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Synlett 2008(10): 1440-1448
DOI: 10.1055/s-2008-1078425
DOI: 10.1055/s-2008-1078425
ACCOUNT
© Georg Thieme Verlag Stuttgart · New YorkRecent Developments on Hemilabile P,O-Type Ligands in Cross-Coupling Reactions
Weitere Informationen
Received
22 February 2008
Publikationsdatum:
16. Mai 2008 (online)
Publikationsverlauf
Publikationsdatum:
16. Mai 2008 (online)
Abstract
This review describes the concepts of and recent developments on monophosphine P,O-type ligands. The attractive synthetic pathways to these ligands are highlighted, and the applications of the ligands in cross-coupling reactions are fully illustrated. The hemilabile properties of P,O-type ligands on complexation with transition metals are also discussed.
1 Introduction
2 Different P,O-Type Ligands
2.1 P,O-Type Ligands with an Acetal Moiety
2.2 P,O-Type Ligands with a Sulfonyl Group
2.3 P,O-Type Ligands with an Amido Group
3 Chirality of P,O-Type Ligands
4 Achiral P,O-Type Ligands with a Ferrocenyl Scaffold
5 Conclusion
Key words
ligands - cross-coupling - catalysis - phosphines - P,O-coordination
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