DOI: 10.1055/s-00000131

Synfacts

Issue 09 · Volume 19 · September 2023 DOI: 10.1055/s-013-58080

Synform

  • A149

    SYNFORM ISSUE 2023/09

    • Synthesis of Natural Products

  • z0849

    All PDFs of this category

  • 0849

    Total Synthesis of (–)-Mitragynine Pseudoindoxyl

  • 0850

    Synthesis of (–)-Caulamidine A

  • 0851

    Synthesis of (+)-Malettinin C and (+)-Malettinin E

  • 0852

    Total Synthesis of (–)-Retigeranic Acid A

  • 0853

    Synthesis of (+)-Hinckdentine A

  • 0854

    Synthesis of (+)-Asteriscanolide

    • Synthesis of Heterocycles

  • z0855

    All PDFs of this category

  • 0855

    Rh-Catalyzed Asymmetric Carbometallation to Access 3-Substituted Piperidines

  • 0856

    Synthesis of Hybrid Scaffolds Featuring 4-Pyridine and 4-Piperidine Moieties

  • 0857

    Cu-Mediated C(sp2)–H Elaboration of Benzylic Scaffolds

  • 0858

    Copper-Catalyzed Synthesis of Axially Chiral Arylpyrroles via Atroposelective Cyclization of Diyne

  • 0859

    One-Pot Synthesis of Pyrazolooxazines from 2,2-Dichlorovinylacetophenones

  • 0860

    Efficient Exploration of Reaction Space to Optimize Sustainable Cu-Mediated Ullmann Couplings

  • 0861

    Photocatalyzed Formate-Mediated Deoxygenation of Alcohols through Benzoate Ester Intermediates

  • 0862

    Synthesis of Polysubstituted Furans via Electrocatalyzed Cyclization

  • 0863

    Synthesis of Azabicyclic Systems through [3+2] Cycloaddition of Oxidopyridinium Ions

  • 0864

    Versatile Synthesis of 4-Fluoropyrroles

  • 0865

    Regioselective Synthesis of Isoxazoles from Ynones

  • 0866

    Catalyst-Controlled [3+2] Cycloaddition for the Synthesis of endo- or exo-Substituted Pyrrolidines

  • 0867

    Catalytic Asymmetric Synthesis of Morpholinones and Piperazinones via Domino Ring-Opening Cyclization

    • Synthesis of Materials and Unnatural Products

  • z0869

    All PDFs of this category

  • 0869

    Adamantane-Annulated Arenes

  • 0870

    Synthesis of Boratatriptycene

  • 0871

    Molecular Cage from Diradical Dimerization

  • 0872

    A New Benzotrisazulene Synthesis

  • 0873

    Arylquinoline from Three Components in One-Pot

  • 0874

    One Stone, Two Birds: Versatile Grignard Reagent-Enabled Coupling for Advanced Arylamines and Biaryls

  • 0875

    Aromatic C–C Bond Cleavage in a Curved π‑System of Aminocorannulene

  • 0876

    A Helicene-Bridged Cyclophane

  • 0877

    Synthesis of Tetraphenanthroporphyrins

  • 0878

    A Self-Accelerated Polymerization

  • 0879

    Tetraradical in Cyclic Paraphenylene

  • 0880

    Facile 10- and 11-Membered Azalactam Synthesis

    • Metals in Synthesis

  • z0881

    All PDFs of this category

  • 0881

    Making Acid Chlorides from Olefins by Palladium-Catalyzed Regiodivergent Hydrochlorocarbonylation

  • 0882

    Palladium-Catalyzed Synthesis of Polysubstituted Cyclopropanecarbonitriles

  • 0883

    Rhodium Catalyzed Aryl C–H Functionalization with Nitroalkenes

  • 0884

    Nickel-Catalyzed Alkenyl C(sp2)–H Functionalization via an Aryl-to-Vinyl 1,4-Nickel/Hydride Shift

  • 0885

    Rh-Catalyzed Synthesis of Propargylic Sulfides via a [2,3]-Sigmatropic Rearrangement

  • 0886

    Synthesis of Chiral meta-Arylated 2-Aryl Anilines via an Atroposelective Palladation Relay

