtained by this procedure. The degree of success was diverse, depending on the structure of RI.