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Synlett 2016; 27(01): 1-5
DOI: 10.1055/s-0035-1560541
DOI: 10.1055/s-0035-1560541
letter
Synthesis and Evaluation of a Novel Hydrophilic 6,6′-Bis(1,2,4-triazin-3-yl)-2,2′-bipyridine Ligand for Separating Actinide(III) from Lanthanide(III)
Further Information
Publication History
Received: 15 September 2015
Accepted after revision: 02 November 2015
Publication Date:
18 November 2015 (online)
Dedicated to Professor Steven Ley on the occasion of his 70th birthday
Abstract
We report the synthesis and evaluation of a novel hydrophilic 6,6′-bis(1,2,4-triazin-3-yl)-2,2′-bipyridine (BTBP) ligand containing carboxylate groups as a selective aqueous complexing agent for the minor actinides over lanthanides. The novel ligand is able to complex and separate Am(III) from Eu(III) in alkaline solutions selectively.
Key words
BTBP - americium - separation factor - europium - N-heterocycle - used nuclear fuel - ligandSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1560541.
- Supporting Information
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References and Notes
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