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Synthesis 2016; 48(01): 136-140
DOI: 10.1055/s-0035-1560498
DOI: 10.1055/s-0035-1560498
paper
New Reaction of Fullerene C60 with Cyanoacrylates and Ethylmagnesium Bromide in the Presence of Titanium(IV) Isopropoxide
Further Information
Publication History
Received: 16 July 2015
Accepted after revision: 18 September 2015
Publication Date:
05 October 2015 (online)
Abstract
The reaction of fullerene C60 with cyanoacrylates and ethylmagnesium bromide in the presence of stoichiometric amounts of titanium(IV) isopropoxide was studied for the first time. Under the developed conditions, cyanoacrylates, unlike carboxylic acid esters and nitriles, were found to react with C60 to form aminofullerocyclopropanes, which are otherwise difficult to access.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1560498.
- Supporting Information
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