  • 0887

    Copper-Catalyzed Three-Component Carboesterification of Styrenes to Access Chiral γ-Butyrolactones

  • 0888

    C(sp3)–H Functionalization Enabled by Hydrogen Atom Transfer with Tertiary Cyclopropyl Radicals

  • 0889

    Palladium-Catalyzed Cross-Coupling of 2-Benzoylpyridine N-Oxides via C(sp2)–C(O) Bond Cleavage

  • 0890

    Synergystic Catalysis Used Toward the Synthesis of Strychnan Alkaloids

  • 0891

    Enantioselective Hydroamination of Cyclopropenes Catalyzed by Copper

  • 0892

    Synthesis of β-N-Glycopyranosides via Palladium-Catalyzed Tsuji–Trost Amination

  • 0893

    Synthesis of Imidazolidines by Copper-Catalyzed Formal (3+2) Cycloaddition of Aziridines and Diazetidines

  • 0894

    Cyclization of Enynes by Iron-Catalyzed Hydrochlorination

  • 0895

    Nickel-Catalyzed Synthesis of Hydrazides from O-Benzoylated Hydroxamates and Aryl/Aliphatic Amines

  • 0896

    Nickel-Catalyzed Regioselective Allylic Alkylation of Unsymmetric Ketones at the Higher-Substituted α-Site

  • 0897

    Palladium-Catalyzed Directed Regio- and Stereoselective 1,1-Diarylation of Alkenes

  • 0898

    Dual Nickel/Photoredox-Catalyzed Regioselective β-Allylation of Silyl Enol Ethers

  • 0899

    Regio- and Chemoselective Synthesis of Trisubstituted Allenes via a Pd-Catalyzed Three-Component Reaction

  • 0900

    Chromium-Catalyzed Enantioselective Cyclopropanation of Terminal Olefins with gem-Dihaloalkanes

  • 0901

    Aerobic α,β-Dehydrogenation of Lactams and Flavanones under Iron Catalysis

  • 0902

    Rh-Catalyzed Regio- and Diastereoselective Synthesis of Difluorinated Cyclopentanes via a [3+2] Cycloaddition

  • 0903

    Time-Dependent Synthesis of Spirocyclic Silacycles via Pd-Catalyzed Domino C–H Activation Reactions

  • 0904

    Ru-Catalyzed Intermolecular [4+3] Cycloaddition of ortho-Quinone Methides with Carbonyl Ylides

  • 0905

    The Overman Asymmetric Intramolecular Heck Reaction for the Synthesis of 3-Alkyl-3-Aryloxindoles

  • 0906

    Asymmetric Alkylation of N‑Sulfonyl Ketimines

  • 0907

    The Larock Indole Synthesis: Pd-Catalyzed Annulation of 2-Iodoaniline and Internal Alkyne Derivatives

    • Polymer-Supported Synthesis

  • z0909

    All PDFs of this category

  • 0909

    Electrochemical Allylation of Imines Promoted by Single-Atomic Zinc on Nitrogen-Doped Carbon

  • 0910

    Selective Oxidation of Sulfides to Sulfoxides by a Nickel-Salphen Based Porous Organic Polymer Catalyst

  • 0911

    Photocatalytic α-Alkynylation of Tertiary Amines by Copper-Doped Carbon Nitride

  • 0912

    Photocatalytic Oxidative Hydroxylation of Arylboronic Acids to Phenols by a CdS-TiO2 Nanohybrid

  • 0913

    Photocatalytic Borylation, Silylation, Phosphorylation, and Thiolation Using a Metal–Organic Framework

  • 0914

    Photocatalytic Olefination of Aldehydes with Benzyl Bromides Promoted by Quantum Dots

  • 0915

    A Polyacrylonitrile Fiber-Supported Acid-Base Bifunctional Catalyst for the Henry Reaction

  • 0916

    One-Pot Four-Component Synthesis of Substituted Imidazole Derivatives Using Magnetic Polyborate NPs

  • 0917

    Photocatalytic C–N Bond Formation with Single Iron Atoms on Sulfur-Containing Carbon Nitride

