Copper-Catalyzed Negishi Coupling of Diarylzinc Reagents with Aryl Iodides

Abstract

We report an efficient copper(I) iodide catalyzed cross-coupling­ of diarylzinc reagents with aryl iodides. The reaction proceeds under ligand-free conditions at low catalyst loading (5 mol%) and tolerates a variety of functional groups.

Key words

copper - cross-coupling - diarylzinc - ligand-free - Negishi coupling

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