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Synthesis 2006(23): 4075-4080
DOI: 10.1055/s-2006-950344
DOI: 10.1055/s-2006-950344
SPECIALTOPIC
© Georg Thieme Verlag Stuttgart · New YorkMannich-Type Reaction in Water in the Presence of a Surfactant
Further Information
Received
3 August 2006
Publication Date:
02 November 2006 (online)
Publication History
Publication Date:
02 November 2006 (online)

Abstract
The effect of sodium dodecyl sulfate (SDS) loading in fluoroboric acid catalyzed Mannich-type reactions of ketene silyl acetals with aldimines was studied. The reaction proceeded smoothly in the presence of 1 mol% of SDS. Formation of small particles was observed by transmission electron microscopy.
Key words
Mannich-type reaction - water - imine - surfactant - amino ester
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References
We formerly studied the loading of SDS using a ketene silyl enol ether as a substrate.