DOI: 10.1055/s-00000131

Synfacts

Issue 12 · Volume 19 · December 2023 DOI: 10.1055/s-013-58592

Synform

  • A194

    SYNFORM ISSUE 2023/12

    • Synthesis of Natural Products

  • z1173

    All PDFs of this category

  • 1173

    Synthesis of (–)-Zygadenine

  • 1174

    Syntheses of ent-(–)-Njaoamine C

  • 1175

    Total Synthesis of (–)-Cotylenol

  • 1176

    Total Synthesis of (–)-Silicine and (–)-20-Episilicine

  • 1177

    Total Synthesis of (±)-Neocaesalpin A

  • 1178

    Chemoenzymatic Synthesis of Cylindrocyclophanes A and F and Merocyclophanes A and D

  • 1179

    Total Synthesis of (±)-Antheridium-Inducing Factor AAn

    • Synthesis of Heterocycles

  • z1181

    All PDFs of this category

  • 1181

    Regiodivergent C–H Arylation of Thiophenes

  • 1182

    Doebner Hydrogen-Transfer Reaction to Access Electron-Deficient Quinolines

  • 1183

    Cobalt-Catalyzed Olefin Cyclopropanation via Masked Dialkyl Diazomethanes

  • 1184

    TBAI-Mediated Synthesis of Methylsulfonyl Oxazoles from Propargylic Amides

  • 1185

    Direct Carbon for Nitrogen Replacement Reaction to Access Functionalized Pyridines

  • 1186

    Palladium-Catalyzed C–H Arylation of Functionalized Pyrazoles/Triazoles and Imidazoles

  • 1187

    Fused Piperidine Derivatives Featuring Stereogenic CF3 Substitution

  • 1188

    Stereoselective Cascade Reaction for the Synthesis of Chiral Fused Diazaheterocycle Scaffolds

  • 1189

    Scalable Synthesis of Silacyclohexanones for Silaheterocycles Construction

  • 1190

    Modular, Chiral-Auxiliary-Mediated Synthesis of Sterically Constrained β-Amino Acid Derivatives

  • 1191

    Synthesis of Functionalized Pyrrolidinones via Smiles–Truce Cascade

  • 1192

    Rhodium(III)-Catalyzed Synthesis of Unsymmetrically Substituted 2,2'-Dipyridyl Amines Using 1,2,4-Trizoles

    • Synthesis of Materials and Unnatural Products

  • z1193

    All PDFs of this category

  • 1193

    A Figure-of-Eight Molecular Shuttle

  • 1194

    Benzoselenophenes from Elemental Selenium

  • 1195

    A Trisradical Tricationic Cage

  • 1196

    Let Light Do the Trick

  • 1197

    Sulfur-Free Cationic RAFT

  • 1198

    Palladium-Catalyzed Decarbonylative Intermolecular Annulation

  • 1199

    Multi-Component Synthesis of 2,3,6-Substituted Pyridines

  • 1200

    Photodegradable Vinyl Polymers from Living Cationic Ring Opening

  • 1201

    C–H Activation with Polyolefins by Photoinduced Catalysis

  • 1202

    Three-Dimensional Covalent Organic Framework

  • 1203

    Chalcogen-Extrusion from Nanographene

  • 1204

    Alkylated Boroles from Aluminum–Boron Exchange

    • Metals in Synthesis

  • z1205

    All PDFs of this category

  • 1205

    Iridium-Catalyzed Enantioselective Cascade Allylic Etherification/[2+2] Photocycloaddition

  • 1206

    Cobalt-Catalyzed Asymmetric Alkynylative Ring Opening of Oxabicyclic Alkenes

  • 1207

    Dealkenylative C(sp3)–N Cross-Coupling of Alkenes and Amines by Merging Ozonolysis and Copper Catalysis

  • 1208

    A Nickel-Catalyzed Alkene Dicarbofunctionalization Approach Avoiding Carbon–Metal Intermediates

  • 1209

    Cu-Catalyzed Synthesis of Oxazoles via [3+2] Annulation/Olefination Sequence

  • 1210

    Catalytic Alkyne-Carbonyl Ring-Closing Metathesis to Make γ-Butenolides from Propargyl α-Ketoesters

