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Synthesis 2008(6): 957-961  
DOI: 10.1055/s-2008-1032172
PAPER
© Georg Thieme Verlag Stuttgart · New York

Scalable Synthesis of Lissamine Rhodamine B Sulfonyl Chloride and Incorporation of Xanthene Derivatives onto Polymer Supports

Hua Yanga, Sundar Vasudevanb, Christopher O. Oriakhib, Jay Shieldsb, Rich G. Carter*a
a Department of Chemistry, Oregon State University, 153 Gilbert Hall, Corvallis, OR 97331, USA
Fax: +1(541)7379496; e-Mail: rich.carter@oregonstate.edu;
b Hewlett-Packard Corporation, 1000 NE Circle Blvd, Corvallis, OR 97330, USA
Further Information

Publication History

Received 7 November 2007
Publication Date:
08 February 2008 (online)

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Abstract

A scalable synthetic route to lissamine rhodamine B sulfonyl chloride has been developed and a series of monomeric derivatives of this xanthene dye have been synthesized. Their subsequent incorporation into polymer supports has been accomplished and led to improved thermal stability for the conjugates as compared to the free dye.

Key words

heterocycles - polymers - dyes

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3

Acros Catalog Number 41323-0050. Pricing in 2006/2007 catalog: $407.90 for 5 grams.

6

Also called Food Red No. 106: TCI America catalog #F0144. 2006-2007 catalog price $66.95 for 25 grams.