  • 0918

    Visible-Light-Induced Aerobic C=C Bond Cleavage of Vinylarenes Using CsPbBr3

    • Organo- and Biocatalysis

  • z0919

    All PDFs of this category

  • 0919

    Photo-Organocatalyst Enables Reduction of C–F, C–Cl, and C–O Bonds

  • 0920

    Asymmetric Dearomatization of N-Heteroarenes Catalyzed by a Multidentate Halogen-Bond Donor

  • 0921

    Photocatalytic Radical Alkene Hydrogenation by Phosphine-Mediated Water Activation

  • 0922

    NHC Catalysis Permits Regioselective C3–OH or C5–OH Acylation of Unprotected Nucleosides

  • 0923

    Discovery of a General Catalyst for the Oxidative Desymmetrization of Structurally Diverse Diols

  • 0924

    N-Triflyl Phosphoramide-Catalyzed Atroposelective C–C Cross-Coupling of 1-Azonaphthalenes

  • 0925

    Chiral Phosphoric Acid-Catalyzed Asymmetric Synthesis of Remotely Chiral Naphthols and Naphthylamines

  • 0926

    Transition-Metal-Free Synthesis of Bicyclo[2.1.1]hexan-2-ones – meta- and ortho-Benzene Bioisosteres

  • 0927

    P(III)/P(V) Redox Catalysis Enables Isodesmic Deoxygenation of Phosphine Oxides

    • Innovative Drug Discovery and Development

  • z0929

    All PDFs of this category

  • 0929

    Discovery of Selective SYK Inhibitors by the Macrocyclization and Prodrug Approaches

  • 0930

    pH-Switchable Phase-Transfer Agents for Impurity Purging from Biocatalytic Transformations

  • 0931

    Bioinspired Total Synthesis and Bioactivity Evaluation of a Novel Sesquiterpene (–)-Adenophorone

  • 0932

    Lewis Acid-Mediated Tagging of Bioactive Amides

  • 0933

    Site-Specific Functionalization of RNA by a Ribozyme

  • 0934

    Discovery of a Potent and Orally Bioavailable Keap1–Nrf2 PPI Inhibitor

  • 0935

    The Influence of Variable Solvent Peroxide Levels on endo/exo-Selectivity

  • 0936

    Modular Synthesis of Ligand-Directed Covalent Probes

  • 0937

    Radio-Pharmaceutical Probe for ROS Self-Monitoring

  • 0938

    New sp3-Rich Isosteres of the Phenyl Ring with Enhanced Physicochemical Properties

  • 0939

    From Carboxylic Acid Derivatives to Ketones: Modular Ketone Synthesis via Catalytic Olefination

  • 0940

    ortho-Substituted Cannabinoids Achieve Axial Chirality and Impact Receptors Affinity

  • 0941

    SARS-CoV-2 Inhibitors from Synthetic Alotaketal C Analogs

    • Peptide Chemistry

  • z0943

    All PDFs of this category

  • 0943

    Peptide Elongation Using α-NCAs Both as Nucleophiles and Electrophiles

  • 0944

    Cu-Catalyzed Late-Stage Functionalization of Glycine Derivatives and Glycine-Containing Peptides

  • 0945

    Silver-Catalyzed Intermolecular [3+2] Cycloaddition for the Synthesis of Tetrazole-Fused Amino Acids

  • 0946

    Pinnick Oxidation to Form 4-Substituted Proline

  • 0947

    Amine Installation and Facilitated Peptide Elongation

  • 0948

    Ir-Catalyzed Functionalization of Cysteine-Containing Peptides

  • 0949

    Peptide Modification Using Ag-Catalyzed C–H Amination

  • 0950

    Fluorous Sulfur-Containing Boronic Acid Catalyst for Amidation

  • 0951

    Synthesis of Sterically Hindered Tripeptides Using a Modified Ugi Reaction

  • 0952

    Cu-Catalyzed γ-Addition to Form Unnatural Amino Acid Bearing Allene Units

    • Flow Chemistry

  • z0953

    All PDFs of this category

  • 0953

    Rapid Access to Benzodiazepines Using Flow Chemistry

  • 0954

    Transformation of Amides to Nitriles Catalyzed by CeO2 in Continuous-Flow Synthesis