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Synlett 1994; 1994(10): 836-838
DOI: 10.1055/s-1994-23023
DOI: 10.1055/s-1994-23023
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Synthesis of Cyclic Imines by Addition of Grignard Reagents to ω-Bromonitriles
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Publication History
Publication Date:
22 March 2002 (online)
ω-Bromonitriles readily undergo a tandem addition-cyclization reaction sequence with Grignard reagents at room temperature in hydrocarbon/ether solvent mixtures to give good yields of 2-substituted pyrrolines and tetrahydropyridines.