New Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions

Z. Liu; H. Du

doi:10.1055/s-0030-1258690

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Synfacts 2010(10): 1168-1168
DOI: 10.1055/s-0030-1258690

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

New Ligands for Palladium-Catalyzed Asymmetric Allylic Substitutions

Contributor(s): Hisashi Yamamoto, Jiajing Tan
Z. Liu, H. Du*
Beijing National Laboratory of Molecular Science, P. R. of China

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Publication History

Publication Date:
22 September 2010 (online)

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Significance

A novel class of terminal-alkene-phosphine hybrid ligands was developed and successfully applied to palladium-catalyzed asymmetric allylic substitutions with carbon, nitrogen and oxygen nucleophiles giving the desired products in good yields and enantioselectivities.