Asymmetric Synthesis of Chiral Polymers by Means of Repetitive Addition of Allylsilane to Aldehyde

Abstract

Monomers having both allyltrimethylsilyl and formyl groups were prepared. Chiral (acyloxy)borane initiated the repetitive polyaddition of the monomers to give optically active polymers having main chain configurational chirality. Optical purity of the chiral polymer was evaluated by the analysis of the degradation product.

allylations - asymmetric catalysis - polymers - asymmetric polymerization - optically active polymers

References

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