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Synthesis 2015; 47(12): 1696-1705
DOI: 10.1055/s-0034-1380195
DOI: 10.1055/s-0034-1380195
short review
Recent Advances in Iron-Catalyzed Csp2–Csp2 Cross-Couplings
Further Information
Publication History
Received: 20 December 2014
Accepted: 11 March 2015
Publication Date:
02 April 2015 (online)
Abstract
The present review article highlights recent progress in the field of iron-catalyzed cross-coupling reactions between Csp² centers. The reaction scope of various iron-catalyzed couplings between aromatic Grignard reagents and unsaturated halides is described and some mechanistic insights are given.
1 Introduction
2 Historical Work
3 Iron-Catalyzed Homocouplings of Aryl Organometallics
4 Iron-Catalyzed sp2–sp2 Cross-Couplings
4.1 Arylcopper Reagents as Nucleophiles
4.2 Arylmagnesium Reagents as Nucleophiles
4.2.1 Couplings with Alkenyl Halides
4.2.2 Couplings with Heteroaryl Halides
4.2.3 Coupling with Aryl Halides
5 Conclusion
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For selected reviews on iron-catalyzed cross-coupling reactions, see:
For selected publications on mechanistic investigations of iron-catalyzed coupling reactions, see: