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Synfacts 2010(10): 1168-1168
DOI: 10.1055/s-0030-1258690
DOI: 10.1055/s-0030-1258690
Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions
© Georg Thieme Verlag
Stuttgart ˙ New York
New Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions
Z. Liu, H. Du*
Beijing National Laboratory of Molecular Science, P. R. of China
Further Information
Publication History
Publication Date:
22 September 2010 (online)
Significance
A novel class of terminal-alkene-phosphine hybrid ligands was developed and successfully applied to palladium-catalyzed asymmetric allylic substitutions with carbon, nitrogen and oxygen nucleophiles giving the desired products in good yields and enantioselectivities.