DOI: 10.1055/s-00000131

Synfacts

Issue 02 · Volume 12 · February 2016 DOI: 10.1055/s-006-30867

Synform

A19
Zanda, Matteo: SYNFORM ISSUE 2016/02

Synthesis of Natural Products and Potential Drugs

z109
All PDFs of this category
0109
Synthesis of (R)-Verapamil by Enantioselective Heck Arylation
0110
Synthesis of Sacubitril
0111
Synthesis of Gymnocin-A
0112
Total Synthesis of Rakicidin A
0113
Synthesis of Omarigliptin
0114
Synthesis of an ORL-1 Antagonist
0115
Synthesis of an ORL-1 Antagonist
0116
Total Synthesis of (–)-Lepadiformine A
0117
Synthesis of (–)-Enigmazole A
0118
Synthesis of a Key Intermediate in the Manufacture of Tetracyclines
0119
(±)-Spiramilactone B, (±)-Spiraminol, (±)-Di-hydroajaconine, and (±)-Spiramines C and D
0120
Total Synthesis of Linckoside A
0121
Synthesis of Emindole SB
0122
Synthesis of Codeine

Synthesis of Heterocycles

z123
All PDFs of this category
0123
Multicomponent Reaction/Staudinger/aza-Wittig Synthesis of 2H-Pyrrolo[3,4-c]quinolines
0124
Palladium-Catalyzed Carbonylative C–H Functionalization of Heterocycles
0125
Synthesis of Cyclic Amino Boronates from Boryl Sulfamate Esters
0126
Synthesis of N-Methyliminodiacetic Acid Boryl Heteroaryls
0127
Synthesis of α,β-Epoxy Ketones by Ruthenium-Catalyzed Oxidative Coupling
0128
Triarylantimony-Catalyzed Heteroannulation Route to 2-Arylquinoxalines
0129
Stereoselective Synthesis of Tetrahydro-benzofuranones with Lewis-Base Catalysis
0130
Rhodium/Scandium-Catalyzed Synthesis of Dihydronaphthofurans
0131
Synthesis of Substituted Isatogens and Oxindoles
0132
C–H Activation Route to Isoxazolinones and β-Lactams
0133
[3+2] Cycloaddition Route to Spiropyrrolidin-2-ones
0134
Palladium-Catalyzed Synthesis of 2-Alkenyl-3-arylindoles
0135
Heteroannulation Route to Imidazo[1,2-a]pyridines
0136
Synthesis of Tetrahydrofurans and Pyrrolidines from β-Hydroxy or β-Amino Ketones
0137
Palladium-Catalyzed Benzylic Arylation of Azaarylmethylamines

Synthesis of Materials and Unnatural Products

z139
All PDFs of this category
0139
Easy Access to Triarylmethanes from Acetophenones
0140
Palladium-Catalyzed Polymerization of Diallyl Ether
0141
Functional Polyacrylates by Post-Polymerization Transesterification
0142
Air and Room Temperature Stable Radicals
0143
Octasubstituted Tetrathia[8]circulenes
0144
Two Paths to Twisted Spiro Double Helicene-like Compounds
0145
Layered Heteroacene Dimers with Distinct Emissions
0146
Divalent Nitrogen(I) Compounds with a New Cyclic Carbene Ligand
0147
Liquids with Permanent Porosity
0148
Spirocyclic Germafluorene–Germoles with Tunable Fluorescence
0149
Aerobic Access to Highly Substituted Naphthalene Frameworks
0150
Synthesis and Study of 7,12,17-Trioxa[11]helicene

