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Synthesis
DOI: 10.1055/a-2759-6476
Paper

Radical allylation of vinyl perfluorocyclic sulfonamides leading to 1,1,2,2,3,3-hexafluorohex-5-ene-1-sulfonamides

Autoren

  • Takaaki Maejima

    1   Department of Applied Chemistry, Yamaguchi University, Ube, Japan (Ringgold ID: RIN13150)

  • Moeri Terauchi

    2   Department of Applied Chemistry, Yamaguchi University, UBE, Japan (Ringgold ID: RIN13150)

  • Takuji Kawamoto

    2   Department of Applied Chemistry, Yamaguchi University, UBE, Japan (Ringgold ID: RIN13150)

Gefördert durch: Japan Science and Technology Agency GteX JPMJGX23S3,GteX JPMJGX23SA
Gefördert durch: Japan Society for the Promotion of Science 22K05116 ,25K00077
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Allylation reactions are essential for the introduction of alkene functionalities into molecules, and radical allylation reactions serve as a powerful strategy to achieve this. Of the various known allylating reagents, allyl bromides offer a particularly direct and efficient approach to allylation. Here, we report the radical allylation of vinyl perfluorocyclic sulfonamides using allyl bromides, which leads to the synthesis of allylated fluoroalkyl sulfonamides.



Publikationsverlauf

Eingereicht: 17. Oktober 2025

Angenommen nach Revision: 29. November 2025

Accepted Manuscript online:
29. November 2025

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