  • 1211

    Enantio- and Diastereoselective Cyclopropanation of Alkenes by Iron(III)-Based Metalloradical Catalysis

  • 1212

    Palladium-Catalyzed C–H Functionalization of Triaryl Phosphates via Eight-Membered Palladacycle

  • 1213

    Visible-Light Photocatalytic [2+2] Cycloaddition of 1,5-Hexadienes to Bicyclo[2.1.1]hexanes

  • 1214

    Lewis Acid Assisted Double CO2 Fixation in Nickel-Catalyzed Carboxylative Cross-Electrophile Coupling

  • 1215

    Copper Catalyzed Formal [3+2] Cycloaddition Between Aziridines and Silyl Dienol Ethers

  • 1216

    Synthesis of 2-Amino Aromatic Acetic Acid Derivatives via Rhodium-Catalyzed C–H Carboxymethylation

  • 1217

    Alcohol-Directed sp3 C–H Arylation Catalyzed by Palladium

  • 1218

    Hydroarylation Strategy Towards Enantioenriched C–N Vinylindole Atropoisomers

  • 1219

    Blue’s Complementary: Photoredox/Nickel-Catalyzed C(sp2)–C(sp3) Cross-Coupling under Orange Light

  • 1220

    Chromium-Catalyzed Cross-Electrophile Coupling of Hydrochlorosilanes with Aryl Pivalates

  • 1221

    Asymmetric Reductive Coupling of Alkynes and Imines via Cobalt-Catalyzed Formation of Zinc Metallacycles

  • 1222

    Gold-Catalyzed Synthesis of Naphthoate Derivatives Via Cascade [5+1] Annulation

  • 1223

    Direct C(sp2)–H ortho-Methoxylation of Aryl Halides by a Catellani-Type Reaction

  • 1224

    Asymmetric and Regiodivergent Synthesis of Silyl-Containing Homoallylic Alcohols Using Cu Catalysis

  • 1225

    Asymmetric Synthesis of Masked Arylglycine Esters via Pd-Catalyzed Arylation of Schöllkopf Bis-Lactim Ethers

  • 1226

    Synthesis of 2-Amino-3-Formylated Chromones via Pd Domino Catalysis

  • 1227

    Amination of Aryl Bromides under Nickel/Mechano-redox Catalysis Using Ball-Milling Technique

  • 1228

    Synthesis of 1,3-Oxazine or Hydropyrimidine Derivatives via Palladium-Catalyzed [4+2] Cycloaddition

  • 1229

    Rhodium Catalyzed Desymmetrization of Metallocenes – A Conjugate Addition Cyclization Cascade

  • 1230

    The Reetz Alkylation: Direct Geminal Dimethylation of Ketones Using Organotitanium Chemistry

    • Polymer-Supported Synthesis

  • z1231

    All PDFs of this category

  • 1231

    Oxidation of C(sp3)–H and C=C Bonds Promoted by Iron Complex Immobilized on COF Nanospheres and Film

  • 1232

    Decarboxylative Coupling of N-Hydroxyphthalimide Esters with Disilanes or Diborons with Au Nanocatalyst

  • 1233

    Transfer Hydrogenation of Azoarenes to Hydrazoarenes by Ammonia Borane Catalyzed by Au/TiO2

  • 1234

    Carbonylative Coupling of Aryl Boronic Acids by Pd NPs within Melamine Dendron and Fibrous Nano-Silica

  • 1235

    Rhodamine B Encapsulated in a Metal–Organic Cage for Photocatalytic Oxidation in Aqueous Media

  • 1236

    Photocatalytic Hydroalkylation and Oxidative Coupling of Phenylacetylenes Catalyzed by a Cu@MOF Composite

  • 1237

    Hydrogenation of Quinolines Using Fully Exposed Iridium Clusters Supported on Sulfur-Doped Carbon

  • 1238

    Electrocarboxylation of Aryl Bromide with CO2 by Bifunctional Cu/Ag Catalysts

  • 1239

    Catalytic Asymmetric Oxirane Ring Opening with Chirally-Modified PCN-222 MOF

  • 1240

    Transfer Hydrogenation of Azides by a Single-Atom Cobalt Catalyst

  • 1241

    Photocatalytic Oxidation Reactions Using Phenothiazine-Anchored CTFs

    • Organo- and Biocatalysis

  • z1243

    All PDFs of this category

  • 1243

    Electrophotocatalytic Generation of Unstabilized Ketyl Radicals and their Coupling to Alkenes