Metal-Catalyzed Asymmetric Synthesis and Stereoselective Reactions

z151
All PDFs of this category
0151
Iridium-Catalyzed Asymmetric Allylic Dearomatization of Indoles
0152
Catalytic Asymmetric Synthesis of β-Hydroxy Acids from Malonic Acid
0153
Azides and Nitriles in Palladium-Catalyzed Decarboxylative Allylation
0154
Asymmetric Synthesis of Polycyclic 3-Spirooxindole Alkaloids
0155
Rhodium-Catalyzed Asymmetric Dehydrogenative Cross-Coupling
0156
Visible-Light Iridium-Catalyzed Asymmetric Synthesis of 1,2-Amino Alcohols
0157
Rhodium-Catalyzed Synthesis of Hydrocarbazoles by a Diels–Alder Reaction
0158
Copper-Catalyzed Enantioselective Diarylation of Alkenes
0159
Rhodium-Catalyzed Stereoselective Carboamination of Alkenes
0160
Enantioselective Synthesis of α-Alkenyl Amino Acids by N–H Insertion Reactions
0161
Rhodium-Catalyzed Asymmetric Synthesis of Spiroindenes
0162
Iridium-Catalyzed Enantioselective Ring Opening of Oxabicycles with Amines
0163
Asymmetric Hydrosilylation of Prochiral Ketones
0164
Zinc-Catalyzed Asymmetric Mannich and Aldol Reactions Using Fluorinated Ketones
0165
Gold-Catalyzed Hydroamination of Methylenecyclopropanes
0166
Asymmetric Silver-Catalyzed Synthesis of Functionalized Pyrrolidines
0167
Copper-Catalyzed Asymmetric Michael Addition of Cyclic Azomethines to Nitroalkenes
0168
Asymmetric Hydrovinylation of Siloxydienes by Cobalt Catalysis
0169
Enantioselective Alkynylation of Oxocarbenium Ions
0170
Palladium-Catalyzed trans-Selective Chlorocarbamoylation of Alkynes
0171
Copper-Catalyzed Asymmetric Ring Opening of D–A Cyclopropanes
0172
Asymmetric Magnesium-Catalyzed Desymmetrization of meso-Aziridines
0173
Suppression of the Retro-Aldol Reaction of Thioamides by an Additive
0174
Asymmetric Addition of Styrenes to Sulfonyl-Ketimino Esters
0175
Enantioselective Nickel-Catalyzed Michael Addition of 2-Azaarenes to Nitroalkenes
0176
Chromium-Catalyzed Enantioselective Syn-thesis of α-exo-Methylene-γ-butyrolactones
0177
Palladium-Catalyzed Asymmetric Phospha-Michael Reaction

Metal-Mediated Synthesis

z179
All PDFs of this category
0179
Photoredox-Generated α-Amino Radicals Used in (Hetero)Arylation
0180
Copper-Mediated Rearrangement of Bisamides
0181
Enantioselective Copper-Catalyzed Carbozincation of Cyclopropenes
0182
Copper(I)-Catalyzed Hydrosilylation of Enynoate
0183
Nickel-Catalyzed Alkyne Arylmagnesiation
0184
Asymmetric Aldol Reaction for the Synthesis of trans-Oxazolines
0185
Zinc Amide Catalyzed Allenylation and Propargylation
0186
Nickel-Catalyzed Allyl–Aryl Coupling
0187
Palladium-Catalyzed C–H Arylation
0188
InBr3-Mediated Oxidative Coupling of Terminal Alkynes with Aldehydes
0189
1,2-Addition and Cross-Coupling of Organolithiums with Weinreb Amides
0190
β-Hydrogen Transfer Reduction of Carbonyl Compounds
0191
Stereoselective Synthesis of Trisubstituted Alkenes
0192
Chromium-Catalyzed Selective Cross-Coupling of Aryl Alkyl Ethers
0193
Copper(II)-Promoted Cyclization/Difunctionalization

Organo- and Biocatalysis

z195
All PDFs of this category
0195
Biocatalytic One-Pot Synthesis of l-Tyrosine Derivatives
0196
Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines
0197
Organocatalytic Asymmetric 2-Aza-Cope Rearrangement
0198
Enantioselective Construction of Tertiary Stereocenters
0199
Hypervalent Iodine Catalyzed Asymmetric Vicinal Dioxygenation of Alkenes
0200
Addition of 2-Alkoxycarbonyl-1,3-dithianes to Imines
0201
Aza-Michael Addition with a Chiral Phosphoric Acid Catalyst

Polymer-Supported Synthesis

z203
All PDFs of this category
0203
Arylations with Rhodium on a Chiral Diene-Based Metal–Organic Framework
0204
Palladium/Carbon-Catalyzed Carbonylative Cyclization
0205
Direct Cross-Coupling of Phenols with Amines Using Palladium on Carbon
0206
Water/Iron Powder as a Hydrogen Source in Olefin Hydrogenation
0207
One-Pot Synthesis of Flavones by Using Supported Gold Nanoparticles
0208
Synthesis of Alkynyl Aryl Sulfides by Heterogeneous Copper(I) Catalysis
0209
Platinum-Catalyzed Hydrodeoxygenation of Phenols with Hydrogen
0210
Cycloaddition of CO2 to Epoxides Catalyzed by Polymeric Ionic Liquids
0211
One-Pot Synthesis of Benzoxazoles with Copper Nanoparticles
0212
Synthesis of β-Phosphonomalonates with Pyridine-Grafted Graphene Oxide
0213
Graphene Oxide-Promoted Friedel–Crafts-Type Alkylation of Arenes
0214
Copper Nanoparticle Catalyzed N-Arylation of Amines
0215
Gold–Ceria Nanomaterial Catalyzed Controlled Hydrogenation of Alkynes
0216
Synthesis of Aryl-Substituted Benzimidazoles by Using Palladium/Carbon
0217
Synthesis of Carboxylic Acids with Oxalic Acid and Palladium Nanoparticles
0218
Direct Amidation of Benzoic Acids with a Metal–Organic Framework Zirconium Catalyst