Synlett 1994; 1994(3): 204-206
DOI: 10.1055/s-1994-22795
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Selenoxide - Sulfonic Acid Adducts: A New System for the Mild, Selective Oxidation of Sulfides to Sulfoxides

D. J. Procter* , S. J. Lovell, C. M. Rayner
  • *School of Chemistry, University of Leeds, Leeds, LS2 9JT, England
Further Information

Publication History

Publication Date:
22 March 2002 (online)

The development of a selenoxide - sulfonic acid system for the mild and selective oxidation of sulfides to sulfoxides is reported. Various selenoxide and sulfonic acid combinations were studied in the search for an effective system. A mechanism for the oxidation is proposed and the potential for the development of an asymmetric oxidation system is assessed.