Download PDF
Synthesis 1989; 1989(11): 870-873
DOI: 10.1055/s-1989-27418
communication
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Aromatic Nucleophilic N,S- and N,O-Exchange Reactions of N,N-Dimethyl-2,4-bistrifluoroacetyl-1-naphthylamine with Various Thiols and Alcohols: A, Facile Synthetic Method for Alkyl and Aryl 1-[2,4-Bis(trifluoroacelyl)naphthyl] Sulfides and Ethers

Masaru Hojo* , Ryōichi Masuda, Etsuji Okada, Hiroshi Miya
  • *Department of Industrial Chemistry, Faculty of Engineering, Kobe University, Rokkodai, Nada, Kobe 657, Japan
Further Information

Publication History

Publication Date:
02 May 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Aromatic nucleophilic N,S- and N,O-exchange reactions of N,N-dimethyl-2,4 -bistrifluoroacetyl-1-naphthylamine (1) with various thiols and alcohols afford the corresponding 2,4-bistrifluoroacetyl-1-naphthyl sulfides 2 and ethers 3 in excellent yields. Hydrolysis of 1 to 1-naphthol derivative 4 is also described.

      >