  • 1244

    Axially Chiral Biaryl Siloxanes Synthesized through Asymmetric Si–CAryl Bond Functionalization

  • 1245

    Enzymatic Enantioselective Amination Using Hydroxylammonium Hydrochloride as Nitrogen Source

  • 1246

    Lewis Acid Catalyzed Deoxyfluorination of Alcohols

  • 1247

    Organocatalytic Direct Acylation of Alkanes

  • 1248

    Enantioselective Isomerization of Substituted Bicyclo[1.1.0]butanes into Cyclobutenes

  • 1249

    Photocatalytic Deracemization Enables the Synthesis of Chiral 2,5-Diketopiperazines

  • 1250

    Chiral Diselenides – Catalysts for the Enantioselective Synthesis of Phosphorus-Stereogenic Compounds

  • 1251

    A Photocatalytic Sulfinamide Synthesis Platform Provides Access to Sulfonamides and Sulfonimidamides

    • Innovative Drug Discovery and Development

  • z1253

    All PDFs of this category

  • 1253

    4-Selective Azaarene Fluorination

  • 1254

    Visualizing New Proteins with THRONCAT

  • 1255

    Total Synthesis of Tetrachlorovancomycin

  • 1256

    One-Pot Formal Carboradiofluorination of Alkenes for PET Imaging Probe Development

  • 1257

    Substrate Plasticity Enables Group-Selective Transmetalation: Catalytic Stereospecific Cross-Couplings of Tertiary Boronic Esters

  • 1258

    A pH and Ca2+ Tolerant Ratiometric Mg2+ Sensor

  • 1259

    Accessing Potential Anti-Obesity Drug via Total Synthesis

  • 1260

    cis-Active Photoswitchable CB2-Receptor Agonist

  • 1261

    Aerobic Oxidation Using Cu/TEMPO as an Alternative to Toxic DDQ-Mediated Reaction

  • 1262

    Flexible Ether-Bearing Emn-BridgePhos Ligands for Enantioselective Desymmetric Hydrogenation

  • 1263

    Fragment Coupling Approach Enables Convergent Access to (–)-Cyclopamine

  • 1264

    Sulfonium Salt Reagents for the Introduction of Deuterated Alkyl Groups in Drug Discovery

  • 1265

    Strategy to Improve Half-Life of DGAT2 Inhibitor Ervogastat: Discovery of PF-07202954

  • 1266

    Aryl (β,β,β-Trifluoro)-tert-Butyl: A Candidate Motif for the Discovery of Bioactives

  • 1267

    Palladium-Catalyzed Preparation of Indolyl-C-Glycosides

  • 1268

    CPA-Catalyzed Synthesis of Chiral α,α-Diaryl Ketones from Unactivated Alkyenes

  • 1269

    Access to Normal and Abnormal Neocannabinoids via Control of Friedel–Crafts Reaction Time

    • Peptide Chemistry

  • z1271

    All PDFs of this category

  • 1271

    Peptide Cleavage Reaction at the C-Terminal Arg Site

  • 1272

    Amide Bond Formation Using Triflylpyridinium as Coupling Reagent

  • 1273

    Thiol-Labile Amino Protecting Group that Suppresses the Epimerization in Peptide Synthesis

  • 1274

    Enantio- and Diastereoselective Synthesis of β-Aminoamides Catalyzed by a Chiral NiH Complex

  • 1275

    Fe-Catalyzed Alkylazidation of Alkenes for the Synthesis of α-Azido α-Amino Esters

  • 1276

    Pd-Catalyzed Synthesis of (Z)-Trisubstituted Allylic Amino Acids

  • 1277

    Esterification of Amino Acids by Using TCFH as Reagent

  • 1278

    Benzylic Lithiation Reaction for the Synthesis of Unnatural Amino Acids

    • Flow Chemistry

  • z1279

    All PDFs of this category

  • 1279

    Investigating Ozone Solubility in Organic Solvents for Use in Flow Ozonolysis Protocols

  • 1280

    Flash Thermal Racemization for Chemoenzymatic Dynamic Kinetic Resolution of Chiral Amines